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1. 发明授权

US5482617A Desulfurization of hydrocarbon streams 失效
标题翻译：烃流的脱硫
公开(公告)号：US5482617A
公开(公告)日：1996-01-09
申请号：US286894
申请日：1994-08-08
申请人： Nick A. Collins , Mohsen N. Harandi
发明人： Nick A. Collins , Mohsen N. Harandi
IPC分类号： C10G29/06 , C10G45/12 , C10G45/28 , C10G45/30
CPC分类号： C10G45/30 , C10G29/06 , C10G45/12 , C10G45/28
摘要： A process for desulfurizing a hydrocarbon stream which includes at least 50 ppmw sulfur in the form of organic sulfur compounds, and C.sub.5 + hydrocarbons including benzene. The hydrocarbon stream is contacted in the absence of added hydrogen with a fluidized bed of an acidic catalyst having a structure of ZSM-5, ZSM-11, ZSM-22, ZSM-23, ZSM-35, ZSM-48, MCM-22, MCM-36, MCM-49, zeolite Y, zeolite beta or mixtures thereof to convert the organic sulfur compounds to hydrogen sulfide. The catalyst contacts the hydrocarbon stream at a pressure of from 0.0 psig to about 400 psig, a temperature of from about 400.degree. F. to about 900.degree. F., and a weight hourly space velocity of from about 0.1 hr..sup.-1 to about 10.0 hr..sup.-1. Thereafter, the hydrogen sulfide is removed from the hydrocarbon stream.
摘要翻译：一种烃流的脱硫方法，其包括有机硫化合物形式的至少50ppmw的硫和包括苯的C5 +烃。烃流在不存在加氢的情况下与具有ZSM-5，ZSM-11，ZSM-22，ZSM-23，ZSM-35，ZSM-48，MCM-22结构的酸性催化剂的流化床接触，MCM-36，MCM-49，沸石Y，沸石β或其混合物，以将有机硫化合物转化为硫化氢。催化剂在压力为0.0psig至约400psig，温度为约400°F至约900°F，重时空速为约0.1hr.-1至约 10.0小时-1。此后，从烃流中除去硫化氢。

2. 发明授权

US2830013A Catalytic desulphurisation of petroleum hydrocarbons 失效
标题翻译：石油烃的催化脱硫
公开(公告)号：US2830013A
公开(公告)日：1958-04-08
申请号：US56774956
申请日：1956-02-27
申请人： BRITISH PETROLEUM CO
发明人： PURDY NORTHCOTT ROY , CARLTON HOUSAM ERNEST
IPC分类号： C10G45/30
CPC分类号： C10G45/30

3. 发明申请

US20150315483A1 PROCESS FOR CONVERTING PHENOLIC COMPOUNDS INTO AROMATIC HYDROCARBONS 有权
标题翻译：将酚醛化合物转化成芳香烃的方法
公开(公告)号：US20150315483A1
公开(公告)日：2015-11-05
申请号：US14651033
申请日：2013-12-10
申请人： STUDIENGESELLSCHAFT KOHLE MBH
发明人： Roberto RINALDI , Xingyu WANG
IPC分类号： C10G3/00
CPC分类号： C10G3/52 , C10G3/45 , C10G3/47 , C10G3/50 , C10G45/02 , C10G45/28 , C10G45/30 , C10G49/20 , C10G2300/42 , C10G2400/30 , Y02P30/20
摘要： The present invention discloses a process for the conversion of phenolics into aromatic hydrocarbons. In more detail, the present invention refers to a process for the selective hydrodeoxygenation of phenolic feeds into aromatic hydrocarbons, such as benzene, toluene, alkylbenzenes and others. The selective catalytic hydrodeoxygenation is performed in absence of external supply of molecular hydrogen.
摘要翻译：本发明公开了一种将酚类转化为芳族烃的方法。更详细地说，本发明涉及一种将酚类进料选择性加氢脱氧成芳族烃如苯，甲苯，烷基苯等的方法。选择性催化加氢脱氧在没有外部供应分子氢的情况下进行。

