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1. 发明申请

US20030029088A1 Process for converting coal into fuel cell quality hydrogen and sequestration-ready carbon dioxide 失效
公开(公告)号：US20030029088A1
公开(公告)日：2003-02-13
申请号：US09917801
申请日：2001-07-31
发明人： Richard K. Lyon
IPC分类号： C01B003/02 , C10J003/68
CPC分类号： C10J3/725 , B01J8/0055 , B01J8/26 , B01J8/388 , B01J2208/00292 , B01J2208/00513 , B01J2208/025 , C01B3/56 , C01B2203/0425 , C01B2203/0475 , C10J3/463 , C10J3/56 , C10J2300/093 , C10J2300/0956 , C10J2300/0983 , C10J2300/0996 , C10J2300/16 , C10J2300/1646 , F23C2900/99008 , Y02C10/08 , Y02E20/346 , Y02P30/30
摘要： A process for burning coal to produce substantially pure hydrogen for use in fuel cells, together with nullsequestration readynull carbon dioxide and a stream of oxygen depleted air for powering gas turbines, characterized by using a combination of two fluidized bed reactors and a third transfer line reactor, the first reactor being supplied with coal particles or nullcharnull and fluidized with high temperature steam; the second reactor being fluidized with high temperature steam and the third reactor being fluidized by compressed air. Solids circulated among these three reactors include a mixture of materials containing calcium compounds (present as CaO, CaCO3 and mixtures thereof) and iron compounds (present as FeO, Fe2O3 and mixtures thereof). The coal is gasified by the steam in the presence of CaO to produce CaCO3 and relatively pure hydrogen for use in fuel cells per a CO2 acceptor process. Because only part of the coal char input to the first reactor is gasified to produce hydrogen, the remainder can be burned to supply thermal energy necessary to regenerate the CaCO3 back to CaO. Carbon in the middle bed fluidized bed reactor reacts with Fe2O3 in the third reactor and the temperature in the middle fluidized bed reactor is sufficiently high to decompose CaCO3 back into CaO.

2. 发明申请

US20040182003A1 Multi-stage facility and method for gasifying a feedstock including organic matter 有权
标题翻译：用于气化包括有机物质的原料的多级设备和方法
公开(公告)号：US20040182003A1
公开(公告)日：2004-09-23
申请号：US10784235
申请日：2004-02-24
发明人： Jerome Bayle , Eric Marty
IPC分类号： C10J003/20 , C10B001/00 , C10J003/68
CPC分类号： C10J3/482 , B09C1/06 , C10J3/463 , C10J3/466 , C10J3/485 , C10J3/721 , C10J2300/0966 , C10J2300/0969 , C10J2300/0973 , C10J2300/0983 , F23G5/0276 , F23G5/30 , F23G2203/503 , Y02E20/12 , Y02P20/145
摘要： Facility for producing synthesis gas from a solid feedstock including organic matter, said facility including means for circulating a heat-carrying solid providing the heat necessary for such production, and several stages including gasification means (Z1, Z3), intermediate separation means (Z2, Z4) for separating the effluents coming from each stage, and combustion means (Z5).
摘要翻译：用于从包括有机物质的固体原料生产合成气的设备，所述设备包括用于循环提供这种生产所需的热量的传热固体的装置，以及包括气化装置（Z1，Z3），中间分离装置（Z2， Z4），用于分离来自各级的废气和燃烧装置（Z5）。

