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1. 发明申请

US20210163685A1 PHOTOSENSITIZER FOR A PHOTOCATHODE 有权
公开(公告)号：US20210163685A1
公开(公告)日：2021-06-03
申请号：US16772873
申请日：2018-12-15
申请人： CFSO GMBH
发明人： Oyewole TAYE SALAMI , Sigrid OBENLAND , Christian FISCHER , Thorben SCHLUECKER , Andreas WALTER
IPC分类号： C08G75/14 , C07F15/00 , C25B1/55 , C25B11/095 , C08K5/00 , C25B11/087 , C25B11/061
摘要： An improved photosensitizer for a photocathode comprises an oligomeric or polymeric chromphore absorbing, as an ensemble, light at (a) wavelengths at or greater than 420 nm that includes at least 3 identical or different suitable monomeric chromophore units carrying at least two substituents each comprising at least one alkylene, alkenylene and/or alkynylene chain having a chain length of at least 3 carbon atoms, those substituents being terminated by thiol groups, wherein the oligomeric or polymeric chromphore has a disulfide bond between each of the chromophores. A photocathode comprising the photosensitzer is useful for the reduction of water-soluble chemicals in oxidized forms, including protons, with the aid of visible light in a system comprising the photocathode and a photoanode or any other anode or source of electrons. A method for reducing chemicals soluble in aqueous media in oxidized forms, including protons, in aqueous solutions by means of the photocathode is also disclosed.

2. 发明授权

US11819507B2 Cholecalciferol sulfate salts and their use for the treatment of vitamin D deficiency 有权
公开(公告)号：US11819507B2
公开(公告)日：2023-11-21
申请号：US15743327
申请日：2016-07-12
申请人： CFSO GMBH
发明人： Oyewole Taye Salami , Sigrid Obenland , Reinhard Caliebe
IPC分类号： A61K31/593 , A61K9/00 , A61K9/08 , A61K9/10 , A61K47/02 , A61K47/14 , A61P43/00 , A61K9/70 , A61K31/198 , A61K47/10 , A61K47/44 , C07C401/00
CPC分类号： A61K31/593 , A61K9/006 , A61K9/0014 , A61K9/0019 , A61K9/08 , A61K9/10 , A61K9/7023 , A61K31/198 , A61K47/02 , A61K47/10 , A61K47/14 , A61K47/44 , A61P43/00 , A61K2300/00
摘要： Pharmaceutically acceptable cholecalciferol sulfate salts are used for combating vitamin D3 deficiency. New cholecalciferol sulfate salts as well as pharmaceutical compositions of the pharmaceutically acceptable cholecalciferol sulfate salts are described as well.

3. 发明申请

US20120247946A1 MONOLITHIC PHOTOCATALYST SYSTEM FOR GENERATING ELECTRICITY 审中-公开
标题翻译：用于生成电力的单片光电子系统
公开(公告)号：US20120247946A1
公开(公告)日：2012-10-04
申请号：US13389397
申请日：2010-08-09
申请人： Sigrid Obenland , Christian Fischer , Harald Natter
发明人： Sigrid Obenland , Christian Fischer , Harald Natter
IPC分类号： B01J19/12 , C01B3/04 , C01B13/02
CPC分类号： C01B3/042 , B01J23/888 , B01J27/045 , B01J31/1815 , B01J35/004 , B01J35/04 , B01J2231/62 , B01J2231/70 , B01J2531/821 , C01B13/0207 , C25B1/003 , Y02E60/364 , Y02E60/368
摘要： Described is a monolithic catalyst system (1) for the cleavage of water into hydrogen and oxygen with the aid of light, comprising a first photoactive material (50) capable by itself or together with one or more auxiliary catalysts when irradiated with light having a wavelength ≧420 nm of generating oxygen and protons from water, and a second photoactive material (60) capable by itself or together one or more auxiliary catalysts (92) when irradiated with light having a wavelength ≧420 nm of reducing protons in water to hydrogen, the first photoactive material (50) and second photoactive material (60) being in electrical contact via one or more electron-conducting materials (30, 20, 40, 60a) the system being in that characterized in that a load or an electric consumer is interposed in between at least one electron-conducting material. Likewise described is a method of generating oxygen, hydrogen and electricity from water using the catalyst system.
摘要翻译：描述了一种用于借助于光将水裂解成氢和氧的整体式催化剂体系（1），其包括当用具有波长的光照射时本身或与一种或多种辅助催化剂一起使用的第一光活性材料（50）当波长≥420nm的光被水中的还原质子照射到氢时，能够自身或一个或多个辅助催化剂（92）产生的能量的第二光活性材料（60）所述第一光活性材料（50）和所述第二光敏材料（60）经由一个或多个电子传导材料（30,20,40,60a）电接触，所述系统的特征在于负载或电消费者是介于至少一种电子传导材料之间。同样地描述了使用催化剂体系从水产生氧气，氢气和电力的方法。

