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    • 5. 发明授权
    • Supported polymerization catalyst
    • 负载型聚合催化剂
    • US5424263A
    • 1995-06-13
    • US52317
    • 1993-04-23
    • Charles K. Buehler
    • Charles K. Buehler
    • B01J31/02B01J31/12B01J31/14C08F4/60C08F10/00B01J31/00C08F4/02
    • B01J31/0214B01J31/0212B01J31/0274B01J31/128B01J31/143C08F10/00
    • A catalyst component useful in the polymerization of olefins is disclosed. The catalyst component comprises the product obtained by steps of (a) contacting silica with at least one hydrocarbon soluble magnesium-containing compound; (b) contacting the product of step (a) with component (1), a heterocyclic fused ring compound substituted with at least one oxygen atom, and component (2), a modifying compound selected from the group consisting of silicon halides, boron halides, aluminum halides, alkyl silicon halides and mixtures thereof, with the proviso that components (1) and (2) be present such that the molar ratio of component (2) to component (1) is at least about 4:1; and (c) contacting the product of step (b) with a titanium-containing compound having the structural formula TiX.sub.m (OR).sub.n, where X is halogen; R is hydrocarbyl; m is an integer of 1 to 4; and n is 0 or an integer of 1 to 3 with the proviso that the sum of m and n is 4. A catalyst system, used in the polymerization of alpha-olefins, which comprises the catalyst component of this disclosure, an aluminum-containing compound and a silane compound is also taught. Finally, a process for the polymerization of alpha-olefins, utilizing the catalyst system of the present disclosure, is described.
    • 公开了可用于烯烃聚合的催化剂组分。 催化剂组分包括通过以下步骤获得的产物:(a)将二氧化硅与至少一种可溶于烃的含镁化合物接触; (b)使步骤(a)的产物与组分(1)接触,由至少一个氧原子取代的杂环稠环化合物和组分(2),选自卤化硅,卤化硼 ,卤化铝,烷基硅卤化物及其混合物,条件是组分(1)和(2)存在使得组分(2)与组分(1)的摩尔比为至少约4:1; 和(c)使步骤(b)的产物与具有结构式TiXm(OR)n的含钛化合物接触,其中X是卤素; R是烃基; m为1〜4的整数。 并且n为0或1至3的整数,条件是m和n的和为4.在包含本公开内容的催化剂组分的α-烯烃的聚合中使用的催化剂体系,含铝 化合物和硅烷化合物也被教导。 最后,描述了利用本公开的催化剂体系的α-烯烃的聚合方法。
    • 6. 发明授权
    • Releasable stationary plate for rheometer
    • 用于流变仪的可释放固定板
    • US5349847A
    • 1994-09-27
    • US159082
    • 1993-11-29
    • Chun D. LeeDonald L. Broughton
    • Chun D. LeeDonald L. Broughton
    • G01N11/14G01N11/16
    • G01N11/142G01N11/165
    • A stationary plate assembly for a rheometer that selectively provides steady state and dynamic testing of melt viscoelastic characteristics of a material sample. The stationary plate assembly has a stationary sample plate magnetically coupled to its supporting member. Therefore, after the steady state testing is complete, the movable plate, material sample and stationary plate may be moved vertically away from the stationary plate supporting member. Therefore, any spurious, erratic rotations of the movable plate when the rheometer is switched form the steady state test mode to the dynamic test mode will not cause a further working of the material sample.
    • 用于流变仪的固定板组件,其选择性地提供材料样品的熔体粘弹性特性的稳态和动态测试。 固定板组件具有磁性耦合到其支撑构件的固定样品板。 因此,在稳态测试完成之后,可移动板,材料样品和固定板可以垂直移动离开固定板支撑构件。 因此,当流变仪切换形成稳态测试模式到动态测试模式时,可移动板的任何虚假的,不稳定的旋转将不会导致材料样品的进一步的工作。
    • 7. 发明授权
    • Adhesive blends of ethylene-alkyl acrylate copolymers and modified
propylene-ethylene copolymers
    • 乙烯 - 丙烯酸烷基酯共聚物和改性丙烯 - 乙烯共聚物的粘合剂共混物
    • US5336721A
    • 1994-08-09
    • US46251
    • 1993-04-06
    • Webster W. Kiang
    • Webster W. Kiang
    • C09J123/08C08L33/02
    • C09J123/08Y10T428/3188Y10T428/31906Y10T428/3192Y10T428/31928
    • Improved two-component blends which exhibit good adhesion to 4-methylpentene-1 polymers and vinyl alcohol polymers and which may be used as an adhesive interlayer when laminating layers of the polymers are provided. Ethylene-alkyl acrylate copolymers, preferably ethylene n-butyl acrylate copolymers, and modified propylene polymers, preferably maleic anhydride grafted statistical propylene-ethylene copolymers and propylene-ethylene impact copolymers, are combined to obtain the blends of the invention. Useful laminated structures comprised of a layer of poly-4-methylpentene-1 homopolymer or copolymer, a layer of the adhesive blend and a layer of ethylene-vinyl alcohol copolymer with one or more optional layers, such as a paperboard, are also disclosed.
