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    • 5. 发明公开
    • ACTIVE ENERGY RAY-CURABLE INKJET PRINTING INK COMPOSITION
    • US20230287229A1
    • 2023-09-14
    • US18005586
    • 2021-07-08
    • SAKATA INX CORPORATION
    • Okinori NAKASHIMATakuya MYOSEJun KAWABATA
    • C09D11/38C09D11/32
    • C09D11/38C09D11/32
    • An object is to provide an active energy ray-curable inkjet printing ink composition that can demonstrate the effects of low viscosity, with its coating film generating no odor once cured while exhibiting excellent curability and no tackiness, and cured coating film demonstrating excellent bending tolerance property, abrasion resistance, and water resistance. As a solution, an active energy ray-curable inkjet printing ink composition satisfying requirements A to E below is provided:



      (A) the content of amine-modified oligomer is 1.0 to 20.0% by mass in the active energy ray-curable inkjet printing ink composition;
      (B) alkoxy group-containing (meth)acrylate monomers are contained by 2.0 to 20.0% by mass in the active energy ray-curable inkjet printing ink composition;
      (C) (meth)acrylate monomers having an alkyl group with 6 to 20 carbon atoms is contained by 2.0 to 25.0% by mass in the active energy ray-curable inkjet printing ink composition;
      (D) at least one type selected from the group that consists of 1,6-hexanediol diacrylate, 3-methyl-1,5-pentanediol diacrylate, dipropylene glycol diacrylate, 1,10-decanediol diacrylate, propoxylated(2)neopentyl glycol diacrylate, and hydroxypivalic acid neopentyl glycol diacrylate is contained by 30.0 to 60.0% by mass in the active energy ray-curable inkjet printing ink composition;
      (E) as photopolymerization initiators, ethoxy(2,4,6-trimethylbenzoyl)phenylphosphine oxide is contained by 3.0 to 15.0% by mass in the active energy ray-curable inkjet printing ink composition, and oligo(2-hydroxy-2-methyl-1-(4-(1-methylvinyl)phenyl)propanone) and/or 2-hydroxy-1-{4-[4-(2-hydroxy-2-methylpropionyl)phenoxy]phenyl}-2-methylpropanone is/are contained by 2.0 to 10.0% by mass in the active energy ray-curable inkjet printing ink composition, where the total content of photopolymerization initiators is 6.0 to 25.0% by mass in the active energy ray-curable inkjet printing ink composition.