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1. 发明授权

US5739221A Suspension-polymerization process for producing expandable styrene resin beads 失效
标题翻译：用于生产可发性苯乙烯树脂珠的悬浮聚合方法
公开(公告)号：US5739221A
公开(公告)日：1998-04-14
申请号：US643010
申请日：1996-05-03
申请人： Hiroki Shinozaki , Masayuki Tanaka , Yonezo Ueda
发明人： Hiroki Shinozaki , Masayuki Tanaka , Yonezo Ueda
IPC分类号： C08J9/20 , C08F2/18 , C08F12/00 , C08F12/08 , C08J9/16 , C08J9/18
CPC分类号： C08J9/18 , C08F12/08 , C08J9/16 , C08J2325/00 , Y10T428/2982
摘要： Expandable styrene resin beads are described, which, when expanded to a bulk density of 20 g/l, give pre-expanded beads in which the number of cells present along those surface parts of radii which range from the bead surface to a depth of 0.2 mm from the surface is from 3 to 20 per mm and to the bead center is 10 or larger per mm, the number of the number of cells present along those inner parts of the radii which range from a depth of 1 mm from the bead surface to the bead center is 10 or larger per mm, the number of cells present along said surface parts being smaller than the number of cells present along said inner parts.
摘要翻译：描述了可膨胀的苯乙烯树脂珠粒，其当膨胀至20g / l的堆积密度时，得到预发泡珠粒，其中沿着从珠粒表面到深度为0.2的半径的那些表面部分存在细胞数目距离表面的mm为3至20 / mm，并且珠中心为每mm 10mm或更大，沿着半径的内部部分存在的细胞数目，其距离珠粒表面的1mm的深度珠的中心距离为10mm或更大，沿着所述表面部分存在的细胞数小于沿着所述内部部分存在的细胞的数量。

2. 发明授权

US5661191A Expandable rubber-modified styrene resin beads, expanded beads thereof, and expanded molded articles obtained therefrom 失效
标题翻译：可膨胀橡胶改性苯乙烯树脂珠，其发泡珠和由其获得的发泡模塑制品
公开(公告)号：US5661191A
公开(公告)日：1997-08-26
申请号：US576561
申请日：1995-12-21
申请人： Kenji Haraguchi , Takanori Suzuki , Mitsuo Furuichi , Hiromi Yamanaka , Masayuki Tanaka
发明人： Kenji Haraguchi , Takanori Suzuki , Mitsuo Furuichi , Hiromi Yamanaka , Masayuki Tanaka
IPC分类号： C08J9/18 , C08L81/04 , C08J9/16
CPC分类号： C08J9/18 , C08L81/04 , C08J2351/04 , Y10T428/249953
摘要： Expandable rubber-modified styrene resin beads, expanded rubber-modified styrene resin beads, and expanded molded rubber-modified styrene resin articles are described. The expandable beads comprise a rubber-modified styrene resin comprising a styrene resin having dispersed therein 8 to 15% by weight of conjugated diene rubber particles having a 1,4-cis structure in a proportion of not less than 70% and an average particle size of 1.5 to 3.0 .mu.m, the rubber-modified styrene resin having a mineral oil content of not more than 3.0% by weight, and the expandable rubber-modified styrene resin beads containing 1 to 15% by weight of a volatile blowing agent. The expanded molded article has excellent appearance, impact resistance and softness.
摘要翻译：可膨胀橡胶改性苯乙烯树脂珠，膨胀橡胶改性苯乙烯树脂珠，发泡成型橡胶改性苯乙烯树脂制品。可发泡珠粒包含橡胶改性苯乙烯树脂，其包含苯乙烯树脂，其中分散有8至15重量％的具有不小于70％的1,4-顺式结构的共轭二烯橡胶颗粒和平均粒度 1.5〜3.0μm的矿物油含量为3.0重量％以下的橡胶改性苯乙烯系树脂和含有1〜15重量％挥发性发泡剂的发泡性橡胶改性苯乙烯系树脂珠。膨胀成型品具有优异的外观，耐冲击性和柔软性。

