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1. 发明授权

US09828473B2 Nanoparticulates and a linear polymer delivery system 有权
公开(公告)号：US09828473B2
公开(公告)日：2017-11-28
申请号：US14890194
申请日：2014-05-09
申请人： ZYVEX PERFORMANCE MATERIALS, INC.
发明人： Srinagesh Kumar Potluri , Weijun Wang , Srinivas Gadthula , Bao Ngoc Le
IPC分类号： C08J3/22 , C08G18/32 , C08L63/00 , C08L67/00 , C08L75/04 , C08K3/00 , C08K7/00
CPC分类号： C08J3/226 , C08G18/3206 , C08J3/22 , C08J2363/00 , C08J2367/02 , C08J2375/04 , C08J2463/00 , C08J2463/02 , C08J2467/02 , C08J2475/04 , C08K3/00 , C08K7/00 , C08K2201/011 , C08L63/00 , C08L67/00 , C08L75/04
摘要： Methods and compositions are provided for the efficient and beneficial use of nanoparticulates, such as carbon nanotubes. In various embodiments, a nanoparticulate entrapped in a linear polymer, where the linear polymer is formed in the presence of the nanoparticulate, is provided. The entrapped nanoparticulate provides an efficient means to introduce nanoparticulates into compositions, such as resins and fiber-reinforced resins, allowing for increased dispersion and beneficial properties.

2. 发明申请

US20090203867A1 METHODS FOR THE SYNTHESIS OF MODULAR POLY(PHENYLENEETHYNYLENES) AND FINE TUNING THE ELECTRONIC PROPERTIES THEREOF FOR THE FUNCTIONALIZATION OF NANOMATERIALS 审中-公开
标题翻译：用于合成聚亚烷基（苯乙烯）的方法和微调其电子性能的纳米材料的功能化
公开(公告)号：US20090203867A1
公开(公告)日：2009-08-13
申请号：US12423611
申请日：2009-04-14
申请人： Hassan Ait-Haddou , Marni Rutkofsky
发明人： Hassan Ait-Haddou , Marni Rutkofsky
IPC分类号： C08F38/00
CPC分类号： H01B1/125 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B32/18 , C01B2202/02 , C01B2202/06 , C08G61/02 , C08K9/08
摘要： Poly(aryleneethynylene) polymers for exfoliating and dispersing/solubilizing nanomaterial are provided herein. The poly(aryleneethynylene) polymers have unit monomer portions, each monomer portion having at least one electron donating substituent thereby forming an electron donor monomer portion, or at least one electron withdrawing substituent thereby forming an electron accepting monomer portion. Such polymers exfoliate and disperse nanomaterial without presonication of the nanomaterial.
摘要翻译：本文提供了用于剥离和分散/增溶纳米材料的聚（亚芳基亚乙炔基）聚合物。聚（亚芳基亚乙炔基）聚合物具有单元单体部分，每个单体部分具有至少一个给电子取代基，从而形成电子给体单体部分，或至少一个吸电子取代基，从而形成电子接受单体部分。这种聚合物在纳米材料的预先分解的情况下剥离和分散纳米材料。

3. 发明授权

US07544415B2 Polymer and method for using the polymer for solubilizing nanotubes 有权
标题翻译：聚合物和使用聚合物溶解纳米管的方法
公开(公告)号：US07544415B2
公开(公告)日：2009-06-09
申请号：US11775633
申请日：2007-07-10
申请人： Jian Chen , Haiying Liu
发明人： Jian Chen , Haiying Liu
IPC分类号： B32B9/04
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C08G61/02 , C08G61/122 , C08G61/124 , C08G61/126 , Y10T428/2918 , Y10T428/2975 , Y10T428/30
摘要： A new, non-wrapping approach to solubilize nanotubes, such as carbon nanotubes, in organic and inorganic solvents is provided. In accordance with certain embodiments, carbon nanotube surfaces are functionalized in a non-wrapping fashion by functional conjugated polymers that include functional groups for solubilizing such nanotubes. Various embodiments provide polymers that noncovalently bond with carbon nanotubes in a non-wrapping fashion. For example, various embodiments of polymers are provided that comprise a relatively rigid backbone that is suitable for noncovalently bonding with a carbon nanotube substantially along the nanotube's length, as opposed to about its diameter. In preferred polymers, the major interaction between the polymer backbone and the nanotube surface is parallel π-stacking. The polymers further comprise at least one functional extension from the backbone that are any of various desired functional groups that are suitable for solubilizing a carbon nanotube.
摘要翻译：提供了一种在有机和无机溶剂中溶解纳米管（例如碳纳米管）的新的非包裹方法。根据某些实施方案，碳纳米管表面通过包括用于溶解这种纳米管的官能团的官能共轭聚合物以非包裹形式进行官能化。各种实施方案提供以非包装方式非共价结合碳纳米管的聚合物。例如，提供聚合物的各种实施方案，其包含相对于其直径相反的适于与碳纳米管基本上沿着纳米管长度非共价键合的相对刚性的主链。在优选的聚合物中，聚合物主链和纳米管表面之间的主要相互作用是平行的π-堆叠。聚合物还包含至少一个来自主链的功能性延伸，其为适于溶解碳纳米管的各种所需官能团中的任何一种。

