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    • 1. 发明授权
    • Aqueous coating of carboxyl acrylic resin-epoxy resin product
    • 羧基丙烯酸树脂 - 环氧树脂产品的水性涂料
    • US5780532A
    • 1998-07-14
    • US693706
    • 1996-08-07
    • Sumio NodaSeiji TakamiHaruo InoueKaoru Morita
    • Sumio NodaSeiji TakamiHaruo InoueKaoru Morita
    • C09D133/02C08L63/00C09D133/04C09D133/06C09D163/00C08K5/04C08L33/02C08L63/02
    • C09D163/00C09D133/064C08L63/00
    • An aqueous coating composition comprising a carboxyl-containing reaction product neutralized and dispersed in an aqueous medium, the reaction product being produced by the esterification reaction of a carboxyl-containing acrylic resin (A) and an epoxy resin (B), the acrylic resin (A) comprising a carboxyl-containing polymerizable unsaturated monomer (A) and another polymerizable unsaturated monomer (b) as a monomer component, the acid value of the acrylic resin (A) at a higher molecular weight region with respect to its weight average molecular weight being higher by at least 80 mg KOH/g than at a lower molecular weight region, and a process for preparing said aqueous coating composition. The coating composition is capable of forming a coating film excellent in fabrication property, corrosion resistance, water resistance, flavor-retaining ability, among others. As a consequence, even a thin film of the composition is uniform in thickness and is outstanding in resistance to cratering and sagging.
    • 一种水性涂料组合物,其包含中和并分散在水性介质中的含羧基的反应产物,所述反应产物通过含羧基的丙烯酸树脂(A)和环氧树脂(B)的酯化反应,丙烯酸树脂( A)包含含羧基的聚合性不饱和单体(A)和作为单体成分的另一种可聚合不饱和单体(b),相对于其重均分子量,丙烯酸树脂(A)在较高分子量区域的酸值 比在较低分子量区域高至少80mg KOH / g,以及制备所述水性涂料组合物的方法。 涂料组合物能够形成制造性能,耐腐蚀性,耐水性,香味保持性等优异的涂膜。 因此,组合物的薄膜甚至厚度均匀,并且在耐发泡和下垂方面是突出的。