3. 发明授权

US6027806A Expanded resin beads 失效
标题翻译：膨胀树脂珠
公开(公告)号：US6027806A
公开(公告)日：2000-02-22
申请号：US3342
申请日：1998-01-06
申请人： Tadashi Abe , Masaaki Yokoyama , Toshihiro Gotoh , Teruya Ohkuwa
发明人： Tadashi Abe , Masaaki Yokoyama , Toshihiro Gotoh , Teruya Ohkuwa
IPC分类号： B29B9/12 , C08J3/12 , C08J9/16 , C08J9/18 , B32B5/16 , C08J3/34
CPC分类号： C08J9/18 , B29B9/12 , C08J9/16 , C08J2323/02 , Y10T428/2998
摘要： The present invention relates to an expanded resin bead comprising:a core which comprises a crystalline thermoplastic resin and is in an expanded state, anda coat which comprises an ethylene-based polymer which is lower in melting point than said thermoplastic resin or shows substantially no melting point, and which coat is in a substantially unexpanded state.
摘要翻译：本发明涉及一种发泡树脂珠粒，其包括：包含结晶热塑性树脂并处于膨胀状态的芯，以及包含熔点低于所述热塑性树脂的乙烯基聚合物或基本上不显示的涂层熔点，哪个涂层处于基本未膨胀的状态。

4. 发明授权

US5889285A Suspending agent-containing slurry for suspension polymerization 失效
标题翻译：用于悬浮聚合的含悬浮剂的浆料
公开(公告)号：US5889285A
公开(公告)日：1999-03-30
申请号：US609614
申请日：1996-03-01
申请人： Mitsushi Murata , Tsunenori Takahashi , Yukio Kato
发明人： Mitsushi Murata , Tsunenori Takahashi , Yukio Kato
IPC分类号： C08F2/20 , B01F17/00 , C08F2/18
CPC分类号： B01F17/005 , B01F17/0007 , B01F17/0028 , B01F17/0042 , B01F17/0057 , B01F17/0064 , B01F17/0085 , C08F2/18
摘要： A suspending agent-containing slurry is disclosed which comprises a dispersant and a particulate suspending agent having a particle size distribution in which the particle diameter at weight-cumulative 95%, from the minimum particle size, is 1 .mu.m or smaller. A method for efficiently producing the suspending agent-containing slurry is also disclosed. A process for suspension polymerization by use of the suspending agent-containing slurry is further disclosed. The slurry not only has such an excellent suspending ability in suspension polymerization that it enables the production of vinyl polymer beads having a narrow bead size distribution, but also is capable of retaining this ability over long and of exhibiting the same ability even when it has a high concentration. The suspension polymerization process enables vinyl polymer beads having a narrow bead size distribution to be produced efficiently due to the use of the slurry.
摘要翻译：公开了一种含悬浮剂的浆料，其包含分散剂和粒度分布的颗粒状悬浮剂，其中粒径从最小颗粒尺寸的重量累积95％为1μm或更小。还公开了一种有效生产含悬浮剂的浆料的方法。进一步公开了通过使用含悬浮剂的浆料进行悬浮聚合的方法。该浆料不仅在悬浮聚合中具有优异的悬浮能力，能够制造具有窄珠粒度分布的乙烯基聚合物珠粒，而且能够长时间保持该能力，并且即使具有相同的能力也能表现出相同的能力高浓度悬浮聚合方法使得能够由于使用浆料而有效地制备具有窄珠粒度分布的乙烯基聚合物珠粒。

5. 发明授权

US5616413A Expandable styrene resin beads and suspension-polymerization process for producing the same 失效
标题翻译：可发性苯乙烯树脂珠及其制备的悬浮聚合方法
公开(公告)号：US5616413A
公开(公告)日：1997-04-01
申请号：US421244
申请日：1995-04-13
申请人： Hiroki Shinozaki , Masayuki Tanaka , Yonezo Ueda
发明人： Hiroki Shinozaki , Masayuki Tanaka , Yonezo Ueda
IPC分类号： C08J9/20 , C08F2/18 , C08F12/00 , C08F12/08 , C08J9/16 , C08J9/18 , B32B5/16
CPC分类号： C08J9/18 , C08F12/08 , C08J9/16 , C08J2325/00 , Y10T428/2982
摘要： Expandable styrene resin beads are described, which, when expanded to a bulk density of 20 g/l, give pre-expanded beads in which the number of cells present along those surface parts of radii which range from the bead surface to a depth of 0.2 mm from the surface is from 3 to 20 per mm and the number of cells present along those inner parts of the radii which range from a depth of 1 mm from the bead surface to the bead center is 10 or larger per mm, the number of cells present along said surface parts being smaller than the number of cells present along said inner parts.
摘要翻译：描述了可膨胀的苯乙烯树脂珠粒，其当膨胀至20g / l的堆积密度时，得到预发泡珠粒，其中沿着从珠粒表面到深度为0.2的半径的那些表面部分存在细胞数目距离表面的mm为3至20 / mm，沿半径范围从胎圈表面到胎圈中心1mm的深度内部存在的细胞数量为每毫米10个或更大，沿着所述表面部分存在的细胞小于沿着所述内部部分存在的细胞的数量。

