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    • 7. 发明申请
    • Direct synthesis of copper carbonate
    • 直接合成碳酸铜
    • US20070269362A1
    • 2007-11-22
    • US11436528
    • 2006-05-19
    • Gang Zhao
    • Gang Zhao
    • C01G3/14
    • C01G3/00C01G3/08C01G3/10C01P2004/61C01P2006/10C01P2006/11
    • A basic copper salt selected from basic copper carbonate, basic copper sulfate, basic copper acetate, basic copper citrate, and basic copper nitrate is manufactured by contacting copper metal with an aqueous solution having ammonia; an acid selected from carbonic acid, sulfuric acid, acetic acid, nitric acid, or citric acid; and oxygen, under conditions where the copper metal is converted to the basic copper salt; and then recovering the basic copper salt. The most economical embodiment is where the ammonia is present in the aqueous solution is in an amount between about 6.7 g/l and about 15 g/l calculated as NH3, and the pH of the composition is between 8 and 10, and the temperature of the composition is between 25° C. and 100° C. The method is particularly useful if the basic copper salt is basic copper carbonate. The basic copper carbonate produced has the formula: (CuCO3)x(Cu(OH2)y, where y is 1 and x is between 0.1 to less than 1; or where y is 1 and x is 1, or where y is 1 and x is between 0.5 to less than about 0.95, or where y is 1 and x greater than 1.
    • 通过使铜金属与具有氨的水溶液接触来制造碱性碳酸铜,碱式硫酸铜,碱式乙酸铜,碱式柠檬酸铜和碱式硝酸铜的碱性铜盐, 选自碳酸,硫酸,乙酸,硝酸或柠檬酸的酸; 和氧气,在铜金属转化为碱性铜盐的条件下; 然后回收碱性铜盐。 最经济的实施方案是其中氨在水溶液中的存在量为按NH 3计算的约6.7g / l和约15g / l之间的量,并且组合物的pH在 8和10,并且组合物的温度在25℃和100℃之间。如果碱性铜盐是碱式碳酸铜,该方法是特别有用的。 所生产的碱式碳酸铜具有下式:(CuCO 3)x(Cu(OH 2))y, 其中y为1且x为0.1至小于1;或其中y为1且x为1,或其中y为1且x为0.5至小于约0.95,或者y为1且x大于1 。