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1. 发明授权

US3576909A Catalyzed isomerization of alpha-beta unsaturated carboxylic acid esters 失效
标题翻译： ALPHA-BETA不饱和羧酸酯的催化异构化
公开(公告)号：US3576909A
公开(公告)日：1971-04-27
申请号：US3576909D
申请日：1968-01-19
申请人： GEN TIRE & RUBBER CO
发明人： SCHMIDLE CLAUDE J , SCHMUCKER ARDEN E
IPC分类号： C08G63/58 , C08F1/76 , C08F21/02 , C08F27/00
CPC分类号： C08G63/58
摘要： MORPHOLINE OR ITS ALKYL DERIVATIVES ARE USED AS CATALYSTS FOR THE ISOMERIZATION OF A-B UNSATURATED ESTERS OF CISCONFIGURATION INTO TRANS-CONFIGERATION. THE ISOMERIZATION MAY PROCEED AT LOW TEMPERATURES WITH GOOD YIELDS AND IS USEFUL FOR PRODUCTION OF FIBER REINFORCED PLASTIC LAMINATION RESINS FROM MALEIC ANHYDRIDE VIA MALERATE POLYESTERS, WHICH ARE THEN ISOMERIZED TO FUMARATE POLYESTERS.

2. 发明授权

US3505266A Process for the production of spinnable acrylonitrile polymer solutions 失效
标题翻译：用于生产可旋转丙烯腈聚合物溶液的方法
公开(公告)号：US3505266A
公开(公告)日：1970-04-07
申请号：US3505266D
申请日：1967-05-08
申请人： BAYER AG
发明人： SULING CARLHANS , KRAMER DIETER , UNBEHEND MANFRED
IPC分类号： C08F20/44 , D01F6/18 , C08F1/76 , C08F3/76
CPC分类号： D01F6/18 , C08F2/36 , C08F20/44
摘要： A solution of an acrylonitrile polymer is produced by polymerizing acrylonitrile in an organic solvent for polyacrylonitrile, at a temperature of from + 10 DEG to - 68 DEG C. in the presence of 0.1 m.mol. to 0.1 mol., per mol. of monomer, of an alkali metal salt of an aliphatic or cycloaliphatic sulphonamide of the formula wherein M represents Li, Na, K, Rb or Cs, R1 represents an alkyl or cycloalkyl radical and R2 represents an alkyl radical. Specified salts are those of N-methyl, N-isopropyl or N-isobutyl methane sulphonamide, N-methyl n-butane sulphonamide, N - n - propyl ethane sulphonamide, N-methyl cyclohexane sulphonamide and long-chain aliphatic sulphonamides. Suitable solvents are dimethyl formamide and dimethyl sulphoxide. In examples, dimethyl formamide solutions of polyacrylonitrile are produced using potassium N-methyl or N-isobutyl methane sulphonamide or lithium N-isobutyl or N-isopropyl sulphonamide. The catalyst is deactivated with HCl or toluene sulphonic acid.

3. 发明授权

US3763131A Synthetic wax process 失效
标题翻译：合成WAX工艺
公开(公告)号：US3763131A
公开(公告)日：1973-10-02
申请号：US3763131D
申请日：1970-10-30
申请人： EXXON RESEARCH ENGINEERING CO
发明人： LANGER A
IPC分类号： C07C2/04 , C08F10/00 , C08F212/04 , C08F1/76 , C08F3/06
CPC分类号： C08F212/04 , C07C2/04 , C07C2531/02 , C07C2531/12 , C08F10/00 , Y10S585/946 , C08F4/14
摘要： A NOVEL SYNTHETIC WAX PROCESS IN WHICH ETHYLENE IS REACTED WITH EITHER AN AROMATIC OR A HYDROCARBLY SUBSITUTED AROMATIC COMPOUND IN THE PRESENCE OF A CHELATED LIR CATALYST WHEREIN R IS A MONOVALENT HYDROCARBON RADICAL CONTAINING 1-20 CARBON ATOMS, SAID REACTION TAKING PLACE ALSO IN THE PRESENCE OF A SATRATED HYDROCARBON SOLVENT UNDER REACTION CONDITIONS TO OPTIMIZE THE ACTIVITY AND SELECTIVITY OF THE CATALYST TO FORM LINEAR WAX COMPOSITION HAVING A MOLECULAR WEIGHT RANGING BETWEEN 500 TO 5000. THIS PROCESS ALSO PROVIDES FOR NOVEL WAX COMPOSITION CONTAINING ALKYL CYCLOALKANE STRUCTURES IN ADDITION TO ALKYL AROMATIC TELOMER STRUCTURES.

