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1. 发明授权

US3935024A Halogen hydrates 失效
标题翻译：卤素水合物
公开(公告)号：US3935024A
公开(公告)日：1976-01-27
申请号：US320806
申请日：1973-01-03
申请人： Philip Charles Symons
发明人： Philip Charles Symons
IPC分类号： H01M10/36 , H01M12/08 , H01M35/00
CPC分类号： H01M12/085 , H01M10/365 , Y02E60/128
摘要： A process for the useful storage of electrical energy employing halogen hydrates is described. The halogen hydrate can be generated during the charging of a secondary battery or may be chemically generated and placed in a primary battery.
摘要翻译：描述了使用卤素水合物有效储存电能的方法。卤素水合物可以在二次电池的充电期间产生，或者可以化学生成并放置在一次电池中。

2. 发明授权

US3907593A Electrochemical cells 失效
标题翻译：电化学电池
公开(公告)号：US3907593A
公开(公告)日：1975-09-23
申请号：US47089074
申请日：1974-05-17
申请人： GTE LABORATORIES INC
发明人： MARINCIC NIKOLA
IPC分类号： H01M6/12 , H01M6/14 , H01M35/00
CPC分类号： H01M6/12 , H01M2/0222 , H01M6/14
摘要： Electrochemical cells having an alkali metal anode, a carbon or (C4F)n cathode, and an electrolyte, comprising a solute dissolved in an inorganic oxyhalide or thiohalide solvent, between and in contact with the anode and cathode. The cathode material, which catalyzes the electrochemical decomposition of the solvent, is present as a composite structure wherein a metallic screen is coated on both sides thereof with the cathode material. The screen is so positioned that sharp spikes at the ends thereof cut into the walls of the can thereby maintaining positive electrical and structural contact. The invention is particularly related to the use of the composite cathode structure in flat, button-type cells since assembly of such cells using a prefabricated cathode composite disc, is readily facilitated.
摘要翻译：具有碱金属阳极，碳或（C 4 F）n阴极和电解质的电化学电池，其包含溶解在无机卤氧化物或硫代卤素溶剂中的溶质，并且与阳极和阴极接触。催化溶剂的电化学分解的阴极材料以其复合结构的形式存在，其中金属屏幕在其两侧用阴极材料涂覆。屏幕是如此定位，使得其端部处的尖锐的尖峰切入罐的壁中，从而保持正的电气和结构接触。本发明特别涉及使用复合阴极结构在扁平的钮扣式电池中，因为使用预制阴极复合盘来组装这种电池是容易的。

3. 发明授权

US3907588A Electrochemical cell and safety resistor therefor 失效
标题翻译：电化学电池及其安全电阻器
公开(公告)号：US3907588A
公开(公告)日：1975-09-23
申请号：US456070
申请日：1970-01-21
申请人： ESB INC
发明人： BERGUM BERNARD C
IPC分类号： H01M6/50 , H01M10/42 , H01M35/00
CPC分类号： H01M10/42 , H01M2200/00 , H01M2200/10
摘要： An electrochemical cell is disclosed having a resistive element interposed between a cell electrode and its corresponding terminal. The resistive element acts as a safety resistor and is a high resistivity material which has a high temperature coefficient of resistance. The element significantly lessens the high flash amperage current which is characteristic of some electrochemical cells, such as nickel-cadmium cells. The resistance of the element preferably has a value as determined in accordance with the equation:

WHERE Ra is the ohmic value of the element; E is the open circuit voltage of the cell; Ii is the initial flash current of the cell in the absence of the element; and Ip is the flash current of the cell with the element present in the cell.
摘要翻译：公开了一种电化学电池，其具有介于电池电极和其相应端子之间的电阻元件。电阻元件充当安全电阻器，并且是具有高电阻温度系数的高电阻率材料。该元素显着降低了一些电化学电池如镍镉电池的特征的高闪电安培电流。元素的电阻优选具有根据以下等式确定的值：E E Ra = - Ip Ii WHERE Ra是元素的欧姆值; E是电池的开路电压; Ii是在没有元素的情况下电池的初始闪电电流; 并且Ip是具有存在于单元中的元件的单元的闪光电流。

4. 发明授权

US3905828A Electrolytic processes and electrodes therefor 失效
标题翻译：电解过程和电极
公开(公告)号：US3905828A
公开(公告)日：1975-09-16
申请号：US43634874
申请日：1974-01-24
申请人： IMP METAL IND KYNOCH LTD
发明人： BARBER ANTHONY CLIFFORD
IPC分类号： B21C23/22 , B32B15/01 , C23F13/00 , C25B11/04 , C25B11/10 , H01M4/64 , H01M35/00
CPC分类号： C25B11/04 , B21C23/22 , C25B11/0473 , H01M4/64 , Y10T29/49115 , Y10T428/1259 , Y10T428/12743 , Y10T428/12778 , Y10T428/12875 , Y10T428/1291 , Y10T428/12924 , Y10T428/12931
摘要： A method of forming a composite body comprising an elongate body of a film-forming metal such as titanium surrounded by a sheath of a precious metal which comprises the steps of forming an assembly of the two materials, surrounding the same with a sleeve of a solid deformable protection and lubrication material and extruding the assembly to produce the elongate body. The assembly may have a core of high conductivity metal and may be formed into electrodes for use in electrolytic cells such as electro-winning etc.
摘要翻译：一种形成复合体的方法，该复合体包括成膜金属的细长体，例如由贵金属的护套围绕的钛，该方法包括以下步骤：形成两个材料的组合，可变形保护和润滑材料，并挤出组件以产生细长体。组件可以具有高导电性金属的芯，并且可以形成用于电解池中的电极，例如电击等。

