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    • 2. 发明授权
    • Process for the production of xylenes
    • 生产二甲苯的方法
    • US09249068B2
    • 2016-02-02
    • US14735531
    • 2015-06-10
    • ExxonMobil Chemical Patents Inc.
    • Robert G. TingerJeffrey L. AndrewsMichel Molinier
    • C07C2/66C07C6/12C07C1/24C07C4/24C07C5/27C07C2/86C07C4/12C07C6/06B01J19/24
    • C07C5/277B01J19/24B01J19/2445B01J19/245B01J2219/24C07C2/862C07C2/864C07C4/14C07C5/2729C07C5/2732C07C6/04C07C6/06C07C6/123C07C7/005C07C7/04C07C7/12C07C7/13C07C7/14C10G35/04C07C15/08
    • In a process for producing para-xylene, a feed stream comprising C6+ aromatic hydrocarbons is separated into a C7− aromatic hydrocarbon-containing stream, a C8 aromatic hydrocarbon-containing stream, and a C9+ aromatic hydrocarbon-containing stream. The C7− aromatic hydrocarbon-containing stream is contacted with a methylating agent to convert toluene to xylenes and produce a methylated effluent stream. Ethylbenzene is removed from the C8 aromatic hydrocarbon-containing stream, para-xylene is recovered from the ethylbenzene-depleted C8 aromatic hydrocarbon-containing stream and the methylated effluent stream in a para-xylene recovery section to produce a para-xylene depleted stream, which is then contacted with a xylene isomerization catalyst under liquid phase conditions effective to isomerize xylenes in the para-xylene depleted stream and produce an isomerized stream. The C9+-containing stream with a transalkylation catalyst under conditions effective to convert C9+-aromatics to C8−-aromatics and produce a transalkylated stream, which is recycled together with the isomerized stream to the para-xylene recovery section.
    • 在制备对二甲苯的方法中,将包含C 6 +芳族烃的进料流分离成含C7-芳香族烃的物流,含C 8芳族烃的物流和含有C 9 +芳族烃的物流。 使含C7-芳族烃的物流与甲基化剂接触以将甲苯转化为二甲苯并产生甲基化流出物流。 从含有C8芳族烃的物流中除去乙苯,从对苯二甲苯回收部分中的乙苯贫化C8芳族烃流和甲基化流出物流中回收对二甲苯以产生对二甲苯贫化物流,其中 然后在液相条件下与二甲苯异构化催化剂接触,有效地使对二甲苯贫化物流中的二甲苯异构化并产生异构化的物流。 含有C 9+的物流与烷基转移催化剂在有效地将C 9+芳族化合物转化为C 8 - 芳族化合物并产生烷基转移反应的物流的条件下进行反应,该物流与异构化物流一起再循环到对二甲苯回收段。