3. 发明申请

US20020029522A1 Hydrogen-rich gas supply device for fuel cell 有权
标题翻译：用于燃料电池的富氢气体供应装置
公开(公告)号：US20020029522A1
公开(公告)日：2002-03-14
申请号：US09949880
申请日：2001-09-12
申请人： NISSAN MOTOR CO., LTD.
发明人： Mitsutaka Abe
IPC分类号： B01J008/02 , B01J008/00 , B01J007/00 , C10J003/68
CPC分类号： H01M8/0625 , B01J19/0013 , B01J2219/00063 , B01J2219/00191 , B01J2219/002 , B01J2219/00213 , B01J2219/00225 , B01J2219/00231 , C01B3/323 , C01B3/583 , C01B2203/0227 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/1276 , C01B2203/1604 , C01B2203/1619 , C01B2203/169 , H01M8/04097 , H01M8/0662
摘要： To generate hydrogen-rich gas which is supplied to a fuel cell stack (2) of a fuel cell power plant, a reformer (1) generates reformate gas comprising hydrogen from methanol, and a carbon monoxide oxidizer (3) oxidizes carbon monoxide from the reformate gas by an action of a catalyst incorporated therein. A valve (10) which supplies hot gas, and a valve (18) which supplies air are provided. When the catalyst temperature is lower than a predetermined temperature, hot gas is supplied from the valve (10) to the oxidizer (3). Due to the heat of oxidation of carbon monoxide by the air supplied by the valve (18) and the high temperature of the hot gas, the temperature of the catalyst rises rapidly after start-up of the power plant.
摘要翻译：为了产生供应到燃料电池发电厂的燃料电池堆（2）的富氢气体，重整器（1）从甲醇生成包含氢的重整气体，一氧化碳氧化器（3）从一氧化碳通过并入其中的催化剂的作用重新制备气体。提供供给热气体的阀（10）和供给空气的阀（18）。当催化剂温度低于预定温度时，从气门（10）向氧化器（3）供给热气。由于由阀（18）供应的空气和热气体的高温使一氧化碳氧化的热量，催化剂的温度在发电厂启动后迅速上升。

4. 发明申请

US20040107638A1 Apparatus and method for gasifying solid organic materials 有权
标题翻译：用于气化固体有机材料的装置和方法
公开(公告)号：US20040107638A1
公开(公告)日：2004-06-10
申请号：US10704095
申请日：2003-11-07
申请人： Nexterra Energy Corporation
发明人： Robert G. Graham , Jan Barynin
IPC分类号： C10J003/68 , B01J003/00
CPC分类号： C10J3/723 , C10J3/30 , C10J3/34 , C10J2200/09 , C10J2200/15 , C10J2200/158 , C10J2300/0916 , C10J2300/0946 , C10J2300/1687 , C10J2300/1693 , Y02P20/124
摘要： An apparatus and method for starved air gasification of solid organic materials, including biomass and other wastes, to convert the chemical energy stored in such materials to thermal energy or gaseous products that may be used in biochemical and/or chemical synthesis. Specifically, the system utilizes a gasifier having a nullmoving bed of ashnull hearth wherein the feedstock is partially oxidized at a low temperature (less than 1500 degrees F.) in a square or rectangular chamber having a vaulted, tapered or flat roof. Combustion gases from the gasifier are held at temperature using a recovery and regeneration chamber, and then undergo secondary oxidation in an oxidizer. The high temperature gases produced by the system can be utilized to advantage, for example, as the thermal energy source for a conventional heat recovery device such as a heat exchanger, steam generator, hot oil or air heater, or steam boiler.
摘要翻译：一种用于固体有机材料（包括生物质和其他废物）的饥饿空气气化的装置和方法，用于将储存在这些材料中的化学能转化成可用于生物化学和/或化学合成的热能或气态产物。具体地说，该系统利用具有“灰床移动床”的气化器，其中原料在具有拱顶，锥形或平坦屋顶的正方形或矩形室中在低温（小于1500华氏度）下被部分氧化。来自气化器的燃烧气体使用回收和再生室保持温度，然后在氧化器中进行二次氧化。由系统产生的高温气体可以用于例如用作常规热回收装置如热交换器，蒸汽发生器，热油或空气加热器或蒸汽锅炉的热能源。

