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1. 发明授权

US06428762B1 Powder synthesis and characterization of amorphous carbon nitride, a-C3N4 失效
标题翻译：无定形碳氮化物a-C3N4的粉末合成与表征
公开(公告)号：US06428762B1
公开(公告)日：2002-08-06
申请号：US09626173
申请日：2000-07-27
申请人： Valery N. Khabashesku , John L. Margrave , John L. Zimmerman
发明人： Valery N. Khabashesku , John L. Margrave , John L. Zimmerman
IPC分类号： C01C300
CPC分类号： B82Y30/00 , C01B21/0605 , C01P2002/02 , C01P2002/72 , C01P2002/82 , C01P2002/84 , C01P2002/86 , C01P2002/88 , C01P2004/03 , C01P2004/64
摘要： Carbon nitride powder prepared by solid-state reaction between cyanuric chloride or its fluoro analogue and lithium nitride. The determined, by elemental analysis, atomic N/C ratio (1.33) in the synthesized material is consistent with C3N4 stoichiometry. Combined material characterization data, obtained by FTIR, Raman, UV-Vis, (13C) MAS NMR, XPS, TGA/DTA and pyrolysis-EIMS methods, provide substantial evidence for graphite-like sp2-bonded structure composed of building blocks of s-triazine rings bridged by the three-fold coordinated nitrogen atoms in the bulk carbon nitride.
摘要翻译：通过氰尿酰氯或其氟类似物与氮化锂之间的固态反应制备的氮化碳粉末。通过元素分析确定合成材料中的原子N / C比（1.33）与C3N4化学计量一致。通过FTIR，拉曼，UV-Vis，（13C）MAS NMR，XPS，TGA / DTA和热解-EIMS方法获得的组合材料表征数据为石墨样sp2结合结构提供了实质性证据，三氮环由本体碳氮化物中三重配位的氮原子桥连。

2. 发明授权

US06264905B1 Method and apparatus for reducing “ammonia slip” in SCR and/or SNCR NOX removal applications 失效
标题翻译：在SCR和/或SNCR NOX去除应用中减少“氨滑移”的方法和装置
公开(公告)号：US06264905B1
公开(公告)日：2001-07-24
申请号：US09416665
申请日：1999-10-12
申请人： Felix E. Spokoyny
发明人： Felix E. Spokoyny
IPC分类号： C01C300
CPC分类号： B01D53/79 , B01D53/56 , B01D53/8625 , B01D53/90 , F23J15/003 , F23J2215/10 , F23J2215/20 , F23L15/04 , F28D19/04 , Y02E20/348
摘要： A method and apparatus for reducing the amount of unused ammonia (“ammonia slip”) in instances where ammonia is provided to SNCR and/or SCR processes for reducing NOx pollution in flue gas produced by a fossil fuel burning facility. Such a facility incorporates a regenerative heat exchanger (i.e. an air preheater) for absorbing heat on the flue gas side, and releasing such absorbed heat to heat the incoming combustion air. The invention herein includes absorbent/desorbent media carried by at least some of the heat transfer elements of the heat exchanger. The media is active to adsorb at least a portion of the ammonia slip before the flue gas stream is exhausted to the environment, and to desorb essentially an equilibrium portion of such adsorbed ammonia into the incoming combustion air.
摘要翻译：在将氨提供给SNCR和/或SCR工艺以减少由化石燃料燃烧设备产生的烟道气中的NOx污染的情况下，用于减少未使用氨的量（“氨滑移”）的方法和装置。这种设备包括用于吸收烟气侧的热量的再生式热交换器（即，空气预热器），并且释放这种吸收的热量以加热进入的燃烧空气。本文的发明包括由热交换器的至少一些传热元件承载的吸收剂/解吸剂介质。介质在烟气流排放到环境之前，有效地吸附至少一部分氨滑移，并且将这些吸附的氨的基本平衡部分解吸到进入的燃烧空气中。