    • 提供了对4-甲基戊烯-1聚合物和乙烯醇聚合物具有良好粘附性的改进的双组分共混物,并且可以在层压聚合物层时用作粘合剂中间层。 乙烯 - 丙烯酸烷基酯共聚物,优选乙烯丙烯酸正丁酯共聚物和改性丙烯聚合物,优选马来酸酐接枝的统计丙烯 - 乙烯共聚物和丙烯 - 乙烯抗冲共聚物,以得到本发明的共混物。 还公开了由一层聚-4-甲基戊烯-1均聚物或共聚物,一层粘合剂共混物和一层乙烯 - 乙烯醇共聚物与一种或多种任选层如纸板组成的有用的层压结构。
    • 8. 发明授权
    • Process for making an aliphatic polyester by copolymerizing a cyclic
ketene acetal and an olefin and the polyester product thereof
    • 通过使环状乙烯酮缩醛与烯烃共聚而制造脂肪族聚酯的方法及其聚酯制品
    • US5270411A
    • 1993-12-14
    • US865521
    • 1992-04-09
    • Biau-Hung ChangThomas S. Brima
    • Biau-Hung ChangThomas S. Brima
    • C08F2/06C08F4/04C08F234/02C08FC08F212/06
    • C08F234/02
    • A process for making a biodegradable aliphatic polyester and the polyester so formed is disclosed. The process comprises copolymerizing a cyclic ketene acetal having the structural formula ##STR1## where R is a bivalent moiety, and an olefin. This copolymerization occurs in a solution of a tertiary alcohol and in the presence of a free radical initiating effective amount of a compound having the structural formula ##STR2## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are the same or different and are C.sub.1 -C.sub.20 hydrocarbyl, C.sub.1 -C.sub.20 hydrocarbyloxy, cyano, halogen, carboxy, carboalkoxy, carbonyl or formyl. The copolymerization occurs at a temperature in the range of between in excess of ambient temperature and less than 100.degree. C. and at a pressure in excess of about 2,000 psi. The aliphatic polyester product of this process contains repeating structural units of the formula ##STR3## where A is a radical of a polymerized olefinic monomer; R is a bivalent moiety; x is a positive integer; and y and z are 0 or a positive integer with the proviso that the sum of y and z is at least 1, ratio of x to y is in the range of between about 3:1 and about 200,000:1, the ratio of z to y is in the range of between 0 and about 0.5:1; and said polyester has a weight average molecular weight of at least about 40,000.
    • 公开了一种制造可生物降解的脂族聚酯和如此形成的聚酯的方法。 该方法包括使具有结构式“IMAGE”的环状烯酮缩醛共聚,其中R是二价部分,和烯烃。 这种共聚发生在叔醇的溶液中,并且在存在自由基的情况下,引发有效量的结构式为“IMAGE”的化合物,其中R 1,R 2,R 3,R 4,R 5和R 6相同或不同, C 1 -C 20烃基,C 1 -C 20烃氧基,氰基,卤素,羧基,烷氧羰基,羰基或甲酰基。 共聚发生在超过环境温度和小于100℃之间的温度和超过约2,000psi的压力下进行。 该方法的脂族聚酯产物含有下式的重复结构单元:其中A是聚合烯烃单体的基团; R是二价基团; x是正整数; 并且y和z为0或正整数,条件是y和z之和至少为1,x与y的比值在约3:1至约200,000:1之间,z比 y在0至约0.5:1的范围内; 并且所述聚酯具有至少约40,000的重均分子量。
    • 10. 发明授权
    • Supported high activity polypropylene catalyst component with regular
distribution of magnesium values provided utilizing a controlled drying
protocol
    • 支持的高活性聚丙烯催化剂组分,具有规定的镁值分布,使用受控的干燥方案
    • US5221650A
    • 1993-06-22
    • US854199
    • 1992-03-20
    • Charles K. Buehler
    • Charles K. Buehler
    • C08F4/654C08F10/00
    • C08F10/00
    • A novel catalyst support and a method for preparation thereof, characterized by the presence of selected amounts of a hydrocarbon soluble magnesium-containing compound applied to the support relative to solvent, wherein a surface uniformly and essentially continuously moistened with the solvated magnesium compound is achieved in a condition of incipient precipitation to permit the formation of a regular essentially continuous distribution of the magnesium compound onto and conforming to the support material The drying process under these conditions is effective in maintaining to a high degree the effective surface area and pore volume of the material. The support containing the adsorbed magnesium is then dried in a controlled manner to essential incipient wetness conditions providing a regular spatial distribution of stacked reticular magnesium values at a level of one to five molecular monolayers on the support.A representative process for polymerizing or copolymerizing olefins providing stereospecific polymers such as propylene is disclosed.
    • 一种新颖的催化剂载体及其制备方法,其特征在于相对于溶剂存在选择量的可溶于烃的可溶性镁化合物,其中用溶剂化镁化合物均匀且基本上连续润湿的表面在 初始沉淀的条件允许形成镁化合物在支撑材料上并与其一致的规则基本上连续的分布。在这些条件下的干燥过程有效地保持材料的有效表面积和孔体积的高度 。 然后将含有吸附的镁的载体以受控的方式干燥至必需的初始湿度条件,从而提供在载体上1-5个分子单层水平的堆叠网状镁值的规则空间分布。 公开了提供立体特异性聚合物如丙烯的烯烃聚合或共聚的代表性方法。