专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明申请

US20180318816A1 METAL ORGANIC FRAMEWORKS, THEIR SYNTHESIS AND USE 审中-公开
公开(公告)号：US20180318816A1
公开(公告)日：2018-11-08
申请号：US15969162
申请日：2018-05-02
申请人： ExxonMobil Research and Engineering Company
发明人： Joseph M. Falkowski , Mary S. Abdulkarim , Mobae Afeworki , Randall J. Meyer , Simon C. Weston
IPC分类号： B01J31/16 , C07C5/25 , C07F9/42
CPC分类号： B01J31/1691 , B01J20/226 , B01J31/00 , C07C5/2293 , C07C5/2562 , C07C2531/16 , C07C2531/24 , C07F9/3843 , C07F9/3856 , C07F9/425 , C07C11/10
摘要： A novel metal organic framework, EMM-39, is described having the structure of UiO-66 and comprising bisphosphonate linking ligands. EMM-39 has acid activity and is useful as a catalyst in olefin isomerization. Also disclosed is a process of making metal organic frameworks, such as EMM-39, by heterogeneous ligand exchange, in which linking ligands having a first bonding functionality in a host metal organic framework are exchanged with linking ligands having a second different bonding functionality in the framework.

2. 发明授权

US3794671A Catalysts and compositions therefor 失效
标题翻译：催化剂及其组合物
公开(公告)号：US3794671A
公开(公告)日：1974-02-26
申请号：US3794671D
申请日：1971-07-20
申请人： JOHNSON MATTHEY CO LTD
发明人： WILKINSON G
IPC分类号： C07C9/14 , B01J31/16 , B01J31/18 , B01J31/20 , B01J31/22 , B01J31/24 , B01J31/28 , C07B61/00 , C07C1/00 , C07C1/207 , C07C5/03 , C07C5/08 , C07C5/13 , C07C5/22 , C07C13/02 , C07C45/50 , C07C67/00 , C07F9/50 , C07F15/00
CPC分类号： C07F15/008 , B01J31/1895 , B01J31/20 , B01J31/2226 , B01J31/2404 , B01J31/28 , B01J2231/645 , B01J2531/822 , C07C5/03 , C07C5/08 , C07C5/2293 , C07C45/50 , C07C2531/24 , Y10S585/906 , C07C47/02
摘要： NONHALOGEN OR PSEUDO-HALOGEN COORDINATION COMPLEXES OF RH(1) CONTAINING A STABILIZING DONOR LIGAND. THE COMPLEXES ARE MADE BY ADDING A COMPOUND WHICH ACATS AS A STABILIZING DONOR TO A SOLUTION OF A RHODIUM (II) CARBOXYLATE PROTONATED BY AN ACID.THE COMPLEXES ARE USEFUL CATALYSTS.

3. 发明授权

US4556720A Fluorochemical rhodium compounds 失效
标题翻译：含氟化合物铑化合物
公开(公告)号：US4556720A
公开(公告)日：1985-12-03
申请号：US541129
申请日：1983-10-12
申请人： Allen R. Siedle , Richard D. Howells
发明人： Allen R. Siedle , Richard D. Howells
IPC分类号： B01J31/00 , C07B31/00 , C07B35/08 , C07B37/10 , C07B41/06 , C07B61/00 , C07C1/00 , C07C2/48 , C07C5/22 , C07C5/25 , C07C11/00 , C07C15/00 , C07C45/00 , C07C45/50 , C07C67/00 , C07F15/00
CPC分类号： C07F15/008 , C07C17/281 , C07C2/48 , C07C45/50 , C07C5/2293 , C07C5/2593 , C07C2531/22 , C07C2531/24
摘要： Coordination compounds of rhodium are solid salts having donor ligands of [(aryl).sub.3 P].sub.3 Rh.sup.+ and a non-coordinated counterion derived from a fluorochemical acid, the salts having the formula:[(aryl).sub.3 P].sub.3 Rh.sup.+ (counterion).sup.-.The salts are prepared by reacting [(aryl).sub.3 P].sub.4 RhH, which is an uncharged rhodium hydride, with a fluorochemical acid selected form acids having the formulae:HC(R)(SO.sub.2 R.sub.f).sub.2, R.sub.f 'SO.sub.3 H, and HN(SO.sub.2 R.sub.f).sub.2wherein R.sub.f and R.sub.f ' are perfluoroalkyl groups and R is lower alkyl substituted or unsubstituted phenyl, hydrogen, Cl, SO.sub.2 R.sub.f or R.sub.f. Carbonylation of the [(aryl).sub.3 P].sub.3 Rh.sup.+ (counterion).sup.- compounds of this invention, e.g., by contacting the salts of the invention with carbon monoxide gas, produces salts having the formula:[(aryl).sub.3 P].sub.3 Rh(CO).sub.n.sup.+ (counterion).sup.-,wherein n is 1 or 2, and (counterion).sup.- is as defined above. These carbonylated derivatives as well as the above-described precursor salts are useful as catalysts in organic transformation reactions, such as isomerization, cyclization and hydroformylation reactions.
摘要翻译：铑的配位化合物是具有[（芳基）3P] 3Rh +的供体配体和衍生自含氟化合物酸的非配位抗衡离子的固体盐，其具有下式：[（芳基）3 P] 3Rh +（抗衡离子） - 。通过使不饱和氢化铑的[（芳基）3 P] 4RhH与选自具有下列通式的酸的含氟化合物反应来制备盐：HC（R）（SO 2 R f）2，Rf'SO 3 H和HN（SO 2 R f） 2其中Rf和Rf'是全氟烷基，R是低级烷基取代或未取代的苯基，氢，Cl，SO2Rf或Rf。 [（芳基）3P] 3Rh +（抗衡离子）化合物的羰基化，例如通过使本发明的盐与一氧化碳气体接触，产生具有下式的盐：[（芳基）3 P] 3Rh（CO）n + （抗衡离子） - ，其中n为1或2，和（抗衡离子） - 如上所定义。这些羰基化衍生物以及上述前体盐可用作有机转化反应中的催化剂，例如异构化，环化和加氢甲酰化反应。

