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    • 1. 发明申请
    • Thermal recording material
    • 热敏记录材料
    • US20040235660A1
    • 2004-11-25
    • US10481958
    • 2003-12-24
    • Masayuki IwasakiTsutomu WatanabeHirofumi Mitsuo
    • B41M005/30
    • B41M5/3336B41M5/3338B41M5/41
    • A thermal recording material having a support and, formed thereon, a thermal coloring layer containing an electron donating colorless dye and an electron accepting compound, wherein the electron accepting compound comprises 4-hydroxybenzenesulfoneanilide and the support comprises a used paper pulp as a primary component; the thermal recording material which further comprises at least one of calcium carbonate of calcite type, amorphous silica and aluminum hydroxide as an inorganic pigment; and the thermal recording material wherein the electron donating colorless dye comprises a specific colorless dye and the recording material is formed through the use of a liquid pigment dispersion having a pH of 7 to 10.
    • 一种具有支持体并在其上形成含有给电子性无色染料和受电子化合物的热着色层的热敏记录材料,其中电子接受性化合物包括4-羟基苯磺酰苯胺,载体包括废纸纸浆作为主要成分; 所述热敏记录材料还包含方解石型碳酸钙,无定形二氧化硅和氢氧化铝中的至少一种作为无机颜料; 和其中给电子性无色染料包含特定无色染料的热敏记录材料,并且通过使用pH为7至10的液体颜料分散体形成记录材料。
    • 2. 发明授权
    • Reversible thermal-recording composite and rewritable reversible
thermal-recording sheet and card using the same
    • 可逆热敏记录复合和可重写的可逆热敏记录纸和卡片使用相同
    • US5972837A
    • 1999-10-26
    • US930502
    • 1997-09-30
    • Shoko SatohKazuyoshi YatsushigeSoichi HasegawaKazuo Nate
    • Shoko SatohKazuyoshi YatsushigeSoichi HasegawaKazuo Nate
    • B42D15/10B41M5/28B41M5/30B41M5/333B41M5/337
    • B41M5/305B41M5/3335B41M5/3338
    • A reversible thermal-recording composite capable of exerting great performance for repeated use and yielding good printing quality at higher coloring concentrations is provided, wherein the coloring and fading reaction of a leuco dye with a coloring and fading agent is utilized and a specific coloring and fading agent, a specific inorganic filler and a specific amine compound and the like are used in the thermal-recording layer, and a thermal-recording sheet and a thermal-recording card using the same are also provided.The thermal-recording sheet comprises the thermal-recording composite and comprises at least (1) a substrate, (2) a reversible thermal-recording layer and (3) a protective layer, wherein the thermal-recording layer contains a reversible coloring dye, a coloring and fading agent, an inorganic filler and an amine compound in an organic polymeric binder and the coloring and fading agent is an amide compound produced by dehydration condensation of an aliphatic carboxylic acid with a phenolic hydroxyl group and an aliphatic alkylamine. A reversible thermal-recording composite with a higher coloring concentration, greater long-term stability of image, excellent printing quality and good durability for repetition, can be realized, together with a thermal-recording sheet or card using the same.
    • PCT No.PCT / JP97 / 00221 Sec。 371日期:1997年9月30日 102(e)1997年9月30日PCT PCT 1997年1月27日PCT公布。 公开号WO97 / 28005 日期1997年7月8日提供了一种能够在较高着色浓度下重复使用并产生良好印刷质量的可逆热敏记录复合材料,其中使用无色染料与着色剂和褪色剂的着色和褪色反应, 在热敏记录层中使用特定的着色和褪色剂,特定的无机填料和特定的胺化合物等,并且还提供热敏记录纸和使用其的热敏记录卡。 热敏记录片材包括热敏记录复合材料,并且至少包括(1)基材,(2)可逆热记录层和(3)保护层,其中热记录层含有可逆着色染料, 有机聚合物粘合剂中的着色和褪色剂,无机填料和胺化合物,着色和褪色剂是通过脂族羧酸与酚羟基和脂族烷基胺的脱水缩合制备的酰胺化合物。 可以实现具有较高着色浓度,更长的图像长期稳定性,优异的印刷质量和良好的重复耐久性的可逆热敏记录复合材料,以及使用其的热敏记录片材或卡片。
    • 3. 发明申请
    • Invisible Ink And Scratch Pad
    • 隐形墨水和划痕垫
    • US20080113862A1
    • 2008-05-15
    • US11972600
    • 2008-01-10
    • Terry StovoldJoAnn Domanski
    • Terry StovoldJoAnn Domanski
    • B41M5/24C09D11/00
    • B41M3/005B41M5/3331B41M5/3335B41M5/3338B41M5/3372B41M7/0036C09D11/50
    • An invisible ink, a method for preparing an invisible ink, and an invisible ink product are disclosed herein. An invisible ink comprising a first ink combined with a second ink is applied to a print medium. The first ink comprises a color developer activator without a color former leuco dye and the second ink comprises a color former leuco dye without a color developer activator. The first ink is prepared with a polyvinyl alcohol binder, dispersant/surfactant, and a wetting agent. The second ink is prepared with a polyvinyl alcohol binder, grind aid, dispersant/surfactant and defoamer. Heat generated by rubbing and/or scratching the invisible ink on the print medium activates the color former leuco dye and activator to change the color on the printing medium.
    • 本文公开了不可见的油墨,制备不可见油墨的方法和不可见的油墨产品。 将包含与第二墨水组合的第一墨水的不可见墨水施加到打印介质。 第一种油墨包含不含着色剂无色染料的彩色显影剂活化剂,第二种油墨包含不含彩色显影剂活化剂的着色剂无色染料。 第一种油墨用聚乙烯醇粘合剂,分散剂/表面活性剂和润湿剂制备。 第二种油墨用聚乙烯醇粘合剂,研磨助剂,分散剂/表面活性剂和消泡剂制备。 通过摩擦和/或刮擦印刷介质上的不可见墨水产生的热量激活着色剂无色染料和活化剂以改变印刷介质上的颜色。