4. 发明申请

US20120259073A1 METHODS FOR THE SYNTHESIS OF MODULAR POLY(PHENYLENEETHYNYLENES) AND FINE TUNING THE ELECTRONIC PROPERTIES THEREOF FOR THE FUNCTIONALIZATION OF NANOMATERIALS 审中-公开
标题翻译：用于合成聚亚烷基（苯乙烯）的方法和微调其电子性能的纳米材料的功能化
公开(公告)号：US20120259073A1
公开(公告)日：2012-10-11
申请号：US13474418
申请日：2012-05-17
申请人： Hassan Ait-Haddou , Marni Rutkofsky
发明人： Hassan Ait-Haddou , Marni Rutkofsky
IPC分类号： C08G61/12
CPC分类号： H01B1/125 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B32/18 , C01B2202/02 , C01B2202/06 , C08G61/02 , C08K9/08
摘要： Poly(aryleneethynylene) polymers for exfoliating and dispersing/solubilizing nanomaterial are provided herein. The poly(aryleneethynylene) polymers have unit monomer portions, each monomer portion having at least one electron donating substituent thereby forming an electron donor monomer portion, or at least one electron withdrawing substituent thereby forming an electron accepting monomer portion. Such polymers exfoliate and disperse nanomaterial without presonication of the nanomaterial.
摘要翻译：本文提供了用于剥离和分散/增溶纳米材料的聚（亚芳基亚乙炔基）聚合物。聚（亚芳基亚乙炔基）聚合物具有单元单体部分，每个单体部分具有至少一个给电子取代基，从而形成电子给体单体部分，或至少一个吸电子取代基，从而形成电子接受单体部分。这种聚合物在纳米材料的预先分解的情况下剥离和分散纳米材料。

5. 发明授权

US07547472B2 Polymer and method for using the polymer for noncovalently functionalizing nanotubes 有权
标题翻译：聚合物和使用聚合物非共价官能化纳米管的方法
公开(公告)号：US07547472B2
公开(公告)日：2009-06-16
申请号：US11775005
申请日：2007-07-09
申请人： Jian Chen , Haiying Liu
发明人： Jian Chen , Haiying Liu
IPC分类号： B32B9/04
CPC分类号： D01F11/14 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/28 , C08G61/02 , C08G61/122 , C08G61/124 , C08G61/126 , Y10S977/737 , Y10S977/847 , Y10T428/2918 , Y10T428/2975 , Y10T428/30
摘要： A new, non-wrapping approach to functionalizing nanotubes, such as carbon nanotubes, in organic and inorganic solvents is provided. In accordance with certain embodiments, carbon nanotube surfaces are functionalized in a non-wrapping fashion by functional conjugated polymers that include functional groups. Various embodiments provide polymers that noncovalently bond with carbon nanotubes in a non-wrapping fashion. For example, various embodiments of polymers are provided that comprise a relatively rigid backbone that is suitable for noncovalently bonding with a carbon nanotube substantially along the nanotube's length, as opposed to about its diameter. In preferred polymers, the major interaction between the polymer backbone and the nanotube surface is parallel π-stacking. In certain implementations, the polymers further comprise at least one functional extension from the backbone that are any of various desired functional groups for functionalizing a carbon nanotube.
摘要翻译：提供了一种在有机和无机溶剂中对纳米管（如碳纳米管）进行功能化的新的非包装方法。根据某些实施方案，碳纳米管表面通过包括官能团的官能共轭聚合物以非包裹的方式被官能化。各种实施方案提供以非包装方式非共价结合碳纳米管的聚合物。例如，提供聚合物的各种实施方案，其包含相对于其直径相反的适于与碳纳米管基本上沿着纳米管长度非共价键合的相对刚性的主链。在优选的聚合物中，聚合物主链和纳米管表面之间的主要相互作用是平行的π-堆叠。在某些实施方案中，聚合物还包含至少一个来自主链的功能性延伸，其为用于官能化碳纳米管的各种所需官能团中的任何一种。

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