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1. 发明授权

US12138564B2 Method for removing inert gas from liquid ammonia 有权
公开(公告)号：US12138564B2
公开(公告)日：2024-11-12
申请号：US17277499
申请日：2019-09-13
申请人： thyssenkrupp Industrial Solutions AG , thyssenkrupp AG
发明人： Klaus Nölker
IPC分类号： B01D19/00 , B01D1/28 , B01D5/00 , C01C1/02
CPC分类号： B01D19/0073 , B01D1/2887 , B01D5/006 , B01D5/0069 , B01D5/0093 , B01D19/0036 , C01C1/024
摘要： A method of removing inert gas dissolved in liquid ammonia involves evaporating, compressing, and then condensing the liquid ammonia together with the inert gas dissolved therein. Thereby, a product stream of warm liquid ammonia that has been freed of the inert gas is obtained, which is under elevated pressure relative to standard pressure and hence suitable for immediate use in methods in which pure liquid pressurized ammonia is required. If, by contrast, the ammonia is cooled first, for example, below the boiling temperature for ammonia and expanded to standard pressure to store it in tanks as liquid ammonia at low temperatures, it is necessary first to reheat and compress it for further processing operations. Thus the disclosed methods lead to significant energy savings.

2. 发明授权

US12030838B2 Method and system for the production of methanol 有权
公开(公告)号：US12030838B2
公开(公告)日：2024-07-09
申请号：US17688371
申请日：2022-03-07
申请人： thyssenkrupp Industrial Solutions AG , thyssenkrupp AG
发明人： Alexander Schulz , Steffen Schirrmeister
IPC分类号： C07C29/151 , C07C29/74 , C07C29/78 , C07C29/80 , C07C31/04 , C10J1/00 , C10L3/08 , C25B1/04 , C25B15/08 , F25J3/02
CPC分类号： C07C29/1512 , C07C29/1518 , C07C29/78 , C07C29/80 , C10J1/00 , C10L3/08 , C25B1/04 , C25B15/08 , F25J3/0223 , C10J2300/1665 , C10L2290/08 , C10L2290/10 , C10L2290/24 , C10L2290/38 , C10L2290/46 , C10L2290/54 , C10L2290/543 , Y02E60/36 , Y02P20/133 , C07C29/1518 , C07C31/04 , C07C29/80 , C07C31/04 , C07C29/78 , C07C31/04
摘要： A process for preparing methanol by a methanol synthesis reaction of carbon dioxide with hydrogen may involve a distillation step and a condensation step following the synthesis of a crude methanol. A volatile component and water may be separated off from a methanol-containing product stream, and a gas stream containing a volatile component that has been separated off may be discharged at least partially as offgas. At least part of the gas stream that has been separated off may be recirculated into the methanol synthesis reaction. A plant for preparing methanol can store or utilize electric power generated from renewable energy sources and provide facilities for discharging the offgas stream, which can be purified by catalytic after-combustion. Alternatively, the plant can be configured without discharge of an offgas substream, or the offgas streams are so small that they can be released without treatment into the environment at a suitable position.

3. 发明授权

US12006848B2 Device and method for the utilisation of low-temperature heat by decoupling the low-temperature heat from process gas, and use 有权
公开(公告)号：US12006848B2
公开(公告)日：2024-06-11
申请号：US17280955
申请日：2020-05-13
申请人： thyssenkrupp Industrial Solutions AG , thyssenkrupp AG
发明人： Marco Scholz
IPC分类号： F01K23/06 , F01K3/18
CPC分类号： F01K23/064 , F01K3/188
摘要： A low-temperature heat utilization assembly may be configured to decouple low-temperature heat from process gas at temperatures below 200° C. and to provide the process gas at a lowered intermediate temperature or at a still further lowered final temperature for at least one subsequent process. In the low-temperature heat utilization assembly the process gas may be fed to a first unit, by means of which the temperature may be lowered to the intermediate temperature. The process gas may in some cases be provided to a heat exchanger stage for further lowering to the final temperature. The first unit is an ORC unit for energy transformation of the heat energy into electrical energy and may be coupled to an electrical consumer unit. The ORC unit may be configured for energy feedback of electrical energy within the low-temperature heat utilization assembly or to a process upstream of the ORC unit.

