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1. 发明授权

US06713216B2 Thin alkali metal film member and method of producing the same 失效
标题翻译：薄碱金属膜构件及其制造方法
公开(公告)号：US06713216B2
公开(公告)日：2004-03-30
申请号：US09884632
申请日：2001-06-18
申请人： Hirokazu Kugai , Nobuhiro Ota , Shosaku Yamanaka
发明人： Hirokazu Kugai , Nobuhiro Ota , Shosaku Yamanaka
IPC分类号： H01M440
CPC分类号： H01M4/0421 , C23C14/14 , C23C14/564 , H01M4/0404 , H01M4/0423 , H01M4/0426 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M4/383 , H01M4/40 , H01M4/66 , H01M10/052 , H01M10/0562 , Y10T29/49115
摘要： A member having a lithium metal thin film is provided, which is extremely thin, uniform, and not degraded by air. The member includes a substrate and a thin lithium metal film formed on the substrate by a vapor deposition method. The thin film typically has a thickness of 0.1 &mgr;m to 20 &mgr;m. The substrate is typically made of a metal, an alloy, a metal oxide, or carbon. The substrate typically has a thickness of 1 &mgr;m to 100 &mgr;m. The member is used as an electrode member for a lithium cell.
摘要翻译：提供具有锂金属薄膜的构件，其极薄，均匀，并且不会被空气劣化。该构件包括通过气相沉积法在衬底上形成的衬底和薄的锂金属膜。薄膜通常具有0.1μm至20μm的厚度。基底通常由金属，合金，金属氧化物或碳制成。基底通常具有1μm到100μm的厚度。该构件用作锂电池的电极构件。

2. 发明授权

US06465131B1 Lithium secondary cell with a stannous electrode material 失效
标题翻译：具有硫化亚锡电极材料的锂二次电池
公开(公告)号：US06465131B1
公开(公告)日：2002-10-15
申请号：US09588338
申请日：2000-06-06
申请人： Yasuyuki Kusumoto , Masahisa Fujimoto , Shin Fujitani
发明人： Yasuyuki Kusumoto , Masahisa Fujimoto , Shin Fujitani
IPC分类号： H01M440
CPC分类号： H01M4/583 , C01G19/00 , C01G19/006 , C01G31/006 , C01G37/006 , C01G45/006 , C01G45/1228 , C01G49/12 , C01G51/30 , C01G51/42 , C01G53/11 , C01G53/42 , C01P2002/54 , C01P2006/40 , H01M4/131 , H01M4/505 , H01M4/525 , H01M10/052 , H01M10/0525 , H01M2004/027 , H01M2004/028
摘要： A lithium secondary cell having incorporated therein a positive electrode or negative electrode active substance which is a compound sulfide having substantially the same crystal structure as stannous sulfide (SnS) or a lithium-containing compound sulfide comprising said compound sulfide and lithium contained therein, said compound sulfide comprising at least one transition metal selected from among copper (Cu), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co) and nickel (Ni), tin and sulfur. This stabilizes the crystal structure of SnS serving as the active substance, giving the cell practically useful charge-discharge cycle characteristics.
摘要翻译：一种锂二次电池，其中并入有正极或负极活性物质，其为与硫化亚锡（SnS）基本相同的结构结构的化合物硫化物或包含所述化合物硫化物和锂的含锂化合物硫化物，所述化合物包含选自铜（Cu），钒（V），铬（Cr），锰（Mn），铁（Fe），钴（Co）和镍（Ni），锡和硫中的至少一种过渡金属的硫化物。这稳定了作为活性物质的SnS的晶体结构，给予电池实际有用的充放电循环特性。

