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    • 6. 发明授权
    • Strengthening glass articles with electromagnetic radiation and
resulting product
    • 用电磁辐射加强玻璃制品和产品
    • US5102833A
    • 1992-04-07
    • US727883
    • 1991-07-10
    • Jeetendra SehgalLenwood D. Pye
    • Jeetendra SehgalLenwood D. Pye
    • C03C10/00C03C10/12C03C23/00
    • C03C23/002C03C10/0027C03C10/0036C03C10/0045C03C23/003
    • Alkali metal- and alkaline earth metal-oxide aluminosilicate amorphous glass articles can be strengthened by providing such glass with a cerium dioxide sensitizer and a nucleating agent, irradiating the article with electromagnetic radiation, heating the irradiated article to a temperature between about the annealing and softening points of the glass, and cooling the heated, irradiated glass article. The treated article has a thick lower layer of the amorphous glass, but a thin layer of this glass at the surface of the article has been converted to a crystalline state. In this surface layer, some of the cerium has been converted from a +3 to a +4 ionic state and some of the metal element in the nucleating agent has been changed to a metallic state. The adjacent location of the lower and surface layers creates large compressive stresses at the surface layer which imparts great strength to the glass article.
    • 碱金属和碱土金属氧化物铝硅酸盐非晶玻璃制品可以通过提供这种玻璃与二氧化铈敏化剂和成核剂,用电磁辐射照射物品,加热照射的物品到约退火和软化之间的温度 玻璃的点,并冷却加热的被照射的玻璃制品。 经处理的制品具有较厚的非晶玻璃下层,但是该制品表面的该玻璃薄层已转化为结晶状态。 在该表面层中,一些铈已经从+3转变为+4离子状态,并且成核剂中的一些金属元素已经变成金属状态。 下层和表面层的相邻位置在表面层产生大的压应力,这给玻璃制品赋予了很大的强度。