5. 发明申请

US20020059753A1 Fuel reforming system and stopping method thereof 有权
标题翻译：燃料重整系统及其停止方法
公开(公告)号：US20020059753A1
公开(公告)日：2002-05-23
申请号：US09984701
申请日：2001-10-31
申请人： NISSAN MOTOR CO., LTD.
发明人： Hiroyuki Ichikawa
IPC分类号： C10J003/68 , B01J007/00 , C10J001/20 , C10K003/06
CPC分类号： H01M8/0612 , H01M2250/20 , Y02T90/32
摘要： When a fuel reforming system for a fuel cell comprising an autothermal reformer 1 wherein a partial oxidation reaction and steam reforming reaction proceeds simultaneously, is stopped, firstly, a supply valve 6 is closed to stop supply of fuel and water for steam reforming, and a supply valve 7 is closed after a predetermined time has elapsed to stop supply of air. In this way, the partial oxidation reaction which is an exothermic reaction is continued temporarily and the catalyst layer temperature of the reformer 1 is raised, so the catalyst layer temperature can be maintained high until the system restarts, and the time required for restarting the system can be shortened.
摘要翻译：当包括部分氧化反应和蒸汽重整反应同时进行的包括自热重整器1的燃料电池的燃料重整系统停止时，首先关闭供给阀6以停止用于蒸汽重整的燃料和水的供应，供给阀7在经过预定时间后关闭以停止供应空气。以这种方式，暂时继续进行放热反应的部分氧化反应，提高重整器1的催化剂层温度，因此催化剂层温度可以保持较高，直到系统重新开始，重新启动系统所需的时间可以缩短。

6. 发明申请

US20010047620A1 Reforming apparatus 失效
标题翻译：重整设备
公开(公告)号：US20010047620A1
公开(公告)日：2001-12-06
申请号：US09864230
申请日：2001-05-25
申请人： NISSAN MOTOR CO., LTD.
发明人： Hiroyuki Ichikawa , Fuminori Yamanashi , Masakazu Hanawa
IPC分类号： C10J003/68 , C10J001/00
CPC分类号： B01J8/0492 , B01J8/0438 , B01J8/0496 , B01J19/0013 , B01J2208/00061 , B01J2208/0053 , B01J2208/00716 , B01J2219/002 , B01J2219/00213 , B01J2219/0022 , B01J2219/00231 , B01J2219/182 , C01B3/38 , C01B3/382 , C01B3/386 , C01B3/48 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/066 , C01B2203/0844 , C01B2203/1064 , C01B2203/1076 , C01B2203/1223 , C01B2203/142 , C01B2203/1604 , C01B2203/1619 , C01B2203/169 , C01B2203/82
摘要： A fuel reforming apparatus quickly heats the temperature of a catalyst to an activation temperature to shorten a startup time. The apparatus supplies a hydrocarbon fuel and an oxidizer upstream from a second catalyst (2 ), and steam upstream from a first catalyst (1 ). The second catalyst starts a rapid oxidation reaction to generate a high-temperature gas which heats the first catalyst. When the apparatus changes a startup operation or an accelerating operation to a steady operation after a predetermined period, the apparatus supplies the hydrocarbon fuel and steam upstream from the second catalyst, and the oxidizer upstream from the first catalyst. As a result, the second catalyst starts a steam reforming reaction to absorb heat from the second catalyst. And the second catalyst rapidly cools to stop reactions and pass the hydrocarbon fuel and steam with out reactions. Then, a hydrogen-rich reformed gas is generated from the passed hydrocarbon fuel and steam.
摘要翻译：燃料重整装置将催化剂的温度快速加热到活化温度以缩短启动时间。该装置在第二催化剂（2）的上游供应烃燃料和氧化剂，并在第一催化剂（1）的上游提供蒸汽。第二催化剂开始快速氧化反应以产生加热第一催化剂的高温气体。当设备在预定时间段之后将启动操作或加速操作改变为稳定操作时，设备将第二催化剂上游的烃燃料和蒸汽以及第一催化剂上游的氧化剂供应。结果，第二催化剂开始蒸汽重整反应以吸收来自第二催化剂的热量。并且第二催化剂快速冷却以停止反应并将烃燃料和蒸汽通过反应。然后，从通过的烃燃料和蒸汽产生富氢重整气体。

