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1. 发明授权

US3867439A Preparation of potassium benzoate 失效
标题翻译：苯甲酸钾的制备
公开(公告)号：US3867439A
公开(公告)日：1975-02-18
申请号：US24489872
申请日：1972-04-17
申请人： DOW CHEMICAL CO
发明人： HILLS DAVID J
IPC分类号： C07C51/41 , C07C63/02 , C07C63/08
CPC分类号： C07C51/412 , C07C63/08
摘要： Substantially pure potassium benzoate is obtained in high yield by reacting an aromatic hydrocarbon solution of benzoic acid such as that obtained from a toluene oxidation process with potassium hydroxide preferably in concentrated aqueous solution, thereby precipitating solid potassium benzoate.
摘要翻译：通过苯甲酸的芳族烃溶液如甲苯氧化法得到的苯甲酸溶液与氢氧化钾优选在浓缩的水溶液中反应，从而使固体苯甲酸钾沉淀，从而以高产率获得了基本上纯的苯甲酸钾。

2. 发明授权

US3816522A Catalytic oxidation of carbonyl compounds 失效
标题翻译：碳化合物的催化氧化
公开(公告)号：US3816522A
公开(公告)日：1974-06-11
申请号：US18681971
申请日：1971-10-05
申请人： MOBIL OIL CORP
发明人： GOLDSTEIN T
IPC分类号： C07C51/235 , C07C59/19 , C07C59/205 , C07C63/16 , C07C63/02
CPC分类号： C07C51/235 , C07C59/19 , C07C59/205 , C07C63/16
摘要： CARBONYL COMPOUNDS, INCLUDING ALDEHYDES, MAY BE OXIDIZED UNDER MILD REACTION CONDITIONS TO THE CORRESPONDDING CARBOXY COMPOUND BY CARRYING OUT THE REACTION IN THE PRESENCE OF A THIAZOLIUM COMPOUND OR CYANIDE IONS AS CATALYST FOR THE OXIDATION. THE REACTION MIXTURES PRODUCED BY THE METHOD OF THIS INVENTION ARE OF UTILITY.

3. 发明授权

US3781344A Process for manufacturing terephthalic acid by oxidation of paraxylene 失效
标题翻译：通过氧化邻苯二甲酸制备庚二酸的方法
公开(公告)号：US3781344A
公开(公告)日：1973-12-25
申请号：US3781344D
申请日：1972-05-01
申请人： INST FRANCAIS DU PETROLE
发明人： ALAGY J , BUSSON C
IPC分类号： C07C51/265 , C07C63/02
CPC分类号： C07C51/265 , C07C63/26
摘要： A PROCESS FOR MANUFACTURING TEREPHTHALIC ACID COMPRISES OCIDIZING PARA-XYLENE IN LIQUID PHASE, RECOVERING THE RESULTING TEREPHTHALIC ACID, CONCENTRATING THE RECOVERED LIQUID PHASE, WASHING THE SAME WITH WATER, SEPARATING THE SOLID BY-PRODUCTS FORM THE LIQUID PHASE AND RECYCLING THE LIQUID PHASE TO THE OXIDATION REACTOR. THE PROCESS MAY BE USED OVER LONG PERIODS WITHOUT A SUBSTANTIAL YIELD DECREASE.

4. 发明授权

US3708531A Promotion of the oxidation of mononuclear aromatic compounds 失效
公开(公告)号：US3708531A
公开(公告)日：1973-01-02
申请号：US3708531D
申请日：1971-06-02
申请人： PETRO TEX CHEM CORP
发明人： CORCE L , BARONE B
IPC分类号： C07C51/265 , C07C51/26 , C07C63/02
CPC分类号： C07C51/265
摘要： A process for the oxidation of mononuclear aromatic compounds having at least one oxidizable group selected from methyl, hydroxymethyl, and aldehyde, at moderate temperatures, and in the presence of oxygen, cobaltous or cobaltic ions, and an effective amount of a specified substituted acid function.