4. 发明授权

US4504371A Process for the photocatalytic isomerization of olefins utilizing a mixed metal cluster 失效
标题翻译：使用混合金属簇的烯烃的光催化异构化方法
公开(公告)号：US4504371A
公开(公告)日：1985-03-12
申请号：US579258
申请日：1984-02-13
申请人： Larry M. Cirjak , Lynne Sutherland
发明人： Larry M. Cirjak , Lynne Sutherland
IPC分类号： B01J19/12 , B01J31/20 , C07C5/22 , C07C5/25 , C07C5/23
CPC分类号： B01J31/2291 , B01J19/121 , B01J19/123 , B01J31/1845 , B01J31/1895 , B01J31/20 , B01J31/2295 , B01J31/24 , B01J31/2404 , C07C5/2286 , C07C5/2293 , C07C5/2593 , B01J2531/0211 , B01J2531/16 , B01J2531/26 , B01J2531/35 , B01J2531/46 , B01J2531/56 , B01J2531/62 , B01J2531/64 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/842 , C07C2531/22 , C07C2531/24 , Y10S204/90
摘要： A novel process for the isomerization of olefins which employs a photocatalytic mixed metal cluster, wherein a solution of the olefin and the cluster is irradiated causing the cluster to become catalytically active and to isomerize the olefin. The photocatalytic mixed metal cluster has the empirical formula:(C.sub.n R.sub.n ').sub.a Fe.sub.b M.sub.c (CO).sub.d L.sub.ewherein n is five; wherein R' is selected from the group consisting of hydrogen, methyl, ethyl, acetyl, formyl, bromine, chlorine and fluorine; wherein M is a transition metal other than iron selected from the group consisting of Mo, Ru, Rh, Sc, Ti, V, Cr, Mn, Co, Ni, Cu and Zn; wherein L is a Group V type ligand; and further wherein a is from about one to five, b and c are from about one to five and b plus c is between two and six, d is from about five to 18 with the proviso that d is always equal to or greater than b plus c, and e is from about 0 to 18. A second novel process for the isomerization of olefins also employs a photocatalytic mixed metal cluster and irradiation wherein the cluster is first irradiated causing it to become catalytically active, and is then combined with an olefin to form a complex allowing the olefin to be isomerized.
摘要翻译：一种使用光催化混合金属簇的烯烃异构化的新方法，其中照射烯烃和簇的溶液，使得簇变成催化活性并使烯烃异构化。光催化混合金属簇具有以下经验式：（CnRn'）aFebMc（CO）dLe其中n为5; 其中R'选自氢，甲基，乙基，乙酰基，甲酰基，溴，氯和氟; 其中M是除了选自Mo，Ru，Rh，Sc，Ti，V，Cr，Mn，Co，Ni，Cu和Zn中的铁以外的过渡金属; 其中L是V型配体; 并且其中a为约1至5，b和c为约1至5，b加c为2至6，d为约5至18，条件是d总是等于或大于b 加上c，e为约0至18.烯烃异构化的第二个新方法还采用光催化混合金属簇和照射，其中首先照射簇使其变成催化活性，然后与烯烃以形成允许烯烃异构化的络合物。