7. 发明申请

US20040261316A1 Pressurized coal gasification fuel distribution, feed, and burner system 审中-公开
标题翻译：加压煤气化燃料分配，进料和燃烧器系统
公开(公告)号：US20040261316A1
公开(公告)日：2004-12-30
申请号：US10827906
申请日：2004-04-20
发明人： Lloyd E. Weaver
IPC分类号： C10J003/68 , C10J001/00 , F27B005/00
CPC分类号： C10J3/78 , C10J3/32 , C10J3/34 , C10J3/723 , C10J2200/09 , C10J2200/152 , C10J2300/0973 , C10J2300/1223 , Y02E20/18
摘要： A PCPG (Pulverized Coal Pressurized Gasifier) including improved fuel distribution means among burners, better burner feeding, enhanced flame retention burner, and improved process control. The flame retention burner has a both a rapidly spinning air flow to create a tornado effect plus a Coanda effect from the swirled air causing traverse eddies into the burning air/fuel mixture and induced circulation eddies of hot gas to prolong exposure of coal particles to hot flame conditions near the ignition area to achieve increased multiple chances to mate air with coal particles. This burner coupled to individualized fuel feed and precise measurements and controls and two-stage PCPG entrained flow and ash bed reactor spaces minimizes carbon in the ash and maximizes gas-making efficiency.

8. 发明申请

US20040244289A1 Process for reforming inflammable gas, apparatus for reforming inflammable gas and gasification apparatus 审中-公开
标题翻译：易燃气体重整方法，易燃气体重整装置和气化装置
公开(公告)号：US20040244289A1
公开(公告)日：2004-12-09
申请号：US10491156
申请日：2004-03-26
发明人： Fumiaki Morozumi , Katsutoshi Naruse , Kaori Sasaki , Yuki Iwadate
IPC分类号： C10J003/68 , F27B005/00
CPC分类号： C10J3/463 , C01B3/323 , C01B3/34 , C01B2203/0227 , C01B2203/10 , C01B2203/1258 , C10J3/02 , C10J2300/0916 , C10J2300/093 , C10J2300/0946 , C10J2300/0969 , C10J2300/0973 , C10J2300/0983 , C10J2300/1606 , C10J2300/1637 , C10J2300/165 , C10J2300/1671 , C10J2300/1675 , C10J2300/1807 , C10J2300/1853 , C10K3/006 , C10K3/023 , Y02P20/129 , Y02P20/584
摘要： The present invention relates to a combustible gas reforming method, a combustible gas reforming apparatus, and a gasification apparatus for gasifying a combustible material such as coal, biomass, municipal wastes, industrial wastes, RDF (refuse-derived fuel), waste plastics, and the like, and reforming a generated combustible gas. According to a combustible gas reforming method of the present invention, combustibles are gasified in a gasification apparatus (11), a generated gas (GA) produced by gasifying the combustibles is reformed in a gas reforming apparatus (12) using a catalyst to produce a product gas (GB), and a catalyst (CAnull) degraded by the gas reforming apparatus (11) is regenerated in a catalyst regenerating apparatus (13). Waste heat (TP) of the combustible gas reforming process is used as heat to regenerate the catalyst in the catalyst regenerating apparatus (13).
摘要翻译：本发明涉及可燃气体重整方法，可燃气体重整装置和用于气化诸如煤，生物质，城市废物，工业废物，RDF（垃圾衍生燃料），废塑料和并且对所产生的可燃气体进行重整。根据本发明的可燃性气体重整方法，在气化装置（11）中将可燃物气化，在气体重整装置（12）中使用催化剂将产生气化的可燃物气体（GA）重整生成气体在气体重整装置（11）中降解的产物气体（GB）和催化剂（CA'）在催化剂再生装置（13）中再生。可燃气体重整工艺的余热（TP）用作催化剂再生装置（13）中的催化剂再生热。