6. 发明授权

US6155505A Method of producing a suspending agent-containing slurry for suspension polymerization 失效
标题翻译：制备悬浮聚合用悬浮剂浆液的方法
公开(公告)号：US6155505A
公开(公告)日：2000-12-05
申请号：US850699
申请日：1997-05-02
申请人： Mitsushi Murata , Tsunenori Takahashi , Yukio Kato
发明人： Mitsushi Murata , Tsunenori Takahashi , Yukio Kato
IPC分类号： C08F2/20 , B01F17/00 , C08F2/18 , B02C17/00
CPC分类号： B01F17/005 , B01F17/0007 , B01F17/0028 , B01F17/0042 , B01F17/0057 , B01F17/0064 , B01F17/0085 , C08F2/18
摘要： A suspending agent-containing slurry is disclosed which comprises a dispersant and a particulate suspending agent having a particle size distribution in which the particle diameter at weight-cumulative 95%, from the minimum particle size, is 1 .mu.m or smaller. A method for efficiently producing the suspending agent-containing slurry is also disclosed. A process for suspension polymerization by use of the suspending agent-containing slurry is further disclosed. The slurry not only has such an excellent suspending ability in suspension polymerization that it enables the production of vinyl polymer beads having a narrow bead size distribution, but also is capable of retaining this ability over long and of exhibiting the same ability even when it has a high concentration. The suspension polymerization process enables vinyl polymer beads having a narrow bead size distribution to be produced efficiently due to the use of the slurry.
摘要翻译：公开了一种含悬浮剂的浆料，其包含分散剂和粒度分布的颗粒状悬浮剂，其中粒径从最小颗粒尺寸的重量累积95％为1μm或更小。还公开了一种有效生产含悬浮剂的浆料的方法。进一步公开了通过使用含悬浮剂的浆料进行悬浮聚合的方法。该浆料不仅在悬浮聚合中具有优异的悬浮能力，能够制造具有窄珠粒度分布的乙烯基聚合物珠粒，而且能够长时间保持该能力，并且即使具有相同的能力也能表现出相同的能力高浓度悬浮聚合方法使得能够由于使用浆料而有效地制备具有窄珠粒度分布的乙烯基聚合物珠粒。

7. 发明授权

US5837740A Expandable ABS resin beads and process for producing the same 失效
标题翻译：可膨胀的ABS树脂珠及其制造方法
公开(公告)号：US5837740A
公开(公告)日：1998-11-17
申请号：US531603
申请日：1995-09-21
申请人： Kenji Haraguchi , Takanori Suzuki , Yoshinari Itoh
发明人： Kenji Haraguchi , Takanori Suzuki , Yoshinari Itoh
IPC分类号： C08J9/18
CPC分类号： C08J9/18 , C08J2355/02 , Y10T428/249989 , Y10T428/2998
摘要： Expandable ABS resin beads containing a volatile blowing agent are disclosed which have an internal-water content of 5% by weight or lower and, when expanded in an expansion ratio of 30, give expanded beads each having a non-expanded surface layer having a thickness of not more than 50 .mu.m. A process for producing the expandable ABS resin beads is also disclosed which comprises dispersing ABS resin beads into an aqueous medium in a closed vessel and impregnating a volatile blowing agent into the ABS resin beads, said aqueous medium containing an electrolyte at least during the impregnation of the volatile blowing agent, with the concentration of the electrolyte in the aqueous medium being from 0.01 to 2 mol/l. The expandable resin beads are capable of giving an expanded molded article excellent in chemical resistance and toughness and especially in surface appearance and heat resistance.
摘要翻译：公开了含有挥发性发泡剂的可发性ABS树脂珠，其内含水量为5重量％以下，当以30的发泡倍率膨胀时，得到各自具有非发泡表面层的发泡珠，其厚度为不超过50亩。还公开了一种用于生产可膨胀ABS树脂珠粒的方法，其包括将ABS树脂珠粒分散在密闭容器中的水性介质中，并将挥发性发泡剂浸渍到ABS树脂珠粒中，所述水性介质至少在浸渍期间含有电解质挥发性发泡剂，水介质中电解质的浓度为0.01〜2mol / l。可膨胀树脂珠能够赋予耐化学性和韧性优异，特别是表面外观和耐热性优异的发泡成型体。

