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    • 1. 发明授权
    • Nitrogen fertilizer
    • 氮肥
    • US5024689A
    • 1991-06-18
    • US153594
    • 1988-02-08
    • Allen R. SuttonRichard L. Balser
    • Allen R. SuttonRichard L. Balser
    • C05C1/00C05C13/00C05G3/00
    • C05G3/0076C05C1/00Y10S71/902
    • An improved aqueous nitrogen fertilizer has been developed that increases first-year nitrogen uptake efficiency to plants. It is also a nitrogen with features to minimize exposure to nitrogen loss. It is a nitrogen fertilizer consisting of urea, ammonium nitrate, dicyandiamide, ammonium thiosulfate, and a phosphate compound which is preferably an ammonium phosphate compound. This composition can contain a herbicide and/or various micro nutrients. This aqueous fertilizer solution can be applied to a field crop in a single application and is available to the growing plant throughout its growth and maturing cycle. The aqueous fertilizer composition is conveniently prepared by the addition of a slurry containing dicyandiamide, ammonium thiosulfate and the phosphate compound to a urea-ammonium nitrate solution wherein the nitrogen content has been adjusted to account for the nitrogen that will be supplied by the slurry.
    • 已经开发了改进的含氮氮肥,其提高了植物的第一年氮吸收效率。 它也是一种具有最小化氮损失暴露的特征的氮。 它是一种由尿素,硝酸铵,双氰胺,硫代硫酸铵和优选磷酸铵化合物的磷酸盐化合物组成的氮肥。 该组合物可含有除草剂和/或各种微量营养物质。 这种含水肥料溶液可以在单一应用中应用于田间作物,并且在其生长和成熟周期中可用于生长的植物。 通过将含有双氰胺,硫代硫酸铵和磷酸盐化合物的浆料加入到硝酸铵 - 硝酸铵溶液中,其中氮含量已经被调整以考虑由浆料供应的氮气,方便地制备了含水肥料组合物。
    • 2. 发明授权
    • Fluid urea-containing fertilizer
    • 含尿素的肥料
    • US5364438A
    • 1994-11-15
    • US151280
    • 1993-11-12
    • Charles W. WestonLawrence A. PeacockWillis L. Thornsberry, Jr.
    • Charles W. WestonLawrence A. PeacockWillis L. Thornsberry, Jr.
    • C05C1/00C05G3/00C05C9/00
    • C05C1/00C05G3/0064Y10S71/902
    • An improved fluid urea-containing fertilizer composition is disclosed; the composition is essentially comprised of an aqueous solution of urea, ammonium nitrate, N-(n-butyl)thiophosphoric triamide (NBPT), dicyandiamide (DCD), and may optionally also contain a clay as a suspending agent. The fluid fertilizer composition can be applied to a field crop in a single application and will nevertheless supply sufficient nitrogen to the plants throughout their growth and maturing cycles. As a result, the improved composition increases the nitrogen uptake efficiency of plants, enhances crop yields, and minimizes the loss of nitrogen from the soil.The NBPT is incorporated into the fluid fertilizer composition by blending a concentrated solution of N-(n-butyl)thiophosphoric triamide in a solvent selected from the group consisting of liquid amides such as an N-alkyl pyrrolidone directly with an aqueous solution of urea and ammonium nitrate, optionally also containing a suspending agent and commonly referred to in the fertilizer trade as UAN; the DCD may be added to the UAN fluid as a solid, a suspension, or in dissolved form along with the NBPT.
    • 公开了一种改进的含有流体尿素的肥料组合物; 该组合物基本上由尿素,硝酸铵,N-(正丁基)硫代磷酸三酰胺(NBPT),双氰胺(DCD)的水溶液组成,并且还可任选地含有粘土作为悬浮剂。 流体肥料组合物可以在单一应用中施用于田间作物,并且将在其生长和成熟周期中向植物提供足够的氮。 结果,改进的组合物增加植物的氮吸收效率,增加作物产量,并最小化土壤中氮的损失。 NBPT通过将N-(正丁基)硫代磷酸三酰胺的浓缩溶液在选自由N-烷基吡咯烷酮的液体酰胺直接与尿素水溶液组成的组的溶剂中混合而并入流体肥料组合物中, 硝酸铵,任选地还含有悬浮剂,在化肥贸易中通常称为硝酸铵; DCD可以与NBPT一起作为固体,悬浮液或溶解形式加入到UAN流体中。
    • 3. 发明授权
    • Removal of aluminum contamination during production of phosphoric acid
    • 在磷酸生产过程中去除铝污染
    • US5236679A
    • 1993-08-17
    • US879254
    • 1992-05-06
    • John W. WenCharles W. Weston
    • John W. WenCharles W. Weston
    • C01B25/225
    • C01B25/225
    • This invention provides a method for removing aluminum contamination from phosphoric acid during the acidulation of phosphate rock with sulfuric acid in the presence of recycled phosphoric acid. The method of this invention involves the addition of acid soluble silica to the acidulation slurry and calls for maintaining the molar ratio of non-fluosilicate fluoride (i.e. fluoride not complexed with silica) to aluminum in the liquid phase of the acidulation slurry between 2.5 and 5.0. These conditions favor the precipitation of aluminum as calcium tetrafluoaluminate dihydrate and enable the co-removal of this compound by filtration with by-product gypsum. This invention is particularily suitable for the processing of phosphate rocks with high iron and aluminum contents, such as the nonsedimentary phosphate rocks occurring in Sri Lanka.