5. 发明授权

US3903190A Acyclic olefin isomerization in nitrogen atmosphere using cobalt hydride complexes 失效
标题翻译：使用氢化钴络合物在氮气气氛中进行非环烯烃异构化
公开(公告)号：US3903190A
公开(公告)日：1975-09-02
申请号：US41680673
申请日：1973-11-19
申请人： PHILLIPS PETROLEUM CO
发明人： PENNELLA FILIPPO
IPC分类号： B01J31/12 , B01J31/18 , B01J31/24 , C07C5/22 , C07C5/25 , C07C3/62
CPC分类号： B01J31/2404 , B01J31/121 , B01J31/1895 , B01J2231/52 , B01J2531/845 , C07C5/2293 , C07C5/2593 , C07C2531/24 , C07C11/10
摘要： Cobalt hydride complexes containing tertiary phosphine, arsine or stibine ligands are employed as catalysts for isomerization of olefins. Enhanced catalytic activity is achieved by use of nitrogen in the isomerization.
摘要翻译：含有叔膦，胂或锑配体的钴氢化物络合物用作烯烃异构化的催化剂。通过在异构化中使用氮来实现增强的催化活性。

6. 发明授权

US3641184A Olefin isomerization 失效
标题翻译： OLEFIN异构化
公开(公告)号：US3641184A
公开(公告)日：1972-02-08
申请号：US3641184D
申请日：1969-12-16
申请人： PHILLIPS PETROLEUM CO
发明人： SMITH CLIFFORD E , WHITE BOBBY J
IPC分类号： C07C5/22 , C07C5/25
CPC分类号： C07C5/2293 , C07C5/2593 , C07C2521/08 , C07C2521/12 , C07C2531/14 , C07C2531/24 , C07C11/02
摘要： AN OLEFIN IS ISOMERIZED BY CONTACT WITH A CATALYST FORMED FROM A SUPPORTED NICKEL COMPLEX ASSOCIATED WITH AN ALUMINUM COMPOUND.

7. 发明申请

US20180318817A1 METAL ORGANIC FRAMEWORKS, THEIR SYNTHESIS AND USE 审中-公开
公开(公告)号：US20180318817A1
公开(公告)日：2018-11-08
申请号：US15969182
申请日：2018-05-02
申请人： ExxonMobil Research and Engineering Company
发明人： Joseph M. Falkowski , Mary S. Abdulkarim , Mobae Afeworki , Randall J. Meyer , Simon C. Weston
IPC分类号： B01J31/16 , C07C5/25
CPC分类号： B01J31/1691 , B01J20/226 , B01J31/00 , C07C1/24 , C07C5/2293 , C07C5/2562 , C07C2531/16 , C07C2531/18 , C07C2531/24 , C07F9/3843 , C07F9/3856 , C07F9/425 , C07C11/10 , C07C11/08
摘要： A novel metal organic framework, EMM-42, is described having the structure of UiO-66 and comprising bisphosphonate linking ligands. EMM-42 has acid activity and is useful as a catalyst in olefin isomerization. Also disclosed is a process of making metal organic frameworks, such as EMM-42, by heterogeneous ligand exchange, in which linking ligands having a first bonding functionality in a host metal organic framework are exchanged with linking ligands having a second different bonding functionality in the framework.