4. 发明授权

US08900447B2 Synthesis of acidic silica to upgrade heavy feeds 有权
标题翻译：酸性二氧化硅的合成来提升重质饲料
公开(公告)号：US08900447B2
公开(公告)日：2014-12-02
申请号：US13910195
申请日：2013-06-05
申请人： Board of Regents, The University of Texas System
发明人： Karina Castillo , Jason Parsons , Russell R. Chianelli
IPC分类号： C10G21/00 , C10G1/04 , C10G45/30 , C10G1/00 , C07D333/76
CPC分类号： C10G45/24 , C07D333/76 , C10G1/00 , C10G1/002 , C10G45/28 , C10G45/30 , C10G2300/107 , C10L1/04 , C10L2200/0438 , C10L2270/026 , C10L2290/24
摘要： A method and a product made by treating a sulfur-containing hydrocarbon heavy feed, e.g., heavy crude asphaltene reduction is disclosed herein. The method comprises the steps of: mixing the sulfur-containing hydrocarbon heavy feed with a hydrogen donor solvent and an acidified silica to form a mixture and oxidizing the sulfur in the mixture at a temperature between 50° C. and 210° C., wherein the oxidation lowers the amount sulfur in the sulfur-containing hydrocarbon heavy feed by at least 90%.
摘要翻译：本文公开了通过处理含硫烃重原料（例如重质粗沥青质还原）制备的方法和产品。该方法包括以下步骤：将含硫烃重原料与氢供体溶剂和酸化二氧化硅混合以形成混合物并在50℃至210℃的温度下氧化混合物中的硫，其中氧化剂将含硫烃重质原料中的硫含量降低至少90％。

5. 发明授权

US2893953A Equilibrium pressure autofining with a silica-alumina base autofining catalyst 失效
标题翻译：平衡压力用二氧化硅 - 氧化铝基底自动精炼催化剂自动精制
公开(公告)号：US2893953A
公开(公告)日：1959-07-07
申请号：US60252256
申请日：1956-08-07
申请人： BRITISH PETROLEUM CO
发明人： ROY TURNER , ARTHUR WHITE ERIC
IPC分类号： B01J21/12 , C10G45/30
CPC分类号： C10G45/30 , B01J21/12

6. 发明授权

US2852437A Catalytic desulphurization of petroleum hydrocarbons 失效
标题翻译：石油烃的催化脱硫
公开(公告)号：US2852437A
公开(公告)日：1958-09-16
申请号：US52034755
申请日：1955-07-06
申请人： BRITISH PETROLEUM CO
发明人： BERTRAM PORTER FREDERICK WILLI , CARLTON HOUSAM ERNEST
IPC分类号： B01J21/04 , C10G45/30
CPC分类号： C10G45/30 , B01J21/04

7. 发明授权

US2769755A Hydrodesulfurizing petroleum with desulphurisation catalysts on calcined trihydrate bauxite 失效
标题翻译：用煅烧三水铝土进行脱硫催化剂加氢脱硫石油
公开(公告)号：US2769755A
公开(公告)日：1956-11-06
申请号：US27270252
申请日：1952-02-20
申请人： BRITISH PETROLEUM CO
发明人： BERTRAM PORTER FREDERICK WILLI , NORMAN HARESNAPE JOHN
IPC分类号： B01J23/882 , C10G45/30
CPC分类号： C10G45/30 , B01J23/882

8. 发明授权

US09580660B2 Deoxygenation of biomass derived oxygenates to hydrocarbons via direct methane intervention 有权
标题翻译：通过直接甲烷干预将生物质衍生的含氧化合物脱氧化为烃
公开(公告)号：US09580660B2
公开(公告)日：2017-02-28
申请号：US13157455
申请日：2011-06-10
申请人： Sandun Fernando , Duminda Anuradh Gunawardena
发明人： Sandun Fernando , Duminda Anuradh Gunawardena
IPC分类号： C10G3/00 , C07C2/76 , C10G1/00 , C10G45/30
CPC分类号： C10G3/49 , C07C2/76 , C07C2529/40 , C10G1/002 , C10G3/44 , C10G3/47 , C10G3/52 , C10G45/30 , C10G2300/1014 , C10G2300/1025 , C10G2300/42 , C10G2400/30 , Y02P30/20 , C07C15/02
摘要： The application describes a process where methane or any short chained hydrocarbon could be catalytically coupled with an oxygenate (preferably derived from thermal processing of biomass) to dehydrate and produce a deoxygenated hydrocarbon. The presence of oxygen in biomass derivatives adversely affects its ability to be further processed into hydrocarbon fuels because the resulting water poisons many catalysts (including alumina containing catalysts, zeolites, etc.) found in petrochemical refineries. While commonly used hydrodeoxygenation methods require expensive hydrogen to instigate deoxygenation, the present process uses short chained hydrocarbons (such as methane or natural gas) to instigate hydrodeoxygenation.
摘要翻译：本申请描述了一种方法，其中甲烷或任何短链烃可以与含氧化合物（优选衍生自生物质的热处理）催化偶联以脱水并产生脱氧烃。生物质衍生物中氧气的存在不利地影响其进一步加工成烃燃料的能力，因为所产生的水会在石化炼油厂中发现许多催化剂（包括含氧化铝的催化剂，沸石等）。虽然通常使用的加氢脱氧方法需要昂贵的氢气来引发脱氧，但是本方法使用短链烃（例如甲烷或天然气）来引发加氢脱氧。