    • 本发明提供一种在再循环磷酸存在下用硫酸酸化磷酸盐岩时,从磷酸中除去铝污染的方法。 本发明的方法涉及向酸化浆料中加入酸溶性二氧化硅,并要求在酸性浆液的液相中保持2.5至5.0之间的非氟硅酸盐氟化物(即,与二氧化硅不络合的氟化物)与铝的摩尔比 。 这些条件有利于铝作为四氟铝酸钙二水合物的沉淀,并且能够通过用副产物石膏过滤来共同去除该化合物。 本发明特别适用于加工具有高铁和铝含量的磷酸盐岩,如斯里兰卡发生的非磷酸盐岩。
    • 5. 发明授权
    • Sulfur recovery process
    • 硫回收过程
    • US4722832A
    • 1988-02-02
    • US900633
    • 1986-08-27
    • Charles W. WestonJohn W. Wen
    • Charles W. WestonJohn W. Wen
    • C01B17/027C01B17/42C01B17/033
    • C01B17/027C01B17/42
    • A process for the recovery of sulfur from sulfur-bearing ores employing an aqueous leaching solution containing calcium monosulfide, calcium hydrosulfide or mixtures of such calcium sulfide species. The sulfur ore is contacted in an extraction zone with the aqueous leaching solution under conditions to solubilize sulfur from the ore in the form of calcium polysulfide. Preferably, the extraction step is carried out at an elevated temperature. The loaded leaching solution is recovered from the extraction zone and applied to a sulfur-production zone. Here the loaded solution is contacted with hydrogen sulfide under conditions to react the hydrogen sulfide with the calcium polysulfide to produce calcium hydrosulfide and elemental sulfur. The calcium hydrosulfide solution is recycled for use as leaching solution in the sulfur extraction zone.
    • 使用含有单硫化钙,硫氢化钙或这种硫化钙物质的混合物的含水浸出溶液从含硫矿石中回收硫的方法。 使硫矿石在提取区域与含水浸出溶液接触,条件是以多硫化钙的形式从矿石中溶解硫。 优选地,提取步骤在升高的温度下进行。 加载的浸出溶液从萃取区回收并施加到硫生产区。 在这里,将负载的溶液与硫化氢接触,以使硫化氢与多硫化钙反应以产生硫氢化钙和元素硫。 硫酸氢钙溶液被再循环用作硫提取区的浸出溶液。
    • 7. 发明授权
    • Granular urea-based fertilizer
    • 颗粒状尿素型肥料
    • US5352265A
    • 1994-10-04
    • US151553
    • 1993-11-12
    • Charles W. WestonLawrence A. PeacockWillis L. Thornsberry, Jr.Allen R. Sutton
    • Charles W. WestonLawrence A. PeacockWillis L. Thornsberry, Jr.Allen R. Sutton
    • C05C9/00
    • C05C9/00Y10S71/902
    • An improved homogenous granular fertilizer composition is disclosed; the composition is comprised primarily of urea, N-(n-butyl)thiophosphoric triamide (NBPT), and dicyandiamide (DCD). The composition of this invention can be applied to a field crop in a single surface application and will nevertheless supply sufficient nitrogen to the plants throughout their growth and maturing cycles. The new improved composition increases the nitrogen uptake by plants, enhances crop yields, and minimizes the loss of both ammonium nitrogen and nitrate nitrogen from the soil.The NBPT is incorporated into the homogenous granular fertilizer composition of this invention by blending a concentrated solution of NBPT in a solvent selected from the group consisting of liquid amides, 2-pyrrolidone, and N-alkyl 2-pyrrolidones directly into molten urea prior to its granulation; the DCD may be added to the urea melt as a solid or in dissolved form along with the NBPT.
    • 公开了一种改进的均匀颗粒肥料组合物; 该组合物主要由尿素,N-(正丁基)硫代磷酸三酰胺(NBPT)和双氰胺(DCD)组成。 本发明的组合物可以在单一表面施用中应用于田间作物,并且在其生长和成熟周期期间将向植物提供足够的氮。 新的改进的组合物增加植物的氮吸收,增加作物产量,并最小化来自土壤的铵氮和硝态氮的损失。 NBPT通过将NBPT的浓缩溶液在选自液体酰胺,2-吡咯烷酮和N-烷基2-吡咯烷酮的溶剂中直接掺入到熔融尿素中之前,将NBPT掺入本发明的均匀颗粒肥料组合物中 制粒 DCD可以与NBPT一起作为固体或溶解形式加入到尿素熔体中。