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    • 1. 发明申请
    • POLYMER USEFUL AS VISCOSITY INDEX IMPROVER
    • 聚合物用作粘度指数改进
    • US20120302477A1
    • 2012-11-29
    • US13576098
    • 2011-02-24
    • Justin August LangstonJen-Lung WangPeter Moore
    • Justin August LangstonJen-Lung WangPeter Moore
    • C10M145/14C08F20/14C08F20/18
    • C10M145/14C08F220/18C10M145/16C10M2203/1025C10M2209/084C10M2209/086C10N2230/02C10N2230/68C10N2240/042C10N2240/045C10N2240/046C10N2270/00C10N2260/02
    • The present invention describes a polymer useful as viscosity index improver comprising units derived from one or more ethylenically unsaturated ester compounds of formula (I), where R is hydrogen or methyl, R1 means a linear, branched or cyclic alkyl residue with 1-6 carbon atoms, R2 and R3 independently represent hydrogen or a group of the formula —COOR′, where R′ means hydrogen or a alkyl group with 1-6 carbon atoms, units of one or more ethylenically unsaturated ester compounds of formula (II), where R is hydrogen or methyl, R4 means a 2-alkyl branched alkyl residue with 12-18 carbon atoms, R5 and R6 independently are hydrogen or a group of the formula —COOR″, where R″ means hydrogen or an alkyl group with 12-18 carbon atoms, and units of one or more ethylenically unsaturated ester compounds of formula (III), where R is hydrogen or methyl, R7 means a linear alkyl residue with 12-24 carbon atoms, R8 and R9 independently are hydrogen or a group of the formula —COOR″, where R″ means hydrogen or an alkyl group with 12-24 carbon atoms wherein said polymer comprises at least 10% by weight units derived from one or more ethylenically unsaturated ester compounds of formula (I), based on the total weight of the polymer, said polymer comprises at least 10% by weight units derived from one or more ethylenically unsaturated ester compounds of formula (II), based on the total weight of the polymer, and said polymer comprises at least 10% by weight units derived from one or more ethylenically unsaturated ester compounds of formula (III), based on the total weight of the polymer.
    • 本发明描述了可用作粘度指数改进剂的聚合物,其包含衍生自一种或多种式(I)的烯属不饱和酯化合物的单元,其中R是氢或甲基,R 1表示具有1-6个碳原子的直链,支链或环状烷基 原子,R2和R3独立地表示氢或式-COOR'的基团,其中R'表示氢或具有1-6个碳原子的烷基,一个或多个式(II)的烯属不饱和酯化合物的单元,其中 R是氢或甲基,R4表示具有12-18个碳原子的2-烷基支链烷基,R5和R6独立地是氢或式-COOR“的基团,其中R”表示氢或具有12- 18个碳原子和一个或多个式(III)的烯属不饱和酯化合物的单元,其中R是氢或甲基,R7表示具有12-24个碳原子的直链烷基,R8和R9独立地是氢或一个 式-COOR“, 其中R“表示氢或具有12-24个碳原子的烷基,其中所述聚合物包含衍生自一种或多种式(I)的烯属不饱和酯化合物的至少10重量%单元,基于聚合物的总重量, 所述聚合物包含至少10重量%的衍生自一种或多种式(II)的烯属不饱和酯化合物的单元,基于聚合物的总重量,并且所述聚合物包含至少10重量%的衍生自一个或多个 式(III)的烯属不饱和酯化合物,基于聚合物的总重量。
    • 3. 发明授权
    • Method for the determination of the oxidative stability of a lubricating fluid
    • 确定润滑液的氧化稳定性的方法
    • US08021885B2
    • 2011-09-20
    • US11545421
    • 2006-10-11
    • Bernard KinkerRaymond Romaszewski
    • Bernard KinkerRaymond Romaszewski
    • G01N33/03
    • G01N33/2888
    • The present invention concerns a method for the determination of the oxidative stability of a lubricating fluid, comprising the steps of: introducing a sample of the lubricating fluid under test in an reaction cell; introducing catalytic amounts of a catalyst to the reaction cell; heating the cell to the oxidation temperature of the lubricating fluid and maintaining this temperature; delivering oxygen containing gas at constant flow rate through the cell over the course of the reaction; delivering a gas comprising nitrogen dioxide at a constant flow rate through the cell for a specified time; applying and maintaining a specified vacuum on the reaction cell; allowing the mixture to react for a specified time; measuring the viscosity of the oxidized lubricating fluid. Additionally, the present invention describes an apparatus for the determination of the oxidative stability of a lubricating fluid.