4. 发明授权

US3609128A Method of producing nitrile polymers 失效
标题翻译：生产NITRILE聚合物的方法
公开(公告)号：US3609128A
公开(公告)日：1971-09-28
申请号：US3609128D
申请日：1969-10-24
申请人： MONSANTO RES CORP
发明人： JOHNS IRAL B
IPC分类号： C08G73/00 , C08F1/72 , C08F1/76 , C08F3/74
CPC分类号： C08G73/00
摘要： Method for producing polymers of nitriles, especially perfluoroglutaronitrile and acetonitrile, in the presence of catalytic materials such as, graphite, nickel chloride, metal cyanocoordination compounds, e.g., copper phthalocyanine, at elevated temperatures, and in some cases, elevated pressures.

5. 发明授权

US3579492A Method for preparing long chain alkyl compounds 失效
标题翻译：制备长链烷基化合物的方法
公开(公告)号：US3579492A
公开(公告)日：1971-05-18
申请号：US3579492D
申请日：1968-04-18
申请人： FOOTE MINERAL CO
发明人： SMITH WILLIAM NOVIS JR
IPC分类号： C08F10/00 , C08F1/76 , C08F3/06
CPC分类号： C08F10/00 , Y10S585/931 , Y10S585/935 , C08F4/14
摘要： ETHYLENE IS POLYMERIZED IN A SOLUTION OF AN N-BUTYLLITHIUM: N,N,N'',N''-TETRAMETHYLETHYLENE DIAMINE COMPLEX UNDER TEMPERATURE AND PRESSURE CONDITIONS SELECTED FROM A NARROW RANGE OF EACH UNTIL SUBSTANTIALLY ALL OF THE RESULTING POLYMER HAS PRECIPITATED FOR THE SOLUTION AS A LONG CHAIN N-ALKYLLITHIUM COMPOUND WHICH MAY BE CONVERTED TO THE CORRESPONDING POLYETHYLENE HAVING A MOLECULAR WEIGHT FROM ABOUT 1500 TO ABOUT 4000 WITH A MW/MN RATIO OF ABOUT 1.

6. 发明授权

US3536684A Copolymerization with azo catalyst of 2-phenyl allyl alcohol and styrene and solid copolymers thereof 失效
标题翻译：与丙烯酸和苯乙烯和固体共聚物的AZO催化剂的共聚合
公开(公告)号：US3536684A
公开(公告)日：1970-10-27
申请号：US3536684D
申请日：1967-04-04
申请人： SINCLAIR RESEARCH INC
发明人： VERDOL JOSEPH A , THIENOT MARC O
IPC分类号： C08F16/02 , C08F212/08 , C08F1/76 , C08F21/02
CPC分类号： C08F212/08 , C08F16/02

7. 发明授权

US3536679A Lithiated-amine polymerization catalyst 失效
标题翻译： LITHIATED-AMINE聚合催化剂
公开(公告)号：US3536679A
公开(公告)日：1970-10-27
申请号：US3536679D
申请日：1969-05-16
申请人： EXXON RESEARCH ENGINEERING CO
发明人： LANGER ARTHUR W JR
IPC分类号： C07F7/08 , C08C19/26 , C08F4/12 , C08F36/04 , C08G65/12 , C08G65/26 , C08D1/12 , C08F1/76 , C08F3/74
CPC分类号： C08G65/269 , C07F7/0827 , C08C19/26 , C08F4/12 , C08F36/04 , C08G65/12 , C08F4/484 , C08F4/48 , C08F4/44