3. 发明授权

US06190802B1 Transition metal based ceramic material and electrodes fabricated therefrom 有权
标题翻译：过渡金属基陶瓷材料和由其制造的电极
公开(公告)号：US06190802B1
公开(公告)日：2001-02-20
申请号：US09315169
申请日：1999-05-20
申请人： Daryl Clerc , Matthew Fay , Levi Thompson , Michael Wixom
发明人： Daryl Clerc , Matthew Fay , Levi Thompson , Michael Wixom
IPC分类号： H01M440
CPC分类号： H01M4/131 , C01B21/0821 , C01P2002/52 , C01P2004/61 , C04B35/58007 , C04B35/58028 , C04B35/624 , C04B2235/3201 , C04B2235/3244 , C04B2235/3886 , C04B2235/441 , H01M4/485 , H01M4/58
摘要： A transition metal based ceramic material having the general formula Li&agr;M1−&bgr;T&bgr;NxO67, wherein M is a transition metal, T is a dopant metal, and wherein x is greater than 0 and less than or equal to l, &dgr; is 0, or less than or equal to 4; &agr; is less than or equal to 3−x, and &bgr; is less than 1 is disclosed. The ceramic material has utility as a cathode material for rechargeable lithium batteries.
摘要翻译：具有通式LialphaM1-βTbetaNxO67的过渡金属基陶瓷材料，其中M是过渡金属，T是掺杂剂金属，并且其中x大于0且小于或等于1，δ为0或小于或等于1，等于4; α小于或等于3-x，并且β小于1。陶瓷材料可用作可再充电锂电池的阴极材料。

4. 发明授权

US06805999B2 Buried anode lithium thin film battery and process for forming the same 有权
标题翻译：埋入阳极锂薄膜电池及其成型工艺
公开(公告)号：US06805999B2
公开(公告)日：2004-10-19
申请号：US10110581
申请日：2003-03-17
申请人： Se-Hee Lee , C. Edwin Tracy , Ping Liu
发明人： Se-Hee Lee , C. Edwin Tracy , Ping Liu
IPC分类号： H01M440
CPC分类号： H01M10/058 , H01M4/0421 , H01M4/0426 , H01M4/0438 , H01M4/0445 , H01M4/1391 , H01M4/1395 , H01M4/382 , H01M4/485 , H01M4/505 , H01M4/525 , H01M10/0436 , H01M10/052 , H01M10/0562 , Y10T29/49108 , Y10T29/49115
摘要： A reverse configuration, lithium thin film battery (300) having a buried lithium anode layer (305) and process for making the same. The present invention is formed from a precursor composite structure (200) made by depositing electrolyte layer (204) onto substrate (201), followed by sequential depositions of cathode layer (203) and current collector (202) on the electrolyte layer. The precursor is subjected to an activation step, wherein a buried lithium anode layer (305) is formed via electroplating a lithium anode layer at the interface of substrate (201) and electrolyte film (204). The electroplating is accomplished by applying a current between anode current collector (201) and cathode current collector (202).
摘要翻译：具有掩埋锂阳极层（305）的反向配置的锂薄膜电池（300）及其制造方法。本发明由通过将电解质层（204）沉积在基板（201）上制成的前体复合结构（200）形成，随后在电解质层上依次沉积阴极层（203）和集电器（202）。前体经受活化步骤，其中通过在基底（201）和电解质膜（204）的界面处电镀锂阳极层来形成掩埋的锂阳极层（305）。通过在阳极集电器（201）和阴极集电器（202）之间施加电流来实现电镀。