9. 发明申请

US20150090633A1 SYNTHESIS OF ACIDIC SILICA TO UPGRADE HEAVY FEEDS 审中-公开
标题翻译：酸性二氧化硅合成重组饲料
公开(公告)号：US20150090633A1
公开(公告)日：2015-04-02
申请号：US14558156
申请日：2014-12-02
申请人： Board of Regents, The University of Texas System
发明人： Karina Castillo , Jason Parsons , Russell R. Chianelli
IPC分类号： C10G45/24 , C10L1/04 , C10G45/30 , C10G1/00 , C10G45/28
CPC分类号： C10G45/24 , C07D333/76 , C10G1/00 , C10G1/002 , C10G45/28 , C10G45/30 , C10G2300/107 , C10L1/04 , C10L2200/0438 , C10L2270/026 , C10L2290/24
摘要： A method and a product made by treating a sulfur-containing hydrocarbon heavy feed, e.g., heavy crude asphaltene reduction is disposed herein. The method comprises the steps of: mixing the sulfur-containing hydrocarbon heavy feed with a hydrogen donor solvent and an addled silica to form a mixture and oxidizing the sulfur in the mixture at a temperature between 50° C. and 210° C. wherein the oxidation lowers the amount sulfur in the sulfur-containing hydrocarbon heavy feed by at least 90%.
摘要翻译：在此处处理通过处理含硫烃重质原料（例如重质粗沥青质还原）制备的方法和产品。该方法包括以下步骤：将含硫烃重原料与氢供体溶剂和加成二氧化硅混合以形成混合物并在50℃至210℃的温度下氧化混合物中的硫。其中氧化剂将含硫烃重质原料中的硫含量降低至少90％。

10. 发明申请

US20130264245A1 SYNTHESIS OF ACIDIC SILICA TO UPGRADE HEAVY FEEDS 有权
标题翻译：酸性二氧化硅合成重组饲料
公开(公告)号：US20130264245A1
公开(公告)日：2013-10-10
申请号：US13910195
申请日：2013-06-05
申请人： Board of Regents, The University of Texas System
发明人： Karina Castillo , Jason Parsons , Russell R. Chianelli
IPC分类号： C10G45/30 , C07D333/76
CPC分类号： C10G45/24 , C07D333/76 , C10G1/00 , C10G1/002 , C10G45/28 , C10G45/30 , C10G2300/107 , C10L1/04 , C10L2200/0438 , C10L2270/026 , C10L2290/24
摘要： A method and a product made by treating a sulfur-containing hydrocarbon heavy feed, e.g., heavy crude asphaltene reduction is disclosed herein. The method comprises the steps of: mixing the sulfur-containing hydrocarbon heavy feed with a hydrogen donor solvent and an acidified silica to form a mixture and oxidizing the sulfur in the mixture at a temperature between 50° C. and 210° C., wherein the oxidation lowers the amount sulfur in the sulfur-containing hydrocarbon heavy feed by at least 90%.
摘要翻译：本文公开了通过处理含硫烃重原料（例如重质粗沥青质还原）制备的方法和产品。该方法包括以下步骤：将含硫烃重原料与氢供体溶剂和酸化二氧化硅混合以形成混合物并在50℃至210℃的温度下氧化混合物中的硫，其中氧化剂将含硫烃重质原料中的硫含量降低至少90％。

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