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    • 4. 发明授权
    • Sn—Zn lead-free solder alloy, its mixture, and soldered bond
    • Sn-Zn无铅焊料合金,其混合物和焊接键
    • US07179417B2
    • 2007-02-20
    • US11435614
    • 2006-05-17
    • Masaaki YoshikawaHaruo AoyamaHirotaka Tanaka
    • Masaaki YoshikawaHaruo AoyamaHirotaka Tanaka
    • B23K35/14B23K35/26
    • C22C13/00B23K35/0244B23K35/262H05K3/3484H05K2201/0224
    • An Sn—Zn lead-free solder alloy according to the present invention is constructed in a manner such that it is an Sn-based solder alloy indispensably containing 6 to 10 wt % zinc at least, and further containing 0.0015 to 0.1 wt % magnesium, said magnesium content being effective quantity for forming a protective magnesium oxide film on the solder surface and also for destroying said oxide film during soldering. When solder paste is preserved, the inside of solder particle is protected by the protective magnesium oxide film formed on the surface of solder particle, and a reaction between zinc and an activator is suppressed, so that preservation stability is improved, and at elevated temperature during soldering, a state where said protective oxide film is easily destroyed is obtained, so that good wettability is held.
    • 根据本发明的Sn-Zn无铅焊料合金是以至少含有6〜10重量%的锌,还含有0.0015〜0.1重量%的镁的Sn系焊料合金构成的, 所述镁含量是在焊料表面上形成保护性氧化镁膜的有效量,并且还用于在焊接期间破坏所述氧化膜。 当焊膏被保存时,焊料颗粒的内部由形成在焊料颗粒表面上的保护性氧化镁膜保护,锌和活化剂之间的反应被抑制,从而保持了稳定性,并且在高温下 焊接时,获得容易破坏所述保护氧化膜的状态,从而保持良好的润湿性。
    • 5. 发明授权
    • Sn-Zn lead-free solder alloy and soldered bond
    • Sn-Zn无铅焊料合金和焊接键
    • US07070736B2
    • 2006-07-04
    • US10468606
    • 2002-11-18
    • Masaaki YoshikawaHaruo AoyamaHirotaka Tanaka
    • Masaaki YoshikawaHaruo AoyamaHirotaka Tanaka
    • B23K35/26B23K20/04
    • C22C13/00B23K35/0244B23K35/262B23K35/36B23K2101/42
    • An Sn—Zn lead-free solder alloy according to the present invention is constructed in a manner such that it is an Sn-based solder alloy indispensably containing 6 to 10 wt % zinc at least and further containing 0.0015 to 0.03 wt % magnesium and 0.0010 to 0.006 wt % aluminum. Upon preservation of solder paste not only under refrigeration but also at a room temperature or higher, the inside of solder particle is protected by the protective magnesium/aluminum oxide film formed on the solder particle surface, and a reaction between zinc and an activator is suppressed, so that preservation stability is improved, and at the elevated temperature during soldering, the solder alloy enters a state where said protective oxide film is easily destroyed, so that good wettability is held.
    • 根据本发明的Sn-Zn无铅焊料合金是以至少含有至少还含有0.0015-0.03%(重量)镁和0.0010(重量%)的6至10%重量的锌的Sn基焊料合金构成的 至0.006重量%的铝。 在不仅在制冷下还能在室温以上保存焊膏的情况下,通过在焊料粒子表面形成的保护性镁/氧化铝膜来保护焊锡颗粒的内部,抑制锌与活化剂的反应 ,从而保持稳定性提高,并且在焊接时的高温下,焊料合金进入容易破坏所述保护氧化膜的状态,从而保持良好的润湿性。
    • 6. 发明授权
    • Tin-zinc lead-free solder, its mixture, and solder-joined part
    • 锡锌无铅焊料,其混合物和焊接部分
    • US07175805B2
    • 2007-02-13
    • US10468607
    • 2002-11-18
    • Masaaki YoshikawaHaruo AoyamaHirotaka Tanaka
    • Masaaki YoshikawaHaruo AoyamaHirotaka Tanaka
    • B23K35/14B23K35/26
    • C22C13/00B23K35/0244B23K35/262H05K3/3484H05K2201/0224
    • An Sn—Zn lead-free solder alloy according to the present invention is constructed in a manner such that it is an Sn-based solder alloy indispensably containing 6 to 10 wt % zinc at least, and further containing 0.0015 to 0.1 wt % magnesium, said magnesium content being effective quantity for forming a protective magnesium oxide film on the solder surface and also for destroying said oxide film during soldering. When solder paste is preserved, the inside of solder particle is protected by the protective magnesium oxide film formed on the surface of solder particle, and a reaction between zinc and an activator is suppressed, so that preservation stability is improved, and at elevated temperature during soldering, a state where said protective oxide film is easily destroyed is obtained, so that good wettability is held.