8. 发明授权

US5693683A Expandable styrene resin beads and process for producing the same 失效
标题翻译：可发性苯乙烯树脂珠及其制造方法
公开(公告)号：US5693683A
公开(公告)日：1997-12-02
申请号：US699823
申请日：1996-08-19
申请人： Hiroki Shinozaki , Masayuki Tanaka , Yonezo Ueda , Takanori Suzuki
发明人： Hiroki Shinozaki , Masayuki Tanaka , Yonezo Ueda , Takanori Suzuki
IPC分类号： C08F2/18 , C08F12/00 , C08J9/00 , C08J9/20
CPC分类号： C08J9/0061 , C08J9/20 , C08J2325/00 , C08J2433/00
摘要： An expandable styrene resin bead containing voids therein, wherein the number of the voids present in the area from the surface of the bead to a depth of 0.1 mm along the radial direction is not more than 100 per mm.sup.2 as counted on a cross section passing through approximately the center of the bead. A process for producing expandable styrene resin beads by suspension polymerization is also disclosed in which a styrene monomer is suspended in an aqueous medium in the presence of an initiator and a suspending agent, and a blowing agent is incorporated into polymer beads produced, wherein an alkali metal salt or ammonium salt of persulfuric acid is added to the reaction system in an amount of 0.5 to 30 ppm based on the aqueous medium while the degree of conversion of said monomer is in the range of from 0 to 30%, and an electrolyte is added to the reaction system in a concentration of 0.02 to 5.0 mol/l based on the aqueous medium when the degree of conversion is 30% or higher. The expandable styrene resin bead does not require aging and, when pre-expanded, show little variation in the state of the cells, i.e., expandable styrene resin beads which hardly undergo influences of storage conditions.
摘要翻译：在其中含有空隙的可膨胀苯乙烯树脂珠，其中存在于从珠粒表面到沿径向方向0.1mm深度的区域中的空隙数不超过每mm 2 100个，大约是珠的中心。还公开了通过悬浮聚合制备可发性苯乙烯树脂珠的方法，其中在引发剂和悬浮剂存在下将苯乙烯单体悬浮在水性介质中，并将发泡剂引入所制备的聚合物珠中，其中碱过硫酸的金属盐或铵盐以相对于水性介质为0.5〜30ppm的量添加到反应体系中，而所述单体的转化率为0〜30％，电解质为当转化率为30％以上时，基于水性介质，以0.02〜5.0mol / l的浓度添加到反应体系中。可发性苯乙烯树脂珠不需要老化，并且当预扩展时，细胞状态几乎没有变化，即几乎不受储存条件影响的可发性苯乙烯树脂珠。

9. 发明授权

US5573982A Slurry composition, shaping method using the same, and fired body 失效
标题翻译：浆料组成，使用它的成型方法和烧制体
公开(公告)号：US5573982A
公开(公告)日：1996-11-12
申请号：US398649
申请日：1995-03-03
申请人： Naoyuki Katoh , Kumehiko Sanada , Hiroshi Muto
发明人： Naoyuki Katoh , Kumehiko Sanada , Hiroshi Muto
IPC分类号： C04B33/24 , C04B35/111 , C04B35/634 , C04B35/00
CPC分类号： C04B35/63416 , C04B33/24 , C04B35/111 , C04B35/634 , C04B35/63424
摘要： A slurry composition is described, which comprises 100 parts by weight of a raw mineral material for white ware and/or a raw mineral material for advanced ceramics, from 0.5 to 20 parts by weight of a re-dispersible resin powder, and water. A shaping using the slurry composition and a fired body are also described.
摘要翻译：描述了一种浆料组合物，其包含100重量份的用于白色制品的原始矿物材料和/或用于高级陶瓷的原始矿物材料，0.5至20重量份的可再分散树脂粉末和水。还描述了使用浆料组合物和烧制体的成型。

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