5. 发明授权

US06517590B1 Additives for lubricating agents used in the lamination of lithium sheets into thin films 失效
标题翻译：用于将锂片层压成薄膜的润滑剂用添加剂
公开(公告)号：US06517590B1
公开(公告)日：2003-02-11
申请号：US09480482
申请日：2000-01-11
申请人： Michel Gauthier , Patrick Bouchard , Paul-Emile Guerin , Michel Armand
发明人： Michel Gauthier , Patrick Bouchard , Paul-Emile Guerin , Michel Armand
IPC分类号： H01M440
CPC分类号： H01M4/0404 , B21B1/40 , B21B3/00 , B21B45/0242 , B21B45/0251 , C10M145/38 , C10M2203/02 , C10M2203/022 , C10M2203/024 , C10M2203/04 , C10M2203/045 , C10M2203/06 , C10M2203/065 , C10M2209/084 , C10M2209/104 , C10M2209/105 , C10M2209/108 , C10M2209/109 , C10M2215/04 , C10M2215/042 , C10M2215/26 , C10M2217/046 , C10M2217/06 , C10N2220/02 , C10N2240/402 , C10N2240/403 , C10N2240/404 , C10N2240/405 , C10N2240/406 , C10N2240/407 , C10N2240/408 , C10N2240/409 , H01M4/04 , H01M4/0402 , H01M4/0411 , H01M4/0416 , H01M4/0435 , H01M4/134 , H01M4/1395 , H01M10/052 , H01M10/0565 , Y10T29/49108 , Y10T29/49112
摘要： These additives are represented by the following general formula: L—Y—S in which L designates a hydrocarbon radical which serves as lubricating segment; S designates an oligomer segment which serves as solvating segment of metallic salts and Y designates a chemical bond which joins the hydrocarbon radical and the oligomer segment. With these additives there is no more need to subsequently wash the surface of laminated lithium.
摘要翻译：这些添加剂由以下通式表示：其中L表示作为润滑链段的烃基; S表示用作溶剂化金属盐部分的低聚物部分，Y表示连接烃基和低聚物部分的化学键。使用这些添加剂不再需要随后洗涤层压锂的表面。

6. 发明授权

US06207326B1 Secondary battery 失效
标题翻译：二次电池
公开(公告)号：US06207326B1
公开(公告)日：2001-03-27
申请号：US08980055
申请日：1997-11-26
申请人： Soichiro Kawakami , Shinya Mishina , Naoya Kobayashi
发明人： Soichiro Kawakami , Shinya Mishina , Naoya Kobayashi
IPC分类号： H01M440
CPC分类号： H01M10/05 , H01M2/14 , H01M2/1673 , H01M4/02 , H01M4/04 , H01M4/0402 , H01M4/0404 , H01M4/0409 , H01M4/0414 , H01M4/0416 , H01M4/0419 , H01M4/0421 , H01M4/0426 , H01M4/0428 , H01M4/043 , H01M4/0435 , H01M4/0438 , H01M4/045 , H01M4/0452 , H01M4/0466 , H01M4/0471 , H01M4/13 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/139 , H01M4/1391 , H01M4/24 , H01M4/244 , H01M4/36 , H01M4/366 , H01M4/38 , H01M4/40 , H01M4/42 , H01M4/48 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/58 , H01M4/581 , H01M4/582 , H01M4/62 , H01M4/621 , H01M4/622 , H01M4/623 , H01M4/625 , H01M4/74 , H01M4/742 , H01M4/808 , H01M10/052 , H01M10/056 , H01M10/058 , H01M10/0585 , H01M10/0587 , H01M10/24 , H01M10/30 , H01M12/08 , H01M2004/027 , Y02E60/128 , Y10T29/49108
摘要： A secondary battery exhibiting a long cycle life and comprising a negative pole activating material made of lithium or zinc is provided, the battery at least having a negative pole made of lithium or zinc serving as the negative pole activating material, an electrolyte (electrolytic solution), a separator, a positive pole made of a positive pole activating material, a collecting electrode and a battery case, wherein at least the surface of the negative pole is covered with a film having a structure which allows ions relating to the battery reactions to pass through. Since growth of dendrites of lithium or zinc at the time of charge can be prevented, short circuiting between the negative pole and the positive pole can be prevented. Therefore, the charge/discharge cycle life can significantly be lengthened. As a result, a lithium secondary battery, a nickel-zinc secondary battery, an air-zinc secondary battery, a bromine-zinc secondary battery and a silver oxide-zinc secondary battery of long cycle life can be manufactured.
摘要翻译：提供具有长循环寿命且包含由锂或锌制成的负极活化材料的二次电池，该电池至少具有由用作负极活化材料的锂或锌制成的负极，电解质（电解液）分离器，由正极活化材料制成的正极，集电电极和电池壳体，其中至少负极的表面被具有允许与电池反应相关的离子通过的结构的膜覆盖通过。由于可以防止在充电时锂或锌的枝晶生长，所以可以防止负极和正极之间的短路。因此，充放电循环寿命可以显着延长。结果，可以制造循环寿命长的锂二次电池，镍 - 锌二次电池，空气 - 锌二次电池，溴 - 锌二次电池和氧化银 - 锌二次电池。