9. 发明申请

US20040231243A1 Ash fusing system, method of operating the system, and gasification fusing system for waste 失效
标题翻译：灰熔系统，操作方法，废气气化融化系统
公开(公告)号：US20040231243A1
公开(公告)日：2004-11-25
申请号：US10485272
申请日：2004-01-30
发明人： Chikao Goke , Nobuya Azuma , Masaaki Irie , Kazuo Takano , Tetsuhisa Hirose , Kazuaki Watanabe
IPC分类号： C10J003/00 , C10J003/68 , C10B001/00
CPC分类号： C10J3/487 , C10J3/526 , C10J3/80 , C10J3/84 , C10J2300/1625 , C10K3/023 , F23G5/027 , F23G5/0276 , F23G5/16 , F23G5/50 , F23G2202/103 , F23G2202/104 , F23G2207/101 , F23G2207/113 , F23G2900/00001 , F23G2900/50004 , F23G2900/55006 , F23J1/06 , F23J1/08 , F23J2900/01004 , F23J2900/01005
摘要： An ash melting system of the present invention includes a slagging combustion furnace (10) for melting ash into molten slag; and a slag separating apparatus (50) for bringing the molten slag (121) discharged from the slagging combustion furnace into contact with slag cooling water (152) to produce water-quenched slag (122), and separating the water-quenched slag from the slag cooling water. The ash melting system further includes a gas blowing means for blowing air or inert gas (132) between a slag discharge port (14) of the slagging combustion furnace and the surface of the slag cooling water.
摘要翻译：本发明的灰熔系统包括用于将灰分熔化成熔渣的成渣燃烧炉（10）以及用于使从排渣燃烧炉排出的熔渣（121）与炉渣冷却水（152）接触以产生水淬渣（122）的渣分离装置（50），并且将水淬火渣从炉渣冷却水。灰熔体系还包括用于在排渣燃烧炉的排渣口（14）和炉渣冷却水的表面之间吹送空气或惰性气体（132）的气体吹送装置。

10. 发明申请

US20020031690A1 Fuel reforming apparatus 失效
标题翻译：燃料重整装置
公开(公告)号：US20020031690A1
公开(公告)日：2002-03-14
申请号：US09930989
申请日：2001-08-17
申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA
发明人： Takashi Shimazu , Satoshi Iguchi , Satoshi Aoyama , Koichi Numata , Kazuhisa Kunitake , Takeshi Nishikawa , Shuichi Kubo , Satoshi Yamazaki
IPC分类号： H01M008/06 , B01J007/00 , C10J003/68
CPC分类号： H01M8/0612 , B01B1/005 , B01J19/0006 , B01J19/0013 , B01J19/0026 , B01J19/088 , B01J19/2485 , B01J19/26 , B01J2208/00716 , B01J2219/00006 , B01J2219/00063 , B01J2219/00087 , B01J2219/00117 , B01J2219/00123 , B01J2219/00157 , B01J2219/00159 , B01J2219/00162 , B01J2219/00164 , B01J2219/00166 , B01J2219/00186 , B01J2219/00198 , B01J2219/00211 , B01J2219/00216 , B01J2219/00218 , B01J2219/00231 , B01J2219/00236 , B01J2219/00247 , B01J2219/0896 , B01J2219/182 , B01J2219/1943 , C01B3/38 , C01B3/382 , C01B3/48 , C01B3/583 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0277 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0805 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0844 , C01B2203/0861 , C01B2203/0866 , C01B2203/0877 , C01B2203/0883 , C01B2203/0894 , C01B2203/1041 , C01B2203/1047 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1247 , C01B2203/127 , C01B2203/1282 , C01B2203/1288 , C01B2203/142 , C01B2203/143 , C01B2203/148 , C01B2203/16 , C01B2203/1604 , C01B2203/1614 , C01B2203/1628 , C01B2203/1657 , C01B2203/1685 , C01B2203/169 , C01B2203/1695 , C01B2203/80 , C01B2203/82 , F01N2240/30 , H01M8/04223 , H01M8/04302 , H01M8/241 , H01M8/2457 , Y02P20/128
摘要： In a fuel cell system 10, a cracking unit 20 is provided upstream of a reformer 36. When the cracking unit 20 is supplied with oxygen and gasoline as a hydrocarbon-based fuel, the gasoline is partially oxidized and decomposed using oxidation-generated heat to give a hydrocarbon with a lower carbon number. The hydrocarbon with the lower carbon number obtained by such gasoline pyrolysis is fed to the reformer 36 and supplied to a reforming reaction zone.
摘要翻译：在燃料电池系统10中，在重整器36的上游设置有裂解装置20.当以裂解装置20供给作为烃类燃料的氧气和汽油时，汽油被氧化生成的热量部分氧化分解，得到碳数较少的烃。通过这种汽油热分解获得的具有较低碳原子数的烃被供给至重整器36并供给至重整反应区。

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