5. 发明授权

US3692828A Process for preparing phenyl sulfone carboxylic acids 失效
标题翻译：制备苯基硫代羧酸的方法
公开(公告)号：US3692828A
公开(公告)日：1972-09-19
申请号：US3692828D
申请日：1970-05-01
申请人： GULF RESEARCH DEVELOPMENT CO
发明人： ONOPCHENKO ANTOLI , SCHULZ JOHANN G D
IPC分类号： C07C315/04 , C07C317/44 , C07C63/02
CPC分类号： C07C315/04 , C07C317/44
摘要： A process for preparing phenyl sulfone carboxylic acids which involves contacting an alkyl phenyl sulfone with molecular oxygen while the same is dissolved in a lower carboxylic acid containing cobaltic ions.
摘要翻译：制备苯基砜羧酸的方法，其包括使烷基苯基砜与分子氧接触，同时溶解在含有钴离子的低级羧酸中。

6. 发明授权

US3683018A Integrated oxidation of isomeric xylene mixture to isomeric phthalic acid mixture and separation of mixture of isomeric phthalic acids into individual isomer products 失效
标题翻译：异构二甲苯混合物与异构酸混合物的一体化氧化和将异构酸性酸混合物分离到个体异构体产物中
公开(公告)号：US3683018A
公开(公告)日：1972-08-08
申请号：US3683018D
申请日：1969-05-26
申请人： STANDARD OIL CO
发明人： LONGLAND GEORGE M JR
IPC分类号： C07C51/265 , C07C51/43 , C07C51/42 , C07C51/44 , C07C63/02
CPC分类号： C07C51/43 , C07C51/265 , C07C63/24 , C07C63/26
摘要： Liquid phase oxidation of isomeric xylene mixture with molecular oxygen-containing gas (e.g. air or oxygen gas) in the presence of aqueous or acetic acid reaction media and catalysis provided by one or more heavy metals (metals of about 50 to about 200 atomic weight) or by a side-chain oxidation initiator or promotor (bromine source, or acetaldehyde or methylenic ketone) provides oxidation effluent containing mixture of isomeric phthalic acids for product crystallization and reaction media displacement from concentrate of said effluent by contact of the concentrate with water in a single step, preferably conducted with a vertical column of water, thereby producing aqueous acetic acid for feed to acetic acid recovery and recycle to oxidation and aqueous slurry of mixture of isomeric phthalic acids as feed for separation into individual phthalic acid isomer products. Isoand tere-phthalic acids in particular are separated from mixtures of the same by crystal size classification.
摘要翻译：在含水或乙酸反应介质和由一种或多种重金属（约50至约200原子量的金属）提供的催化作用的情况下，使用含分子氧气体（例如空气或氧气）的异构二甲苯混合物进行液相氧化，或通过侧链氧化引发剂或促进剂（溴源或乙醛或亚甲基酮）提供含有异构邻苯二甲酸混合物的氧化流出物，用于产物结晶，并且通过将浓缩物与水接触，从所述流出物的浓缩物中移出反应介质单步，优选用垂直的水柱进行，从而产生乙酸水溶液用于进料至乙酸回收并循环至氧化，并将异构邻苯二甲酸的混合物的含水浆液作为进料分离成单独的邻苯二甲酸异构体产物。异 - 邻苯二甲酸特别是通过晶体尺寸分类从其混合物中分离出来。

7. 发明授权

US3683017A Oxidation of p-xylene and p-tolujc acid to terephthalic acid 失效
标题翻译：对二甲苯和对羟基苯甲酸氧化成过硫酸
公开(公告)号：US3683017A
公开(公告)日：1972-08-08
申请号：US3683017D
申请日：1970-04-01
申请人： FMC CORP
发明人： AGER JOHN W JR
IPC分类号： C07C51/265 , C07C63/02
CPC分类号： C07C51/265 , C07C63/26
摘要： Terephthalic acid (TPA) is prepared by oxidizing p-xylene, ptoluic acid (PTA) or a mixture of the two, by reaction under pressure of at least 50 psig and at temperatures of about 140* to 250* C., carrying out the reaction in glacial acetic acid as the reaction medium, and using as catalyst cobalt chloride alone, or preferably a combination of cobalt or nickel with chromium and manganese salts, activated by chloride ion. Tungsten is an optional ingredient of the catalyst.
摘要翻译：对苯二甲酸（TPA）通过在至少50psig的压力和约140-250℃的温度下通过反应氧化对二甲苯，对甲苯甲酸（PTA）或二者的混合物来制备，携带在冰醋酸中作为反应介质反应，并且以氯化钴离子作为催化剂，单独使用氯化钴，或优选使用钴或镍与铬和锰盐的组合。钨是催化剂的任选成分。