    • 根据本发明的Sn-Zn无铅焊料合金是以至少含有6〜10重量%的锌,还含有0.0015〜0.1重量%的镁的Sn系焊料合金构成的, 所述镁含量是在焊料表面上形成保护性氧化镁膜的有效量,并且还用于在焊接期间破坏所述氧化膜。 当焊膏被保存时,焊料颗粒的内部由形成在焊料颗粒表面上的保护性氧化镁膜保护,锌和活化剂之间的反应被抑制,从而保持了稳定性,并且在高温下 焊接时,获得容易破坏所述保护氧化膜的状态,从而保持良好的润湿性。
    • 7. 发明申请
    • SN-ZN LEAD-FREE SOLDER ALLOY, ITS MIXTURE, AND SOLDERED BOND
    • SN-ZN无铅焊接合金,其混合物和焊接粘合剂
    • US20060210420A1
    • 2006-09-21
    • US11435614
    • 2006-05-17
    • Masaaki YoshikawaHaruo AoyamaHirotaka Tanaka
    • Masaaki YoshikawaHaruo AoyamaHirotaka Tanaka
    • C22C13/02
    • C22C13/00B23K35/0244B23K35/262H05K3/3484H05K2201/0224
    • An Sn—Zn lead-free solder alloy according to the present invention is constructed in a manner such that it is an Sn-based solder alloy indispensably containing 6 to 10 wt % zinc at least, and further containing 0.0015 to 0.1 wt % magnesium, said magnesium content being effective quantity for forming a protective magnesium oxide film on the solder surface and also for destroying said oxide film during soldering. When solder paste is preserved, the inside of solder particle is protected by the protective magnesium oxide film formed on the surface of solder particle, and a reaction between zinc and an activator is suppressed, so that preservation stability is improved, and at elevated temperature during soldering, a state where said protective oxide film is easily destroyed is obtained, so that good wettability is held.
    • 根据本发明的Sn-Zn无铅焊料合金是以至少含有6〜10重量%的锌,还含有0.0015〜0.1重量%的镁的Sn系焊料合金构成的, 所述镁含量是在焊料表面上形成保护性氧化镁膜的有效量,并且还用于在焊接期间破坏所述氧化膜。 当焊膏被保存时,焊料颗粒的内部由形成在焊料颗粒表面上的保护性氧化镁膜保护,锌和活化剂之间的反应被抑制,从而保持了稳定性,并且在高温下 焊接时,获得容易破坏所述保护氧化膜的状态,从而保持良好的润湿性。
    • 8. 发明授权
    • Sn-Zn lead-free solder alloy, and solder junction portion
    • Sn-Zn无铅焊料合金和焊接部分
    • US07175804B2
    • 2007-02-13
    • US11433325
    • 2006-05-12
    • Masaaki YoshikawaHaruo AoyamaHirotaka Tanaka
    • Masaaki YoshikawaHaruo AoyamaHirotaka Tanaka
    • B23K35/26B23K20/04
    • C22C13/00B23K35/0244B23K35/262B23K35/36B23K2101/42
    • An Sn—Zn lead-free solder alloy according to the present invention is constructed in a manner such that it is an Sn-based solder alloy indispensably containing 6 to 10 wt % zinc at least and further containing 0.0015 to 0.03 wt % magnesium and 0.0010 to 0.006 wt % aluminum. Upon preservation of solder paste not only under refrigeration but also at a room temperature or higher, the inside of solder particle is protected by the protective magnesium/aluminum oxide film formed on the solder particle surface, and a reaction between zinc and an activator is suppressed, so that preservation stability is improved, and at the elevated temperature during soldering, the solder alloy enters a state where said protective oxide film is easily destroyed, so that good wettability is held.
    • 根据本发明的Sn-Zn无铅焊料合金是以至少含有至少还含有0.0015-0.03%(重量)镁和0.0010(重量%)的6至10%重量的锌的Sn基焊料合金构成的 至0.006重量%的铝。 在不仅在制冷下还能在室温以上保存焊膏的情况下,通过在焊料粒子表面形成的保护性镁/氧化铝膜来保护焊锡颗粒的内部,抑制锌与活化剂的反应 ,从而保持稳定性提高,并且在焊接时的高温下,焊料合金进入容易破坏所述保护氧化膜的状态,从而保持良好的润湿性。