    • 本发明涉及一种确定润滑液的氧化稳定性的方法,包括以下步骤:将待测润滑液的样品引入反应池中; 将催化量的催化剂引入反应池; 将电池加热至润滑液的氧化温度并维持该温度; 在反应过程中以恒定流速输送含氧气体通过电池; 以恒定流速通过电池输送包含二氧化氮一定时间的气体; 在反应池上施加和保持指定的真空; 允许混合物反应一定时间; 测量氧化润滑液的粘度。 此外,本发明描述了一种用于确定润滑流体的氧化稳定性的装置。
    • 4. 发明申请
    • Oil Soluble Comb Polymers
    • 油溶性梳子聚合物
    • US20080194443A1
    • 2008-08-14
    • US11909171
    • 2006-04-07
    • Torsten StohrBoris EisenbergMichael Muller
    • Torsten StohrBoris EisenbergMichael Muller
    • C08F120/00C08F112/08C08F136/00C10M169/04
    • C08F290/04C08F299/00C10M159/005C10M2203/1006C10M2203/1025C10M2205/028C10M2205/0285C10M2209/04C10M2209/062C10M2209/084C10M2209/086C10N2220/021C10N2220/028C10N2230/02C10N2230/04C10N2230/06C10N2230/68C10N2220/022
    • The invention relates to comb polymers which comprise, in the main chain, repeating units which are derived from polyolefin-based macromonomers, and repeating units which are derived from low molecular monomers which are selected from the group consisting of styrene monomers having 8-17 carbon atoms, alkyl(meth)acrylates having 1-10 carbon atoms in the alcohol group, vinyl esters having 1-11 carbon atoms in the acyl group, vinyl ethers having 1-10 carbon atoms in the alcohol group, (Di)alkylfumarates having 1-10 carbon atoms in the alcohol group, (Di)alkylmaleates having 1-10 carbon atoms in the alcohol group and mixtures of said monomers. The molar branching degree lies in the region between 0.1-10 mol. % and the comb polymer represents the sum of at least 80 wt. %, in relation to the weight of the repeating units, on repeating units which are derived from polyolefin-based macromonomers, and repeating units which are selected from low molecular monomers which are selected from the group consisting of styrene monomers having 8-17 carbon atoms, alkyl(meth)acrylates having 1-10 carbon atoms in the alcohol group, vinyl esters having 1-11 carbon atoms in the acyl group, vinyl ethers having 1-10 carbon atoms in the alcohol group, (Di)alkylfumarates having 1-10 carbon atoms in the alcohol group, (Di)alkylmaleates having 1-10 carbon atoms in the alcohol group, and mixtures of said monomers.
    • 本发明涉及在主链中包含衍生自聚烯烃基大分子单体的重复单元和衍生自低分子单体的重复单元的梳状聚合物,所述低分子单体选自具有8-17个碳原子的苯乙烯单体 原子,醇基中具有1-10个碳原子的(甲基)丙烯酸烷基酯,酰基中具有1-11个碳原子的乙烯基酯,醇基中具有1-10个碳原子的乙烯基醚,具有1个碳原子的(Di)烷基富马酸盐 -10个碳原子,醇基中具有1-10个碳原子的(Di)烷基马来酸酯和所述单体的混合物。 摩尔分支度位于0.1-10mol之间的区域。 %,梳状聚合物代表至少80wt。 相对于重复单元的重量,衍生自聚烯烃基大分子单体的重复单元的重复单元和选自具有8-17个碳原子的苯乙烯单体的低分子单体的重复单元 ,醇基中具有1-10个碳原子的(甲基)丙烯酸烷基酯,酰基中具有1-11个碳原子的乙烯基酯,醇基中具有1-10个碳原子的乙烯基醚,具有1- 醇基中的10个碳原子,醇基中具有1-10个碳原子的(Di)烷基马来酸化物,以及所述单体的混合物。
    • 5. 发明申请
    • USE OF GRAFT POLYMERS
    • 聚合物的使用
    • US20070213237A1
    • 2007-09-13
    • US11572181
    • 2005-06-23
    • Markus SchererKlaus HedrichAlexander DardinMichael MullerThorsten StoehrBoris Eisenberg
    • Markus SchererKlaus HedrichAlexander DardinMichael MullerThorsten StoehrBoris Eisenberg
    • C10M145/14
    • C10M149/10C08L51/06C10M149/02C10M161/00C10M2209/084C10M2217/02C10M2217/028C10N2220/021C10N2220/022C10N2230/02C10N2230/04C10N2230/06C10N2230/43C10N2240/04C10N2240/08C10N2240/10
    • The invention relates to the use of graft polymers obtained by polymerization in two stages. In a first stage, at least one graft basis is produced by radically polymerizing a monomer composition A) containing 0 to 40 percent by weight of one or several ethylenically unsaturated ester compounds of formula (I), wherein R represents hydrogen or methyl, R1 represents a linear or branched alkyl radical comprising 1 to 5 carbon atoms, R2 and R3 independently represent hydrogen or a group of formula —COOR′, wherein R′ represents hydrogen or an alkyl group comprising 1 to 5 carbon atoms, 60 to 100 percent by weight of one or several ethylenically unsaturated ester compounds of formula (II), wherein R represents hydrogen or methyl, R4 represents a linear or branched alkyl radical comprising 6 to 40 carbon atoms, R5 and R6 independently represent hydrogen or a group of formula —COOR′, wherein R′ represents hydrogen or an alkyl group comprising 6 to 40 carbon atoms, and 0 to 40 percent by weight of comonomers, the percentages being relative to the weight of monomer composition A). In a second stage, a monomer composition B) containing 20 to 100 percent by weight of at least one monomer that comprises at least one nitrogen-containing group is grafted onto the graft basis in order to reduce wear in lubricant oil compositions. Said graft polymer comprises a maximum of 200 ppm of sulfur while the weight ratio between monomer composition A) and monomer composition B) ranges between 99.7:0.3 and 80:20.