8. 发明授权

US3678106A OXIDATION OF p-XYLENE AND p-TOLUIC ACID TO TEREPHTHALIC ACID IN AQUEOUS MEDIUM 失效
标题翻译：对二甲苯和对羟基酸在酸性介质中氧化成过敏酸
公开(公告)号：US3678106A
公开(公告)日：1972-07-18
申请号：US3678106D
申请日：1970-04-02
申请人： FMC CORP
发明人： AGER JOHN W
IPC分类号： C07C51/265 , C07C63/02
CPC分类号： C07C51/265 , C07C63/26
摘要： Terephthalic acid (TPA) is produced by the oxidation of p-xylene and/or p-toluic acid (PTA) with elemental oxygen in aqueous medium at elevated temperatures and pressures and in the absence of a conventional metal catalyst, using instead hydrogen bromide as catalyst, preferably together with small amounts of nitric acid. With p-xylene, active charcoal is additionally needed to insure adequate reaction.
摘要翻译：对苯二甲酸（TPA）通过在水介质中在高温和高压下以及在不存在常规金属催化剂的情况下用元素氧氧化对二甲苯和/或对甲苯甲酸（PTA）来制备，而不是使用溴化氢作为催化剂，优选与少量硝酸一起。使用对二甲苯，还需要活性炭来确保足够的反应。

9. 发明授权

US3674845A Method of producing aromatic carboxylic acids from alkylbenzenes 失效
标题翻译：从苯乙烯生产芳香羧酸的方法
公开(公告)号：US3674845A
公开(公告)日：1972-07-04
申请号：US3674845D
申请日：1970-06-30
申请人： SIR SOC ITALIANA RESINE SPA
发明人： RENI CESARE , GUALDI GIORGIO , LUGO LUIGI
IPC分类号： C07C51/265 , C07C63/02
CPC分类号： C07C51/265 , C07C63/26
摘要： A process for the continuous production of aromatic carboxylic acids by the oxidation of alkyl benzenes in an aliphatic carboxylic acid environment and in the presence of catalysts consisting of heavy metal salts in which an activator selected from chlorides and bromides of chloroacetic and bromoacetic acids is present in the reaction mixture.
摘要翻译：通过在脂族羧酸环境中氧化烷基苯并在由重金属盐组成的催化剂存在下连续生产芳族羧酸的方法，其中选自氯乙酸和氯乙酸和溴乙酸的溴化物的活化剂存在于反应混合物。

10. 发明授权

US3649682A Oxidation in the presence of saccharides 失效
标题翻译：。。。。。。。。。。。。
公开(公告)号：US3649682A
公开(公告)日：1972-03-14
申请号：US3649682D
申请日：1968-12-30
申请人： PETRO TEX CHEM CORP
发明人： BARONE BRUNO J
IPC分类号： C07C51/265 , C07C63/02
CPC分类号： C07C51/265
摘要： A PROCESS FOR THE OXIDATION OF MONONUCLEAR AROMATIC COMPOUNDS HAVING AT LEAST ONE OXIDIZABLE GROUP SELECTED FROM METHYL, HYDROXYMETHYL, AND ALDEHYDE, IN THE PRESENCE OF OXYGEN, COBALTOUS OR COBALTIC IONS AND AN ORGANIC REGULATOR OR ACTIVATOR SELECTED FROM THE CLASS COMPRISING MONOSACCHARIDES, DISACCHARIDES, TRIACCHARIDES, AND OTHER POLYSACCHARIDES WHICH YIELD THESE MATERIALS UNDER THE CONDITIONS OF THE SYSTEM, AND MIXTURES THEREOF, AT ABOUT 60* C. TO ABOUT 160*C., AND AT ATOMOSPHERIC PRESSURE OR GREATER.

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