7. 发明授权

US06828063B2 Anode thin film for lithium secondary battery 失效
标题翻译：锂二次电池用阳极薄膜
公开(公告)号：US06828063B2
公开(公告)日：2004-12-07
申请号：US09987939
申请日：2001-11-16
申请人： Young-sin Park , Hong-koo Baik , Sung-man Lee , Joo-yeal Oh
发明人： Young-sin Park , Hong-koo Baik , Sung-man Lee , Joo-yeal Oh
IPC分类号： H01M440
CPC分类号： H01M4/134 , H01M4/38 , H01M4/386 , H01M4/40 , H01M4/661 , H01M10/0525
摘要： The present invention provides an anode thin film for a lithium secondary battery having a current collector and an anode active material layer formed thereon. Here, the anode active material layer is a multiple-layer thin film comprising a silicon (Si) layer and a silver (Ag) layer or a single-layer thin film comprising silicon (Si) and silver (Ag).
摘要翻译：本发明提供一种用于锂二次电池的阳极薄膜，其上形成有集电体和负极活性材料层。这里，负极活性物质层是包含硅（Si）层和银（Ag）层的多层薄膜，或者包含硅（Si）和银（Ag）的单层薄膜。

8. 发明授权

US06749965B1 Positive active material for lithium secondary batteries and method of preparing the same 有权
标题翻译：锂二次电池用正极活性物质及其制备方法
公开(公告)号：US06749965B1
公开(公告)日：2004-06-15
申请号：US09595075
申请日：2000-06-16
申请人： Ho-Jin Kweon , Hyun-Sook Jung , Geun-Bae Kim , Dong-Gon Park
发明人： Ho-Jin Kweon , Hyun-Sook Jung , Geun-Bae Kim , Dong-Gon Park
IPC分类号： H01M440
CPC分类号： H01M4/485 , H01M4/131 , H01M4/366 , H01M4/525 , H01M4/58 , H01M10/0525 , H01M2004/021 , H01M2004/028
摘要： Disclosed is a positive active material for a lithium secondary battery having high capacity and long durability properties and particularly to a powder of LiaNi1-x-yC OxMyO2, LiaNi1-x-yC OxMyO2-zFz or LiaNi1-x-yC OxMyO2-zSz (where M is a metal selected from the group consisting of Al, Mg, Sr, La, Ce, V, and Ti and wherein 0≦0.99, 0.01≦y≦0.1, 0.01≦z≦0.1, and 1.00≦a≦1.1) is surface-treated by a metal alkoxide solution whereby the durability, capacity and structural safety of said positive active material is increased.
摘要翻译：公开了具有高容量和长的耐久性的锂二次电池的正极活性材料，特别是对于LiaNi1-x-yC OxMyO2，LiaNi1-x-yC OxMyO2-zFz或LiaNi1-x-yC OxMyO2-zSz的粉末（其中 M是选自Al，Mg，Sr，La，Ce，V和Ti的金属，其中0 <=0.99,0.01≤y≤0.1,0.01≤z≤0.1， = a <= 1.1）由金属醇盐溶液进行表面处理，由此提高所述正极活性物质的耐久性，容量和结构安全性。