4. 发明授权

US11958744B2 Method and device for producing ammonia or hydrogen and use of the device 有权
公开(公告)号：US11958744B2
公开(公告)日：2024-04-16
申请号：US17261206
申请日：2019-07-18
申请人： THYSSENKRUPP INDUSTRIAL SOLUTIONS AG , thyssenkrupp AG
发明人： Sebastian Sigge , Klaus Nölker , Steffen Jahn
IPC分类号： C01B3/02 , C01B3/34 , C01C1/04
CPC分类号： C01B3/025 , C01B3/34 , C01C1/0452 , C01B2203/0233 , C01B2203/068 , C01B2203/0833 , C01B2203/0883
摘要： An apparatus for producing ammonia or hydrogen may include a) a gas stream feed conduit having a connecting conduit to a steam reformer with a waste heat section; b) a heat exchanger downstream of the gas stream feed conduit; c) a gas stream preheater downstream of the heat exchanger; d) a recirculation conduit which is located downstream of the gas stream preheater and leads to the gas stream feed conduit or, upstream of the heat exchanger, to the connecting conduit; and e) the steam reformer with the waste heat section, where the waste heat section may be in thermal contact with the gas stream preheater and the flow of the gas stream which has been heated in the gas stream preheater through the recirculation conduit can be regulated. A process for producing ammonia or hydrogen may employ such an apparatus.

5. 发明授权

US09803919B2 Method for drying a humid polymer powder and device suitable for said method 有权
公开(公告)号：US09803919B2
公开(公告)日：2017-10-31
申请号：US14004210
申请日：2012-02-23
申请人： Michael Benje , Peter Kammerhofer
发明人： Michael Benje , Peter Kammerhofer
IPC分类号： F26B3/08 , F26B3/02 , B29B13/06 , F26B3/084 , F26B23/00 , C08F6/00 , F26B23/10
CPC分类号： F26B3/02 , B01J2219/00006 , B29B13/065 , C08F6/005 , F26B3/084 , F26B23/001 , F26B23/10 , Y02P20/124 , Y02P70/405
摘要： An apparatus (1) and method for drying polymer powders is described. The apparatus has an inlet (2) and an outlet (3) for the polymer powder, heat registers (5) installed in the interior space (4) and lines (7) for a heated gas (6a) for drying the polymer powder. The lines open into the interior space (4) and are connected to heat exchangers (9) for heating gas (6). The heat exchangers (9) are connected to a plant for the preparation of 1,2-dichloroethane (15) and/or for the preparation of vinyl chloride from 1,2-dichloroethane so that thermal energy from the plant can be utilized for heating the gas (6). The method comprises treatment of a polymer powder with a heated gas (6a) in the drying apparatus (1).

6. 发明授权

US09421513B2 Catalyst-coated support, method for the production thereof, a reactor equipped therewith, and use thereof 有权
标题翻译：催化剂涂覆的载体，其制备方法，装备有反应器的反应器及其用途
公开(公告)号：US09421513B2
公开(公告)日：2016-08-23
申请号：US13380142
申请日：2010-06-23
申请人： Steffen Schirrmeister , Martin Schmitz-Niederau , Ingo Klüppel , Christoph Filthaut
发明人： Steffen Schirrmeister , Martin Schmitz-Niederau , Ingo Klüppel , Christoph Filthaut
IPC分类号： B01J12/00 , B01J19/00 , B01J21/08 , B01J19/24 , B01J23/52 , B01J35/10 , B01J37/02 , B01J37/34 , C07C45/35 , C07C51/215 , C07C67/05 , B01D53/86 , B01J23/66 , B01J35/00 , B01J37/00
CPC分类号： B01J19/249 , B01D53/86 , B01D2257/7022 , B01J12/007 , B01J19/0093 , B01J21/08 , B01J23/52 , B01J23/66 , B01J35/006 , B01J35/10 , B01J35/1066 , B01J37/0045 , B01J37/0217 , B01J37/0225 , B01J37/0232 , B01J37/0244 , B01J37/349 , B01J2219/00783 , B01J2219/00788 , B01J2219/00822 , B01J2219/00824 , B01J2219/00835 , B01J2219/00837 , B01J2219/00846 , B01J2219/0086 , B01J2219/2453 , B01J2219/2458 , B01J2219/2459 , B01J2219/2479 , C07C45/35 , C07C51/215 , C07C67/05 , C07C47/22 , C07C53/08 , C07C69/15
摘要： A catalyst-coated support including a sheetlike support, a primer layer applied thereto and composed of nanoparticles composed of silicon oxide-comprising material, and at least one catalyst layer applied to the primer layer. The layers applied are notable for a particularly good adhesive bond strength and can be used particularly efficiently in heterogeneously catalyzed gas phase reactions, especially in microreactors.
摘要翻译：一种催化剂涂覆的载体，包括片状载体，施加到其上的底漆层，由含有氧化硅的材料构成的纳米颗粒构成，以及至少一个施加到底漆层的催化剂层。施加的层是特别好的粘合剂粘合强度的特征，并且可以特别有效地用于非均相催化的气相反应中，特别是在微反应器中。