8. 发明授权

US3629370A Process for the production of thermoplastic-elastic moulding compositions of high impact and notched impact strength 失效
标题翻译：生产具有高冲击强度和耐冲击强度的热塑性弹性模塑组合物的工艺
公开(公告)号：US3629370A
公开(公告)日：1971-12-21
申请号：US3629370D
申请日：1968-09-13
申请人： BAYER AG
发明人： OTT KARL-HEINZ , SCHUSTER HERBERT , DINGES KARL , ROHR HARRY
IPC分类号： C08F4/04 , C08F279/02 , C08F1/76 , C08F15/04
CPC分类号： C08F4/04 , C08F279/02 , C08F212/08 , C08F220/44 , C08F220/14 , C08F2/22
摘要： GRAFT COPOLYMERS OF A DIENE POLYMER AS A BASE AND A STYRENE TYPE AND AN ACRYLONITRILE TYPE MONOMER ARE PRODUCED WITH A WATER-SOLUBLE, ALIPHATIC AZO-COMPOUND AS A CATALYST.

9. 发明授权

US3433774A Polymerisation process 失效
公开(公告)号：US3433774A
公开(公告)日：1969-03-18
申请号：US3433774D
申请日：1965-10-23
申请人： ICI LTD
发明人： BAMFORD CLEMENT HENRY , DUNCAN FREDERIC JAMES , REYNOLDS REGINALD JOHN WILLIAM
IPC分类号： C08F2/00 , C08F4/06 , C08F291/00 , D06M14/00 , C08F1/76 , C08F1/64
CPC分类号： D06M14/00 , C08F4/06 , C08F291/00

10. 发明授权

US3431244A Production of polyacrylonitrile fibres 失效
标题翻译：聚丙烯腈纤维的生产
公开(公告)号：US3431244A
公开(公告)日：1969-03-04
申请号：US3431244D
申请日：1966-01-17
申请人： COURTAULDS LTD
发明人： BREALEY GRAHAM JOHN
IPC分类号： C08F20/44 , C08F1/30 , C08F1/76 , C08F3/76
CPC分类号： C08F20/44 , C08F2/04 , C08F2/16
摘要： Polyacrylonitrile fibres of improved colour are obtained by polymerizing acrylonitrile catalytically, in a solvent for polyacrylonitrile comprising an aqueous solution of an inorganic salt, at elevated temperature in the presence of a soluble titanium salt dissolved in the aqueous solvent, and spinning the polymerization product into fibres. The acrylonitrile may be copolymerized with a comonomer to produce a copolymer containing not less than 80% by weight of acrylonitrile units; specified comonomers are styrene, methyl acrylate or methacrylate, vinyl acetate, itaconic acid, acrylic acid, methallyl-sulphonic acid or a salt thereof, and mixtures of such comonomers. The inorganic salt component of the aqueous solvent is exemplified by sodium thiocyanate. A suitable titanium salt additive is potassium titanium oxalate. In examples, acrylonitrile is copolymerized with methyl acrylate and itaconic acid using, as catalyst, azobisisobutyronitrile in conjunction with thiourea dioxide and, in some cases, isopropanol is also present. Aqueous solvent used can be recycled for use in further acrylonitrile polymerizations without the need for purification.
摘要翻译：改性颜色的聚丙烯腈纤维是通过在溶解于含水溶剂中的可溶性钛盐存在下在升高的温度下在包含无机盐的水溶液的聚丙烯腈的溶剂中催化聚合而得到的，并将聚合产物纺丝成纤维。丙烯腈可以与共聚单体共聚以制备含有不少于80重量％的丙烯腈单元的共聚物; 指定的共聚单体是苯乙烯，丙烯酸甲酯或甲基丙烯酸甲酯，乙酸乙烯酯，衣康酸，丙烯酸，甲代烯丙基磺酸或其盐，以及这些共聚单体的混合物。水溶剂的无机盐成分的例子是硫氰酸钠。合适的钛盐添加剂是草酸钛钾。在实例中，丙烯腈与丙烯酸甲酯和衣康酸共聚，使用偶氮二异丁腈作为催化剂与二氧化硫脲结合，在某些情况下也存在异丙醇。所用的水溶剂可以再循环用于进一步的丙烯腈聚合，而不需要纯化。

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