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    • 8. 发明申请
    • Additives for hydrogenated resins
    • 氢化树脂添加剂
    • US20040102575A1
    • 2004-05-27
    • US10713204
    • 2003-11-17
    • Ausimont S.p.A.
    • Stefano TurriAldo SanguinetiMassimo Scicchitano
    • C08K003/00
    • C08K3/00C08G65/007C08G69/40C08G81/025C08L71/02C08L77/06C08L2666/04C08L51/00
    • Additives for hydrogenated resins obtainable by using the following components: a) bifunctional perfluoropolyethers having a nullCOOR end group, optionally in admixture with monofunctional perfluoropolyethers having a nullCOOR end group, b) mono, bi or polyfunctional hydrogenated monomers having functional groups able to react with the nullCOOR end groups of compound a); c) polyolefins having functional groups able to react with the block oligomer/polymer obtained by reaction of a) with b), preferably said functional groups being obtained by grafting with maleic anhydride; reacting in a first step a) with b), until disappearance of the nullCOOR group of component a), and in a second step the product obtained from the reaction of a) with b) with the functionalized polyolefins c).
    • 通过使用以下组分可获得的氢化树脂添加剂:a)具有-COOR端基的双功能全氟聚醚,任选地与具有-COOR端基的单官能全氟聚醚混合,b)具有能够反应的官能团的单,双或多官能氢化单体 与化合物a)的-COOR端基; c)具有能够通过a)与b)反应获得的嵌段低聚物/聚合物反应的官能团的聚烯烃,优选通过与马来酸酐接枝而获得的所述官能团; 在第一步a)中与b)反应,直到组分a)的-COOR基团消失,并且在第二步中,从a)与b)的反应获得的产物与官能化的聚烯烃c)反应。
    • 10. 发明申请
    • Thermoplastic fluorinated polymers
    • 热塑性氟化聚合物
    • US20020198325A1
    • 2002-12-26
    • US10151954
    • 2002-05-22
    • Ausimont S.p.A.
    • Julio A. AbuslemeClaudia Manzoni
    • C08L027/12
    • C08L27/12C08L2205/02C08L2666/04
    • A composition comprising a polymer mixture A of polymers formed by: (a) from 10 to 70% by moles of ethylene (E), (b) from 30 to 90%, by moles of a fluorinated monomer selected from tetrafluoroethylene (TFE), chlorotrifluoroethylene (CTFE), or mixtures thereof, (c) from 0.1 to 30% by moles, with respect to the total amount of monomers (a) and (b), of one or more acrylic monomers; characterized in that the polymer mixture A comprises polymer fractions having a different content of the acrylic comonomer such that the elastic modulus at 23null C. (ASTM D1708) of said polymer mixture A is lower than at least 10% of the elastic modulus of a polymer formed by monomers a), b) and c) wherein the polymer fractions have substantially an equal content of the acrylic comonomer.
    • 一种组合物,其包含通过以下形成的聚合物混合物A:(a)10至70摩尔%的乙烯(E),(b)30至90摩尔的选自四氟乙烯(TFE), 氯三氟乙烯(CTFE)或其混合物,(c)相对于单体(a)和(b)的总量为0.1至30摩尔%的一种或多种丙烯酸类单体; 其特征在于,所述聚合物混合物A包含具有不同含量的丙烯酸共聚单体的聚合物级分,使得所述聚合物混合物A的23℃下的弹性模量(ASTM D1708)低于所述聚合物混合物A的弹性模量的至少10% 由单体a),b)和c)形成的聚合物,其中聚合物部分具有基本相等的丙烯酸共聚单体含量。