7. 发明授权

US09303210B2 Apparatus and process for the discharge of quenched or unquenched coke from a coke quenching car into a receiving device 有权
标题翻译：将淬火或未淬火的焦炭从焦炭淬火车排放到接收装置中的装置和方法
公开(公告)号：US09303210B2
公开(公告)日：2016-04-05
申请号：US13511862
申请日：2010-11-12
申请人： Sven Badura
发明人： Sven Badura
IPC分类号： C10B39/12 , C10B33/10 , C10B33/08 , C10B39/04 , C10B45/00
CPC分类号： C10B39/12 , C10B33/08 , C10B33/10 , C10B39/04 , C10B45/00
摘要： An apparatus for the discharge of quenched or unquenched coke from a coke quenching car into a receiving device, providing that there is an extension of the pusher machine beside at least one coke-oven chamber, which is arranged in one line with the coke-oven chambers, and which is to be operated by the pusher machine, and that there is a receiving device behind the quenching car as seen from the coke-oven battery into which the coke can be pushed from the quenching car by the extension, the receiving device preferably being a wharf. A process for the discharge of the hot coke from a coke quenching car into a receiving device is also disclosed. Capacity bottlenecks of the quenching equipment are compensated so that the coke need not stay in the coke-oven chamber after the end of the coking process, or disturbances of the quenching equipment can be compensated temporarily.
摘要翻译：一种用于将淬火或未熄焦的焦炭从焦化淬火车排放到接收装置中的装置，只要在至少一个焦炉室之间存在推进器机器的延伸部分，该焦炉室与焦炉一起排列并且由推进器操作，并且在从焦化炉电池观察到的淬火车后面存在接收装置，焦炭可以通过延伸从淬火车推到该接收装置中，接收装置最好是一个码头。还公开了一种将焦炭从焦炭熄灭车排放到接收装置中的方法。淬火设备的容量瓶颈被补偿，使得焦炭在焦化过程结束后不需要停留在焦炉室中，或者可以暂时补偿淬火设备的干扰。

8. 发明授权

US09249069B2 Method for removing high-boiling hydrocarbons from solvent flows 有权
标题翻译：从溶剂流中除去高沸点烃的方法
公开(公告)号：US09249069B2
公开(公告)日：2016-02-02
申请号：US13885935
申请日：2011-11-11
申请人： Johannes Menzel , Holger Thielert
发明人： Johannes Menzel , Holger Thielert
IPC分类号： C07C7/08 , C10G21/28 , C07C7/00 , C10G21/06
CPC分类号： C07C7/005 , C07C7/08 , C10G21/06 , C10G21/28 , C10G2300/4081 , C10G2300/44 , C10G2300/805
摘要： A method for removing high-boiling hydrocarbons from water-soluble solvent flows, wherein said solvent flows are produced in industrial processes which circulate a solvent as a part of the process, and the solvent must be periodically or permanently freed of high-boiling hydrocarbons which influence the quality or the desired properties of the solvent in an unwanted way, and water is added for carrying out the method in a phase separator, so that the high-boiling hydrocarbons are separated off because of their immiscibility with water, and then the water-miscible phase containing water and solvent is returned to the process. According to the invention, the proportion of high-boiling hydrocarbons in circulating solvents in an industrial process can be kept permanently low.
摘要翻译：一种从水溶性溶剂流中除去高沸点烃的方法，其中所述溶剂流是在作为该方法的一部分循环溶剂的工业过程中产生的，溶剂必须周期性地或永久性地除去高沸点烃，以不需要的方式影响溶剂的质量或期望的性质，并且在相分离器中加入水以进行该方法，使得高沸点烃因为与水的不混溶而分离出来，然后将水含有水和溶剂的可混溶相返回到该过程中。根据本发明，在工业过程中循环溶剂中的高沸点烃的比例可以保持永久地低。