9. 发明授权

US06489062B1 Non-aqueous electrolyte secondary battery having heat-resistant electrodes 失效
标题翻译：具有耐热电极的非水电解质二次电池
公开(公告)号：US06489062B1
公开(公告)日：2002-12-03
申请号：US09465078
申请日：1999-12-16
申请人： Shunji Watanabe , Shinichi Takasugi , Hideharu Onodera , Toyoo Harada , Tsugio Sakai
发明人： Shunji Watanabe , Shinichi Takasugi , Hideharu Onodera , Toyoo Harada , Tsugio Sakai
IPC分类号： H01M440
CPC分类号： H01M4/131 , H01M2/0413 , H01M2/16 , H01M4/485 , H01M6/166 , H01M10/0525 , H01M2004/027
摘要： A non-aqueous electrolyte secondary battery capable of withstanding a reflow temperature has a positive electrode having a conductive material, a binder, and an electrode active material selected from the group consisting of LiCoO2, LiNiO2 and LiMn2O4. A negative electrode has a conductive material, a binder and an electrode active material selected from the group consisting of a titanium oxide having an anatase structure, lithium titanate having a spinel structure and a molybdenum oxide. An electrolyte has a supporting salt and a non-aqueous solvent having a boiling point greater than 200° C. A gasket is comprised of a material having a heat deformation temperature greater than 230° C. A separator is disposed between the positive electrode and the negative electrode and is comprised of a material having a heat deformation temperature greater than 230° C. At least one of the positive electrode and the negative electrode comprises an electrode heat-treated to a temperature of 250° C. to 450° C. for deactivating a thermally active portion of each of the conductive material, the binder and the electrode active material thereof.
摘要翻译：能够承受回流温度的非水电解质二次电池具有选自LiCoO 2，LiNiO 2和LiMn 2 O 4的导电材料，粘合剂和电极活性物质的正极。负极具有导电材料，粘合剂和选自具有锐钛矿结构的氧化钛，具有尖晶石结构的钛酸锂和氧化钼的电极活性材料。电解质具有支撑盐和沸点大于200℃的非水溶剂。垫片由热变形温度大于230℃的材料构成。隔板设置在正极和负极，并且由热变形温度大于230℃的材料构成。正极和负极中的至少一个包括热处理至250℃至450℃的电极，用于使导电材料，粘合剂及其电极活性物质的热活性部分失活。

10. 发明授权

US06391496B1 Lithium secondary battery with orthorhombic molybdenum and niobium oxide electrodes 失效
标题翻译：具有正交钼和铌氧化物电极的锂二次电池
公开(公告)号：US06391496B1
公开(公告)日：2002-05-21
申请号：US09506588
申请日：2000-02-18
申请人： Hiroshi Nakajima , Taeko Ota , Hiroshi Watanabe , Shin Fujitani
发明人： Hiroshi Nakajima , Taeko Ota , Hiroshi Watanabe , Shin Fujitani
IPC分类号： H01M440
CPC分类号： H01M4/131 , C01G9/00 , C01G33/00 , C01G37/00 , C01G39/00 , C01G39/02 , C01G41/00 , C01G45/00 , C01G45/1228 , C01G45/1242 , C01G49/00 , C01G49/0018 , C01G51/00 , C01G51/42 , C01G51/50 , C01G53/00 , C01G53/42 , C01G53/50 , C01P2002/54 , C01P2002/76 , C01P2004/61 , C01P2004/82 , C01P2006/40 , H01M4/40 , H01M4/485 , H01M4/525 , H01M4/5825 , H01M10/0525 , H01M2004/021 , H01M2004/028
摘要： In a lithium secondary battery of this invention, either a positive electrode or a negative electrode includes, as an active material, an orthorhombic composite oxide represented by a composition formula, MxMo1−xOy, wherein M is at least one transition element selected from the group consisting of Cu, V, Mn, Fe, Co and Ni; 0
摘要翻译：在本发明的锂二次电池中，正极或负极包括由组成式MxMo1-xOy表示的正交复合氧化物作为活性物质，其中M为选自下组的至少一种过渡元素：由Cu，V，Mn，Fe，Co和Ni组成; 0

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