    • 本发明涉及通过两步聚合获得的接枝聚合物的用途。 在第一阶段中,通过自由基聚合含有0至40重量%的一种或几种式(I)的烯键式不饱和酯化合物,其中R表示氢或甲基, SUP> 1表示包含1至5个碳原子的直链或支链烷基,R 2和R 3独立地表示氢或式-COOR基团 ',其中R'表示氢或包含1至5个碳原子的烷基,60至100重量%的一种或几种式(II)的烯属不饱和酯化合物,其中R表示氢或甲基,R 4 代表含有6至40个碳原子的直链或支链烷基,R 5和R 6独立代表氢或式-COOR'基团,其中 R'表示氢或含有6〜40个碳原子的烷基,0〜40重量%的共聚单体,百分比 年龄相对于单体组合物A)的重量。 在第二阶段中,将包含20至100重量%的至少一种包含至少一个含氮基团的单体的单体组合物B)接枝到接枝基上以减少润滑油组合物中的磨损。 所述接枝聚合物包含最多200ppm的硫,而单体组合物A)和单体组合物B)之间的重量比在99.7:0.3和80:20之间。
    • 10. 发明授权
    • Oil soluble comb polymers
    • 油溶性梳状聚合物
    • US08067349B2
    • 2011-11-29
    • US11909171
    • 2006-04-07
    • Torsten StoehrBoris EisenbergMichael Mueller
    • Torsten StoehrBoris EisenbergMichael Mueller
    • C10M145/14C10M149/04C10L1/18
    • C08F290/04C08F299/00C10M159/005C10M2203/1006C10M2203/1025C10M2205/028C10M2205/0285C10M2209/04C10M2209/062C10M2209/084C10M2209/086C10N2220/021C10N2220/028C10N2230/02C10N2230/04C10N2230/06C10N2230/68C10N2220/022
    • The invention relates to comb polymers which comprise, in the main chain, repeating units which are derived from polyolefin-based macromonomers, and repeating units which are derived from low molecular monomers which are selected from the group consisting of styrene monomers having 8-17 carbon atoms, alkyl(meth)acrylates having 1-10 carbon atoms in the alcohol group, vinyl esters having 1-11 carbon atoms in the acyl group, vinyl ethers having 1-10 carbon atoms in the alcohol group, (Di)alkylfumarates having 1-10 carbon atoms in the alcohol group, (Di)alkylmaleates having 1-10 carbon atoms in the alcohol group and mixtures of said monomers. The molar branching degree lies in the region between 0.1-10 mol. % and the comb polymer represents the sum of at least 80 wt. %, in relation to the weight of the repeating units, on repeating units which are derived from polyolefin-based macromonomers, and repeating units which are selected from low molecular monomers which are selected from the group consisting of styrene monomers having 8-17 carbon atoms, alkyl(meth)acrylates having 1-10 carbon atoms in the alcohol group, vinyl esters having 1-11 carbon atoms in the acyl group, vinyl ethers having 1-10 carbon atoms in the alcohol group, (Di)alkylfumarates having 1-10 carbon atoms in the alcohol group, (Di)alkylmaleates having 1-10 carbon atoms in the alcohol group, and mixtures of said monomers.
    • 本发明涉及在主链中包含衍生自聚烯烃基大分子单体的重复单元和衍生自低分子单体的重复单元的梳状聚合物,所述低分子单体选自具有8-17个碳原子的苯乙烯单体 原子,醇基中具有1-10个碳原子的(甲基)丙烯酸烷基酯,酰基中具有1-11个碳原子的乙烯基酯,醇基中具有1-10个碳原子的乙烯基醚,具有1个碳原子的(Di)烷基富马酸盐 -10个碳原子,醇基中具有1-10个碳原子的(Di)烷基马来酸酯和所述单体的混合物。 摩尔分支度位于0.1-10mol之间的区域。 %,梳状聚合物代表至少80wt。 相对于重复单元的重量,衍生自聚烯烃基大分子单体的重复单元的重复单元和选自具有8-17个碳原子的苯乙烯单体的低分子单体的重复单元 ,醇基中具有1-10个碳原子的(甲基)丙烯酸烷基酯,酰基中具有1-11个碳原子的乙烯基酯,醇基中具有1-10个碳原子的乙烯基醚,具有1- 醇基中的10个碳原子,醇基中具有1-10个碳原子的(Di)烷基马来酸化物,以及所述单体的混合物。