5. 发明授权

US3859134A Unformed electrode plates for lead storage batteries 失效
标题翻译：用于铅蓄电池的电气电极板
公开(公告)号：US3859134A
公开(公告)日：1975-01-07
申请号：US37213373
申请日：1973-06-21
申请人： VARTA BATTERIE
发明人： SHIRODKER ROGUNATA
IPC分类号： H01M4/14 , H01M4/22 , H01M35/00
CPC分类号： H01M4/14
摘要： In the process of ''''forming'''' storage battery electrode plates, the plate lugs are at least partly coated, prior to forming, with a thermoplastic, acid resistant, adherent material. The coating prevents the oxidation of lugs during the process of formation, thus eliminating the need of cleaning and flux treatment during the assembly of plates into elements.
摘要翻译：在“形成”蓄电池电极板的过程中，板形凸起在成形之前至少部分地涂覆有热塑性的耐酸粘附材料。该涂层防止在形成过程中凸耳的氧化，从而消除了在将板组装成元件期间清洁和焊剂处理的需要。

6. 发明授权

US3839088A Apparatus for spirally winding components of an electrolytic cell 失效
标题翻译：用于电解槽的螺旋卷绕组件的装置
公开(公告)号：US3839088A
公开(公告)日：1974-10-01
申请号：US32631373
申请日：1973-01-24
申请人： GATES RUBBER CO
发明人： HUG L , STARK R , GROSSMAN P , YOUNG R
IPC分类号： H01M10/04 , H01M35/00
CPC分类号： H01M10/0409
摘要： An electrolytic cell pack consisting for instance of opposite polarity electrodes and alternate interposed separator is spirally wound by (a) attaching a thin flexible leader tab having a folded end to the cell pack, (b) curling the folded end of the leader tab in a spiral manner, (C) bringing a winding mandrel next to the thus formed curl and rotating the mandrel in the direction of the curled tab to thereby uncurl the leader tab and engage its folded end into a peripheral receiving portion of the mandrel, and (d) further rotating the mandrel to form the spiral wound cell pack. The described winding method is particularly suitable for spirally winding under firm stack pressure relatively small diameter cell packs such as may be required in rechargeable alkaline battery cells. The stack pressure achieved by the winding method is maintained by inserting a retainer in the axial void of the cell pack.
摘要翻译：通过（a）将具有折叠端的薄柔性引导片附接到电池组上，（b）将引导片的折叠端卷曲成一个螺旋状缠绕的电解电池组，例如由相反极性电极和交替插入的隔片组成（C）将卷绕的心轴放置在如此形成的卷曲的旁边，并使卷轴在卷曲翼片的方向上旋转，从而使引导片不折叠并将其折叠端接合到心轴的周边接收部分中，并且（d ）进一步旋转心轴以形成螺旋缠绕电池组件。所描述的绕组方法特别适用于在可堆叠的压力下螺旋缠绕相对较小直径的电池组件，例如可充电碱性电池单元中可能需要的。通过将保持器插入电池组的轴向空隙中来维持通过卷绕方法获得的堆叠压力。

7. 发明授权

US3833421A Secondary electrochemical cells with a chalcogen cathode 失效
标题翻译：具有螯合阴离子的二次电化学电池
公开(公告)号：US3833421A
公开(公告)日：1974-09-03
申请号：US31880672
申请日：1972-12-27
申请人： ATOMIC ENERGY COMMISSION
发明人： RUBISCHKO R , CAIRNS E , STEUNENBERG R
IPC分类号： H01M10/39 , H01M35/00
CPC分类号： H01M10/399
摘要： This invention consists of a novel cathode, and a novel method for making such cathode, for use in a secondary electrochemical power-producing cell having an anode containing a molten alkalimetal of low electronegativity, an electrolyte containing alkalimetal ions, and a cathode containing a reactant comprising a chalcogen. The cathode comprises a solid, porous substrate structure, impregnable by the reactant, having interconnected pores. These interconnected pores have their interior surfaces partially coated with a layer of electronically-conducting metal wettable by the electrolyte and are filled with both the electrolyte and the chalcogen-containing reactant. The novel method for making this cathode structure comprises vapor depositing the electronically-conducting metal onto the surfaces of the interconnected pores by vaporizing a volatile compound containing the metal in the presence of an inert gas, and then passing the resulting vapor-inert gas mixture through the porous substrate structure while also passing an electric current therethrough. This structure is then impregnated with both electrolyte and a chalcogen-containing reactant.
摘要翻译：本发明包括一种新颖的阴极和用于制造这种阴极的新方法，用于具有含有低电负性的熔融碱金属的阳极的二次电化学发电电池，含碱金属离子的电解质和含有含有硫属元素的反应物的阴极。阴极包括由反应物浸渍的具有互连孔的固体多孔基底结构。这些相互连通的孔的内表面部分涂覆有可由电解质润湿的电子导电金属层，并且填充有电解质和含硫属元素的反应物。用于制造该阴极结构的新颖方法包括通过在惰性气体存在下蒸发含有金属的挥发性化合物，然后使所得到的蒸汽惰性气体混合物通过，将电子导电金属气相沉积在互连孔的表面上多孔基底结构同时也使电流通过。然后用电解质和含硫属化合物的反应物浸渍该结构。

