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    • 5. 发明申请
    • Rare earth oxide nanocrystals and methods of forming
    • 稀土氧化物纳米晶体及其形成方法
    • US20080175779A1
    • 2008-07-24
    • US11093639
    • 2005-03-30
    • Yunwei Charles Cao
    • Yunwei Charles Cao
    • C01F17/00
    • B82Y30/00C01F17/0043C01P2004/20C01P2004/52C01P2004/64C30B7/00Y10T428/2982
    • A method of forming rare earth oxide nanocrystals include the steps of dissolving a rare earth including compound in a solution containing at least one organic solvent, heating the solution to a temperature of at least 160° C., wherein a concentration of the rare earth including compound provided upon decomposition is sufficient to provide critical supersaturation of at least one active intermediate in the solution to nucleate a plurality of rare earth oxide nanocrystals. The plurality of rare earth nanocrystals are then grown, wherein the growing step proceeds at least in part in the absence of critical supersaturation of the active intermediate. The rare earth nanocrystals can assemble into at least one close-packed, ordered nanocrystal superlattice.
    • 形成稀土氧化物纳米晶体的方法包括以下步骤:将包含化合物的稀土溶解在含有至少一种有机溶剂的溶液中,将溶液加热至至少160℃的温度,其中稀土的浓度包括 分解后提供的化合物足以提供溶液中至少一种活性中间体的临界过饱和以成核多个稀土氧化物纳米晶体。 然后生长多个稀土纳米晶体,其中生长步骤至少部分地在没有活性中间体的临界过饱和的情况下进行。 稀土纳米晶体可以组装成至少一个紧密堆积的有序纳米晶体超晶格。
    • 6. 发明授权
    • Rare earth oxide nanocrystals and methods of forming
    • 稀土氧化物纳米晶体及其形成方法
    • US07754173B2
    • 2010-07-13
    • US12408379
    • 2009-03-20
    • Yunwei Charles Cao
    • Yunwei Charles Cao
    • C01F17/00C04B35/50
    • B82Y30/00C01F17/0043C01P2004/20C01P2004/52C01P2004/64C30B7/00Y10T428/2982
    • A method of forming rare earth oxide nanocrystals include the steps of dissolving a rare earth including compound in a solution containing at least one organic solvent, heating the solution to a temperature of at least 160° C., wherein a concentration of the rare earth including compound provided upon decomposition is sufficient to provide critical supersaturation of at least one active intermediate in the solution to nucleate a plurality of rare earth oxide nanocrystals. The plurality of rare earth nanocrystals are then grown, wherein the growing step proceeds at least in part in the absence of critical supersaturation of the active intermediate. The rare earth nanocrystals can assemble into at least one close-packed, ordered nanocrystal superlattice.
    • 形成稀土氧化物纳米晶体的方法包括以下步骤:将包含化合物的稀土溶解在含有至少一种有机溶剂的溶液中,将溶液加热至至少160℃的温度,其中稀土的浓度包括 分解后提供的化合物足以提供溶液中至少一种活性中间体的临界过饱和以成核多个稀土氧化物纳米晶体。 然后生长多个稀土纳米晶体,其中生长步骤至少部分地在没有活性中间体的临界过饱和的情况下进行。 稀土纳米晶体可以组装成至少一个紧密堆积的有序纳米晶体超晶格。
    • 7. 发明授权
    • Rare earth oxide nanocrystals and methods of forming
    • 稀土氧化物纳米晶体及其形成方法
    • US07527773B2
    • 2009-05-05
    • US11093639
    • 2005-03-30
    • Yunwei Charles Cao
    • Yunwei Charles Cao
    • C01F17/00C30B7/00B01D9/02
    • B82Y30/00C01F17/0043C01P2004/20C01P2004/52C01P2004/64C30B7/00Y10T428/2982
    • A method of forming rare earth oxide nanocrystals include the steps of dissolving a rare earth including compound in a solution containing at least one organic solvent, heating the solution to a temperature of at least 160° C., wherein a concentration of the rare earth including compound provided upon decomposition is sufficient to provide critical supersaturation of at least one active intermediate in the solution to nucleate a plurality of rare earth oxide nanocrystals. The plurality of rare earth nanocrystals are then grown, wherein the growing step proceeds at least in part in the absence of critical supersaturation of the active intermediate. The rare earth nanocrystals can assemble into at least one close-packed, ordered nanocrystal superlattice.
    • 形成稀土氧化物纳米晶体的方法包括以下步骤:将包含化合物的稀土溶解在含有至少一种有机溶剂的溶液中,将溶液加热至至少160℃的温度,其中稀土的浓度包括 分解后提供的化合物足以提供溶液中至少一种活性中间体的临界过饱和以成核多个稀土氧化物纳米晶体。 然后生长多个稀土纳米晶体,其中生长步骤至少部分地在没有活性中间体的临界过饱和的情况下进行。 稀土纳米晶体可以组装成至少一个紧密堆积的有序纳米晶体超晶格。
    • 9. 发明申请
    • RARE EARTH OXIDE NANOCRYSTALS AND METHODS OF FORMING
    • 稀土氧化物纳米晶体和形成方法
    • US20090196815A1
    • 2009-08-06
    • US12408379
    • 2009-03-20
    • Yunwei Charles Cao
    • Yunwei Charles Cao
    • C01F17/00
    • B82Y30/00C01F17/0043C01P2004/20C01P2004/52C01P2004/64C30B7/00Y10T428/2982
    • A method of forming rare earth oxide nanocrystals include the steps of dissolving a rare earth including compound in a solution containing at least one organic solvent, heating the solution to a temperature of at least 160° C., wherein a concentration of the rare earth including compound provided upon decomposition is sufficient to provide critical supersaturation of at least one active intermediate in the solution to nucleate a plurality of rare earth oxide nanocrystals. The plurality of rare earth nanocrystals are then grown, wherein the growing step proceeds at least in part in the absence of critical supersaturation of the active intermediate. The rare earth nanocrystals can assemble into at least one close-packed, ordered nanocrystal superlattice.
    • 形成稀土氧化物纳米晶体的方法包括以下步骤:将包含化合物的稀土溶解在含有至少一种有机溶剂的溶液中,将溶液加热至至少160℃的温度,其中稀土的浓度包括 分解后提供的化合物足以提供溶液中至少一种活性中间体的临界过饱和以成核多个稀土氧化物纳米晶体。 然后生长多个稀土纳米晶体,其中生长步骤至少部分地在没有活性中间体的临界过饱和的情况下进行。 稀土纳米晶体可以组装成至少一个紧密堆积的有序纳米晶体超晶格。