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    • 1. 发明申请
    • UV-transparent pressure sensitive adhesive
    • 紫外线透明压敏胶
    • US20040254289A1
    • 2004-12-16
    • US10745305
    • 2003-12-22
    • tesa Aktiengesellschaft
    • Marc HusemannStephan Zollner
    • C08J003/00
    • C09J133/02C08K3/36Y10S526/905Y10T428/2813Y10T428/2857Y10T428/2896
    • A UV-transparent pressure sensitive adhesive comprising (a) a copolymer of (a1) from 75 to 99.8% by weight of acrylic esters and/or methacrylic esters of the formula CH2nullCH(R1)(COOR2), where R1 is H or CH3 and R2 is an alkyl chain having 1 to 20 carbon atoms; (a2) from 0 to 10% by weight of acrylic acid and/or methacrylic acid of the formula CH2nullCH(R1)(COOH), where R1 is H or CH3; (a3) from 0.2 to 5% by weight of olefinically unsaturated monomers which contain at least one UV-crosslinking functional group per monomer; and (a4) from 0 to 20% by weight of olefinically unsaturated monomers which contain at least one functional group per monomer; the copolymer having a weight average molecular weight of less than 300,000 g/mol and (b) from 2 to 20% by weight, based on the weight of copolymer, of a silicate filler, the silicate filler having a maximum particle diameter of 50 nm; and having a residual solvent fraction of less than 1%, based on the pressure sensitive adhesive.
    • 一种UV透明压敏粘合剂,其包含(a1)75至99.8重量%的式(a1)与式CH2 = CH(R1)(COOR2)的丙烯酸酯和/或甲基丙烯酸酯的共聚物,其中R 1为H或 CH3和R2是具有1至20个碳原子的烷基链; (a2)0至10重量%的丙烯酸和/或式CH 2 = CH(R 1)(COOH)的甲基丙烯酸,其中R 1是H或CH 3; (a3)0.2至5重量%的每单体含有至少一个UV交联官能团的烯属不饱和单体; 和(a4)0至20重量%的每单体含有至少一个官能团的烯属不饱和单体; 所述共聚物的重均分子量小于300,000g / mol,(b)基于共聚物重量的2至20重量%硅酸盐填料,最大粒径为50nm的硅酸盐填料 ; 并且基于压敏粘合剂具有小于1%的残留溶剂分数。
    • 4. 发明申请
    • Low shrinkback hotmelt PSA, its preparation and use
    • 低收缩热熔PSA,其制备和使用
    • US20040249102A1
    • 2004-12-09
    • US10800341
    • 2004-03-12
    • tesa Aktiengesellschaft
    • Marc HusemannStephan Zollner
    • B32B027/08
    • C09J133/04C08K3/013C08K3/26C08L33/00C09J7/21C09J7/38C09J7/385C09J11/04C09J2205/102C09J2400/263C09J2433/00Y10T428/31909
    • The invention relates to a hotmelt pressure sensitive adhesive (PSA), in particular an acrylic hotmelt PSA, featuring low shrinkback after extrusion coating, to a process for preparing it, and to its use for producing PSA tapes. The hotmelt pressure sensitive adhesive of the invention comprises at least one polyacrylate component and added filler comprising calcium carbonate, preferably taking the form of chalk. Said at least one polyacrylate component is based, with a mass fraction of at least 50% by weight, on at least one acrylic and/or methacrylic ester of the general formula (I) CH2nullCH(R1)(COOR2),nullnull(I) where R1nullH or CH3 and R2 is an unbranched, branched or cyclic alkyl radical having 1 to 22 carbon atoms and is substantially free from polar groups, especially carboxylic acid or hydroxyl groups.
    • 本发明涉及一种热熔粘合剂(PSA),特别是挤出涂布后具有低收缩性的丙烯酸热熔性PSA,其制备方法及其用于生产PSA带的用途。 本发明的热熔压敏粘合剂包括至少一种聚丙烯酸酯组分和包含碳酸钙的添加的填料,优选采用粉笔的形式。 所述至少一种聚丙烯酸酯组分以至少一种通式(I)的CH 2 = CH(R 1)(COOR 2),(I)的丙烯酸和/或甲基丙烯酸酯为基础,质量分数为至少50重量% )其中R1 = H或CH3,R2是具有1至22个碳原子的无支链,支链或环状烷基,并且基本上不含极性基团,特别是羧酸或羟基。