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    • 4. 发明申请
    • ELECTROCHEMICAL MACHINING METHOD, ELECTROCHEMICAL MACHINING APPARATUS AND ELECTROCHEMICAL MACHINING FLUID
    • 电化学加工方法,电化学加工设备和电化学加工流体
    • US20160256945A1
    • 2016-09-08
    • US15031018
    • 2013-11-05
    • MITSUBISHI ELECTRIC CORPORATION
    • Akihiro GOTONagao SAITONaotake MOHRIYuichiro HAISHITakashi YUZAWA
    • B23H3/08C25F3/02B23H3/10
    • B23H3/08B23H3/10C25F3/02
    • While switching polarity of an electrode, a voltage is applied between the electrode and a workpiece hard metal with the electrode used as a negative-electrode such that tungsten carbide (WC; component of the hard metal) is anodized to form a tungsten oxide (WO3), and a voltage is supplied therebetween with the electrode used as a positive-electrode such that cobalt (Co) that is a component of the workpiece is electrolytically-eluted and at the same time the WO3 generated by anodization is dissolved in the machining fluid, a saline solution (NaCl) or an aqueous solution of nitrate of soda (Na(No3)) is used as an machining fluid; a calcium salt is added beforehand to the machining fluid to react tungstate soda (Na2WO4) generated in the machining with the calcium salt whereby calcium tungstate (CaWO4) is produced; and a calcium compound is separated and recovered using a difference in specific gravity.
    • 当电极切换极性时,电极和工件硬质金属之间施加电压,其中电极用作负电极,使得碳化钨(WC;硬质金属的组分)被阳极化以形成氧化钨(WO3 ),并且在其间提供电压,使用作为正极的电极使得作为工件的成分的钴(Co)被电解洗脱,同时通过阳极氧化产生的WO 3溶解在加工液中 ,使用盐水(NaCl)或苏打(Na(No3))硝酸盐水溶液作为加工液; 预先将钙盐加入到机加工液中,使加工中产生的钨酸钠(Na2WO4)与钙盐反应,从而产生钨酸钙(CaWO 4); 并且使用比重差来分离和回收钙化合物。