3. 发明授权

US06620393B2 Method and apparatus for reducing “ammonia slip” in SCR and/or SNCR NOx removal applications 失效
标题翻译：用于在SCR和/或SNCR NOx去除应用中减少“氨滑移”的方法和装置
公开(公告)号：US06620393B2
公开(公告)日：2003-09-16
申请号：US09911213
申请日：2001-07-23
申请人： Felix E. Spokoyny
发明人： Felix E. Spokoyny
IPC分类号： C01C300
CPC分类号： B01D53/79 , B01D53/56 , B01D53/8625 , B01D53/90 , F23J15/003 , F23J2215/10 , F23J2215/20 , F23L15/04 , F28D19/04 , Y02E20/348
摘要： A method and apparatus for reducing the amount of unused ammonia (“ammonia slip”) in instances where ammonia is provided to SNCR and/or SCR processes for reducing NOx pollution in flue gas produced by a fossil fuel burning facility. Such a facility incorporates a rotary regenerative heat exchanger (i.e. an air preheater and/or a gas to gas preheater) for absorbing heat from the gas flow on one side of the heat exchanger, and releasing such absorbed heat to heat the gas flow on the other side of the heat exchanger. The invention herein includes absorbent/desorbent media carried by at least some of the elements of the heat exchanger. The media is active to adsorb at least a portion of the ammonia slip after NOx is treated, and before the gas flow is exhausted to the environment, and to desorb essentially an equilibrium portion of such adsorbed ammonia into gas flow upstream from the providing of ammonia for the SNCR/SCR process.
摘要翻译：在将氨提供给SNCR和/或SCR工艺以减少由化石燃料燃烧设备产生的烟道气中的NOx污染的情况下，用于减少未使用氨的量（“氨滑移”）的方法和装置。这种设备包括用于从热交换器的一侧上的气流吸收热量的旋转再生式热交换器（即，空气预热器和/或气体与气体预热器），并释放这种吸收的热量以加热热交换器上的气流热交换器的另一侧。本文的发明包括由热交换器的至少一些元件承载的吸收剂/解吸剂介质。在处理NOx之后，在气体排放到环境之前，介质活性地吸附至少一部分氨滑移，并且将基本上将这种吸附的氨的平衡部分解吸到提供氨上游的气流中用于SNCR / SCR过程。

4. 发明授权

US06517793B1 Method of reducing Nox compounds in flue gases of recovery boiler 失效
标题翻译：还原锅炉废气中Nox化合物的方法
公开(公告)号：US06517793B1
公开(公告)日：2003-02-11
申请号：US09646406
申请日：2000-09-18
申请人： Ari Tamminen , Seppo Tuominiemi , Risto Hämäläinen
发明人： Ari Tamminen , Seppo Tuominiemi , Risto Hämäläinen
IPC分类号： C01C300
CPC分类号： D21C11/06 , D21C11/12
摘要： A method of reducing NOX compounds in the odor gases of a recovery boiler. In the method, ammonia in the odor gases is separated before the odor gases are combusted, the ammonia being then introduced into a recovery boiler at the pulp mill or in a separate catalyzer, where the ammonia reacts with nitrogen oxide forming water and molecular nitrogen.
摘要翻译：一种减少回收锅炉臭气中NO x化合物的方法。在该方法中，在气味气体燃烧之前，气味气体中的氨被分离，然后将氨引入到纸浆厂或单独的催化剂中的回收锅炉中，氨与氮氧化物形成水和分子氮反应。

5. 发明授权

US06471926B2 Method of using aerogel honeycomb catalyst monoliths for selective catalytic reaction of gas phase chemical species 失效
标题翻译：使用气凝胶蜂窝催化剂整料进行气相化学物质选择性催化反应的方法
公开(公告)号：US06471926B2
公开(公告)日：2002-10-29
申请号：US09294127
申请日：1999-04-19
申请人： Matthew T. Sander
发明人： Matthew T. Sander
IPC分类号： C01C300
CPC分类号： B01J13/0091 , C04B38/0022 , C04B2111/0081 , C04B32/02 , C04B38/0003 , C04B38/0045 , C04B40/0082 , C04B20/0048
摘要： A method for utilizing ultra-thin catalytic monoliths, internal molding and high concentrations of reactive catalytic species to exploit the unique high surface area of Aerogels in order to achieve catalytic selectivity of the desired gas phase heterogeneous reaction.
摘要翻译：一种利用超薄催化整体料，内部成型和高浓度反应性催化物质的方法，以利用Aerogels独特的高表面积，以达到所需气相多相反应的催化选择性。

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