8. 发明授权

US4625069A Fluorochemical rhodium compounds 失效
标题翻译：含氟化合物铑化合物
公开(公告)号：US4625069A
公开(公告)日：1986-11-25
申请号：US769590
申请日：1985-08-26
申请人： Allen R. Siedle , Richard D. Howells
发明人： Allen R. Siedle , Richard D. Howells
IPC分类号： C07C2/48 , C07C5/22 , C07C5/25 , C07C45/50 , C07F15/00
CPC分类号： C07C5/2593 , C07C17/281 , C07C2/48 , C07C45/50 , C07C5/2293 , C07F15/008 , C07C2531/22 , C07C2531/24
摘要： Coordination compounds of rhodium are solid salts having donor ligands of [(aryl).sub.3 P].sub.3 Rh.sup.+ and a non-coordinated counterion derived from a fluorochemical acid, the salts having the formula:[(aryl).sub.3 P].sub.3 Rh.sup.+ (counterion).sup.-.The salts are prepared by reacting [(aryl).sub.3 P].sub.4 RhH, which is and uncharged rhodium hydride, with a fluorochemical acid selected form acids having the formulae:HC(R)(SO.sub.2 R.sub.f).sub.2, R.sub.f 'SO.sub.3 H, and HN(SO.sub.2 R.sub.f).sub.2wherein R.sub.f and R.sub.f ' are perfluoroalkyl groups and R is lower alkyl substituted or unsubstituted phenyl, hydrogen, Cl, SO.sub.2 R.sub.f or R.sub.f. Carbonylation of the [(aryl).sub.3 P].sub.3 Rh.sup.+ (counterion).sup.- compounds of this invention, e.g., by contacting the salts of the invention with carbon monoxide gas, produces salts having the formula:[(aryl).sub.3 P].sub.3 Rh(CO).sub.n.sup.+(counterion).sup.-,wherein n is 1 or 2, and (counterion).sup.- is as defined above. These carbonylated derivatives as well as the above-described precursor salts are useful as catalysts in organic transformation reactions, such as isomerization, cyclization and hydroformylation reactions.
摘要翻译：铑的配位化合物是具有[（芳基）3P] 3Rh +的供体配体和衍生自含氟化合物酸的非配位抗衡离子的固体盐，其具有下式：[（芳基）3 P] 3Rh +（抗衡离子） - 。通过使选自酸式（HC（R）（SO2Rf）2，Rf'SO3H和HN（SO2Rf））的含氟化合物酸与[和（不带电荷的氢化铑） 2其中Rf和Rf'是全氟烷基，R是低级烷基取代或未取代的苯基，氢，Cl，SO2Rf或Rf。 [（芳基）3P] 3Rh +（抗衡离子）化合物的羰基化，例如通过使本发明的盐与一氧化碳气体接触，产生具有下式的盐：[（芳基）3 P] 3Rh（CO）n + （抗衡离子） - ，其中n为1或2，和（抗衡离子） - 如上所定义。这些羰基化衍生物以及上述前体盐可用作有机转化反应中的催化剂，例如异构化，环化和加氢甲酰化反应。

9. 发明授权

US4062883A Polymer-bound metallocarborane catalyst product and process 失效
标题翻译：聚合物结合金属环硼烷催化剂产品及工艺
公开(公告)号：US4062883A
公开(公告)日：1977-12-13
申请号：US712416
申请日：1976-08-06
申请人： M. Frederick Hawthorne , William Kalb
发明人： M. Frederick Hawthorne , William Kalb
IPC分类号： B01J31/06 , B01J31/16 , B01J31/24 , C07C5/03 , C07C5/22 , C07F5/02 , C07F15/00
CPC分类号： B01J31/069 , B01J31/2404 , C07C5/03 , C07C5/2293 , C07F15/008 , C07F5/027 , B01J2231/52 , B01J2231/645 , B01J31/1658 , C07C2531/06 , C07C2531/24
摘要： A heterogeneous metallocarborane catalyst bound to a polymeric support by a carbon-boron bond. Chloromethylated polystyrene beads provide the support. The catalytic beads are characterized as3,3-(Ph P)-3-H-4 polystyrylmethyl - 3,1,2-Rh C.sub.2 B.sub.9 H.sub.10.
摘要翻译：异质金属硼烷催化剂通过碳 - 硼键与聚合物载体结合。氯甲基化聚苯乙烯珠提供支持。催化珠的特征是3,3-（Ph P）-3-H-4聚苯乙烯基甲基-3,1,2-铑C2B9H10。

10. 发明授权

US3976596A Hydridometallic carborane catalytic compounds 失效
标题翻译：氢化金属碳硼烷催化剂
公开(公告)号：US3976596A
公开(公告)日：1976-08-24
申请号：US562070
申请日：1975-03-26
申请人： Marion F. Hawthorne , Timm E. Paxson
发明人： Marion F. Hawthorne , Timm E. Paxson
IPC分类号： B01J31/24 , C07C5/03 , C07C5/22 , C07C45/50 , C07F7/08 , C07F15/00 , B01J31/12
CPC分类号： B01J31/2404 , C07C45/50 , C07C5/03 , C07C5/2293 , C07F15/0013 , C07F15/004 , C07F15/008 , C07F7/0801 , B01J2231/321 , B01J2231/52 , B01J2231/645 , B01J2531/0227 , B01J2531/822 , B01J2531/827 , C07C2531/24
摘要： A family of stable hydrido-rhodium and iridium carboranes are described which are effective catalysts for the homogeneous hydrogenation, isomerization and hydroformylation of olefins and the hydrosilylation of ketones.
摘要翻译：描述了一系列稳定的氢化铑和铱碳硼烷，它们是烯烃的均相加氢，异构化和加氢甲酰化以及酮的氢化硅烷化的有效催化剂。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式