9. 发明授权

US09132380B2 Method and apparatus for decomposing nitrosamines formed in removing CO2 from flue gases using an aqueous amine solution 有权
标题翻译：使用胺水溶液分解从烟道气中除去二氧化碳形成的亚硝胺的方法和装置
公开(公告)号：US09132380B2
公开(公告)日：2015-09-15
申请号：US13945318
申请日：2013-07-18
申请人： Johannes Menzel
发明人： Johannes Menzel
IPC分类号： B01D53/14 , B01D53/00
CPC分类号： B01D53/1425 , B01D53/007 , B01D53/1475 , B01D2259/804 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： The invention relates to a method and apparatus for reducing nitrosamines, formed in removal of CO2 from off-gases by means of an aqueous amine solution. A substream of the aqueous amine solution, loaded with nitrosamines, is branched off from a washing fluid circulation and is concentrated by evaporating water and low-boiling constituents. The concentrated amine solution is retained at the boiling point in a unit in which a liquid phase and a vapor phase are in contact to establish a vapor/fluid equilibrium between the phases. The vapor phase is irradiated with UV light, which decomposes nitrosamines entering the vapor phase. Following decomposition of nitrosamines, the concentrated amine solution is recycled to the washing fluid circulation for further use in the scrubber.
摘要翻译：本发明涉及一种用于还原亚硝胺的方法和装置，其通过胺水溶液从废气中除去CO 2形成。装载有亚硝胺的胺水溶液的分流从洗涤液循环中分出，并通过蒸发水和低沸点组分来浓缩。浓胺溶液保持在液相和气相接触的单位的沸点，以确定相之间的蒸汽/流体平衡。用紫外光照射蒸气相，其分解进入气相的亚硝胺。亚硝胺分解后，将浓胺溶液再循环至洗涤液循环，以进一步用于洗涤器。

10. 发明授权

US08900334B2 Method for supplying an entrained-flow gasification reactor with fuel from a storage container 有权
标题翻译：从夹带式气化反应器供给来自储存容器的燃料的方法
公开(公告)号：US08900334B2
公开(公告)日：2014-12-02
申请号：US13138280
申请日：2009-12-23
申请人： Johannes Kowoll , Stefan Hamel , Michael Rieger
发明人： Johannes Kowoll , Stefan Hamel , Michael Rieger
IPC分类号： C10J3/46 , C01B3/02 , C10J3/50
CPC分类号： C10J3/50 , C10J3/466 , C10J3/506 , C10J2200/15 , C10J2200/156 , Y02E50/32 , Y10T137/0329
摘要： The goal of the invention consists in making available a method for supplying fuel to a pressurized gasification system, which ensures, in economically efficient manner, that the emission of pollutants from the coal transfer and the transport is minimized or completely avoided. This is achieved in that a gas that contains at least 10 ppm vol. CO is used for transfer and/or conveying, whereby a gas that contains oxygen is mixed into this gas, and that this gas mixture is heated to a temperature that oxidizes at least 10% of the pollutants contained in the gas.
摘要翻译：本发明的目的在于提供一种向加压气化系统供应燃料的方法，其以经济上有效的方式确保将来自煤炭转运和运输的污染物排放最小化或完全避免。这是通过一种含有至少10ppm体积的气体来实现的。 CO用于转移和/或输送，由此将含有氧的气体混合到该气体中，并将该气体混合物加热至氧化气体中所含污染物的至少10％的温度。

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