4. 发明授权

US08883671B2 Monolithic catalyst system for the photolysis of water 有权
标题翻译：用于光解水的单片催化剂体系
公开(公告)号：US08883671B2
公开(公告)日：2014-11-11
申请号：US12734330
申请日：2008-10-31
申请人： Sigrid Obenland , Christian Fischer
发明人： Sigrid Obenland , Christian Fischer
IPC分类号： B01J31/00 , B01J23/00 , B01J35/00 , B01J23/26 , C25B1/00 , C01B3/04 , B01J31/18 , B01J23/652 , B01J27/045 , B01J31/22 , B01J21/06 , B01J23/52 , B01J23/42
CPC分类号： B01J35/0033 , B01J21/063 , B01J23/26 , B01J23/42 , B01J23/52 , B01J23/6527 , B01J27/045 , B01J31/1815 , B01J31/1865 , B01J31/2226 , B01J35/0006 , B01J35/0013 , B01J35/004 , B01J2231/62 , B01J2231/70 , B01J2531/0216 , B01J2531/72 , B01J2531/821 , B01J2531/824 , C01B3/042 , C25B1/003 , Y02E60/364 , Y02E60/368
摘要： A monolithic catalyst system for the cleavage of water into hydrogen and oxygen comprises a first photoactive material capable by itself or together with an auxiliary material and/or an auxiliary catalyst when irradiated with light having a wavelength≧420 nm of generating oxygen and protons from water, and a second photoactive material capable by itself or together with an auxiliary material and/or an auxiliary catalyst when irradiated with light having a wavelength≧420 nm of reducing protons in water to hydrogen. The first and second photoactive materials are in electrical contact via an electron-conducting material.
摘要翻译：用于将水切割成氢气和氧气的整体式催化剂体系包括当用波长≥420nm的光照射时自身或与辅助材料和/或辅助催化剂一起工作的第一光活性材料，以产生氧和质子的光以及第二光活性材料，当用波长≥420nm的光将水中的还原质子照射到氢时，能够自身或与辅助材料和/或辅助催化剂一起使用。第一和第二光敏材料通过电子传导材料电接触。

5. 发明申请

US20130037414A1 CATALYST SYSTEM AND METHOD FOR THE PHOTOLYSIS OF WATER 审中-公开
标题翻译：催化剂体系和水分光化学方法
公开(公告)号：US20130037414A1
公开(公告)日：2013-02-14
申请号：US13318525
申请日：2010-05-03
申请人： Sigrid Obenland , Christian Fischer
发明人： Sigrid Obenland , Christian Fischer
IPC分类号： C25B1/04 , C25B1/06 , C25B9/00
CPC分类号： C01B3/042 , B01J21/063 , B01J23/462 , B01J23/6527 , B01J27/04 , B01J27/045 , B01J31/223 , B01J33/00 , B01J35/004 , B01J35/04 , B01J37/0215 , B01J37/0219 , B01J37/0244 , B01J37/0248 , B01J37/20 , B01J2531/72 , C01B13/0207 , C01B2203/1023 , Y02E60/364 , Y02E60/366
摘要： A monolithic catalyst system for the cleavage of water into hydrogen and oxygen with the aid of light comprises a first photoactive material capable by itself or together with one or more of an auxiliary material and an auxiliary catalyst of generating oxygen and protons from water, when irradiated with light having a wavelength ≧420 nm of generating oxygen and protons from water, and a second photoactive material selected from gallium arsenide, copper indium disulphide/selenide, copper indium gallium disulphide/selenide and cadmium sulphide/selenide/telluride and having a water resistant coating transparent to visible light capable of the reducing protons in water to hydrogen, when irradiated with visible light. The first photoactive material and the second photoactive material are supported on at least one substrate and are in electrical contact, particularly in direct electrical contact, exclusively via one or more electron-conducting materials. The first photoactive material is not silicon, a III-V semiconductor or II-VI semiconductor or II-VI semiconductor or similar semiconductor having divalent or trivalent cations and anions of the groups Va and VIa of the periodic table of elements or semiconductor which is comprised of elements of the groups Ib (copper group), IIa, and VI or another inorganic photoconductor which is used in photovoltaic. Also disclosed is a process for cleaving water into hydrogen and oxygen with the aid of light using the catalyst system.
摘要翻译：用于借助于光将水切割成氢和氧的整体式催化剂体系包括第一光活性材料，其本身或与辅助材料和辅助催化剂一起产生氧和质子的辅助催化剂，当照射时具有波长≥420nm的来自水的光和质子的光，以及选自砷化镓，二硫化铟/硒化物，铜铟镓二硒化物/硒化物和硫化镉/硒化物/碲化物的第二光活性材料，并具有防水性当用可见光照射时，对能够将水中的还原质子的可见光透明化为氢。第一光活性材料和第二光活性材料被支撑在至少一个基底上，并且特别是通过一种或多种导电材料电接触，特别是直接电接触。第一光活性材料不是硅，具有二价或三价阳离子的III-V半导体或II-VI半导体或II-VI半导体或类似的半导体或元素或半导体的元素周期表的基团Va和VIa的阴离子的Ib族（铜基），IIa和VI族的元素或用于光伏的其它无机光电导体。还公开了使用催化剂体系借助于光将水分解成氢和氧的方法。

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