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    • 1. 发明授权
    • Cellulose sulfate esters
    • 硫酸纤维素酯
    • US4141746A
    • 1979-02-27
    • US786225
    • 1977-04-11
    • Richard G. Schweiger
    • Richard G. Schweiger
    • C08B5/00C08B5/02C08B5/14C08B31/06C08B37/00C08F8/30C08F8/34C08F8/36C08F8/42C08L1/16
    • C08F8/36C08B31/06C08B37/00C08B5/00C08B5/02C08B5/14C08F8/30C08F8/34C08F8/42
    • A water-soluble sulfate ester of cellulose having a degree of substitution of about 0.3 to about 1.0 with a substantially uniform distribution of sulfate ester groups among the polymer units of the cellulose. A thickened aqueous medium containing water and said water-soluble sulfate ester of cellulose having a degree of substitution of about 0.3 to about 1.0.A water-insoluble sulfate ester of cellulose which is highly swellable in the presence of water and has a degree of substitution of up to about 0.3 with the sulfate ester groups being substantially uniformly distributed among the polymer units of the cellulose.A water-soluble colloidal cellulose sulfate ester having a degree of substitution of about 1.3 to about 2 with the sulfate ester groups being substantially uniformly distributed among the polymer units of the cellulose. A thickened aqueous medium containing water and said water-soluble cellulose sulfate ester having a degree of substitution of about 1.3 to about 2.0.A water-soluble colloidal cellulose sulfate ester having a degree of substitution of about 1.0 to about 1.3 with the sulfate ester groups being substantially uniformly distributed among the polymer units of the cellulose. A thickened aqueous medium containing water and said water-soluble sulfate ester having a degree of substitution of about 1.0 to about 1.3.
    • 纤维素的聚合物单元中硫酸酯基的分布基本均匀的纤维素的水溶性硫酸酯,其取代度为约0.3至约1.0。 含有水的增稠水性介质和具有约0.3至约1.0的取代度的纤维素的所述水溶性硫酸酯。
    • 9. 发明授权
    • Process for preparing a sulfate ester of a polyhydroxy polymer
    • 制备多羟基聚合物硫酸酯的方法
    • US4177345A
    • 1979-12-04
    • US934818
    • 1978-08-18
    • Richard G. Schweiger
    • Richard G. Schweiger
    • C07C203/00C07C203/04C08B5/00C08B5/02C08B5/14C08B31/06C08B37/00C08F8/30C08F8/36C08F8/42
    • C08F8/36C08B31/06C08B37/00C08B5/00C08B5/02C08B5/14C08F8/30C08F8/42
    • A process for preparing a sulfate ester of a polyhydroxy polymer which is a partially substituted polysaccharide or a polyvinyl alcohol which contains ether groups, ester groups other than sulfate, or a mixture of ether groups and ester groups other than sulfate. A nitrite ester of the partially substituted polymer is reacted with sulfur trioxide or a complex thereof to obtain a mixed nitrite:sulfate ester which is then reacted with a protic solvent to remove residual nitrite ester groups.A process for preparing a substantially uniformly substituted colloidal cellulose sulfate having a degree of substitution of about 1.1 to 2.0. A nitrite ester of cellulose having a degree of substitution less than about 2 is reacted with sulfur trioxide or a complex thereof to obtain a mixed nitrite:sulfate ester which is reacted with a protic solvent to remove residual nitrite ester groups.A process for preparing a substantially uniformly substituted cellulose sulfate having a degree of substitution ranging up to about 1.1. A nitrite ester of cellulose having a degree of substitution of about 2 to below about 3 is reacted with sulfur trioxide or a complex thereof to obtain a mixed nitrite:sulfate ester which is then reacted with a protic solvent to remove residual nitrite ester groups.
    • 制备多羟基聚合物的硫酸酯的方法,该多羟基聚合物是部分取代的多糖或含有醚基的聚乙烯醇,除硫酸酯以外的酯基,或除了硫酸酯以外的醚基和酯基的混合物。 将部分取代的聚合物的亚硝酸酯与三氧化硫或其络合物反应,得到混合的亚硝酸盐:硫酸酯,然后与质子溶剂反应以除去残留的亚硝酸酯基团。 一种制备基本上均匀取代的取代度为约1.1至2.0的胶体硫酸纤维素的方法。 将取代度小于约2的纤维素的亚硝酸酯与三氧化硫或其配合物反应,得到与质子溶剂反应以除去残留的亚硝酸酯基团的混合亚硝酸盐:硫酸酯。 一种制备基本上均匀取代的具有高达约1.1的取代度的硫酸纤维素的方法。 具有约2至低于约3的取代度的纤维素的亚硝酸酯与三氧化硫或其络合物反应,得到混合的亚硝酸盐:硫酸酯,然后与质子溶剂反应以除去残留的亚硝酸酯基团。