8. 发明授权

US3765943A Fabrication of lead-acid batteries 失效
标题翻译：铅酸蓄电池的制造
公开(公告)号：US3765943A
公开(公告)日：1973-10-16
申请号：US3765943D
申请日：1970-12-09
申请人： BELL TELEPHONE LABOR INC
发明人： BIAGETTI R
IPC分类号： H01M4/20 , H01M35/00
CPC分类号： H01M4/20
摘要： Lead-acid batteries utilizing positive electrodes prepared from specific starting ingredients under critically specified conditions show improved properties in use. Such positive electrodes are prepared by oxidation of tetrabasic lead sulfate (4PbO.PbSO4) which in turn is prepared in accordance with certain critically specified steps. Improved properties include increased product yield, greater life, greater reproducibility in the chemical and physical properties of the product and a crystal morphology more suitable to battery operation.
摘要翻译：利用在特定条件下由特定起始成分制备的正极的铅酸电池在使用中显示出改进的性能。这样的正电极是通过四氧化硫酸铅（4PbO.PbSO 4）的氧化制备的，其依次按照某些特定的步骤制备。改进的性能包括提高产品产量，延长使用寿命，在产品的化学和物理性能方面具有更高的再现性，以及更适合于电池操作的晶体形态。

9. 发明授权

US3645792A Electrical energy storage device utilizing current collector having anisotropic electricl properties 失效
标题翻译：使用具有各向异性电气特性的电流收集器的电力储存装置
公开(公告)号：US3645792A
公开(公告)日：1972-02-29
申请号：US3645792D
申请日：1969-03-20
申请人： STANDARD OIL CO OHIO
发明人： HACHA THOMAS H
IPC分类号： H01M6/20 , H01M2/16 , H01M10/39 , H01M35/00
CPC分类号： H01M10/399 , H01M2/0285 , H01M2/1613 , H01M4/382 , H01M4/463 , H01M4/583 , H01M10/39 , H01M2300/0054
摘要： An electrical energy storage device is provided which has a pair of spaced aluminum-lithium alloy anodes with an active carbon cathode interposed therebetween and the anodes and cathodes are separated by an inert spacer material containing a fused salt electrolyte. This device is assembled by enclosing the cathode in a fiber mat, which functions as the spacer, positioning the cathode in a screen basket, closing the basket to contain the cathode, inserting the screen basket into a container, positioning an anode within the container on each side of the screen basket, and hermetically sealing said container.
摘要翻译：提供了一种电存储装置，其具有一对隔开的铝 - 锂合金阳极，其间插入有活性炭阴极，阳极和阴极由含有熔融盐电解质的惰性间隔物分开。

10. 发明授权

US3640770A Rechargeable metal halide battery 失效
标题翻译：可充电的金属卤化物电池
公开(公告)号：US3640770A
公开(公告)日：1972-02-08
申请号：US3640770D
申请日：1969-10-20
申请人： ZITO CO
发明人： ZITO RALPH JR
IPC分类号： H01M10/36 , H01M12/08 , H01M35/00
CPC分类号： H01M10/365
摘要： A rechargeable metal halide battery, in which a salt of an electroplatable metal and a halogen selected from the class consisting of chlorine, bromine and iodine is electrolyzed from solution in a liquid medium during the charging cycle and reformed during the discharging cycle, the battery comprising at least one electrode comprising an electrically conductive corrodible element and a barrier layer along one side of the corrodible element, the barrier layer being substantially inert and impermeable to halogen in concentrations present in the battery, substantially impermeable to the liquid medium, and having a volume resistivity, Rho , such that Rho d is not greater than about 0.1 ohm-in.2, where d is the thickness of the barrier layer, the electrode having a total interface resistance, per square inch of electrolyte-contacting surface, not greater than about 0.05 ohms.
摘要翻译：一种可再充电金属卤化物电池，其中可电镀金属的盐和选自氯，溴和碘的卤素的盐在充电循环期间由液体介质中的溶液电解并在放电循环期间重整，所述电池包括至少一个电极，其包括沿着可腐蚀元件的一侧的导电可腐蚀元件和阻挡层，所述阻挡层基本上是惰性的，并且对于存在于电池中的浓度基本上不可渗透，液体介质基本上不可渗透，并且具有体积电阻率rho，使得rho不大于约0.1ohm-in.2，其中d是阻挡层的厚度，电极具有每平方英寸的电解质接触表面的总界面电阻，不大于约0.05欧姆。

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