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    • 6. 发明申请
    • Resin composition for press foaming, foam and process for producing the foam
    • 用于压制发泡的树脂组合物,泡沫和用于生产泡沫的方法
    • US20080081845A1
    • 2008-04-03
    • US11902566
    • 2007-09-24
    • Katsuhiro YamadaTatsuhiro Nagamatsu
    • Katsuhiro YamadaTatsuhiro Nagamatsu
    • B29C44/00
    • A43B13/04
    • A resin composition for pressure-foam molding, which comprises an ethylene-based copolymer and a foaming agent, wherein the ethylene-based copolymer has monomer units derived from ethylene and monomer units derived from an a-olefin having 3 to 20 carbon atoms, has a melt flow rate of 0.01 to 0.7 g/10 minutes, a molecular weight distribution of 5 or more determined by a gel permeation chromatography, an activation energy of flow of 40 kJ/mol or more, and inflection points of 3 or less on a melting curve within temperature range from 25° C. to the end point of melting obtained by a differential scanning calorimetry; a foam obtained by press foaming; and a process for producing the foam.
    • 一种用于压力发泡成型的树脂组合物,其包含乙烯基共聚物和发泡剂,其中乙烯类共聚物具有源自乙烯的单体单元和衍生自具有3至20个碳原子的α-烯烃的单体单元,具有 熔体流动速率为0.01〜0.7g / 10分钟,通过凝胶渗透色谱法测定的分子量分布为5以上,流动活化能为40kJ / mol以上,拐点为3以下 在25℃至通过差示扫描量热法获得的熔点终点的温度范围内的熔融曲线; 通过压制泡沫获得的泡沫; 和泡沫的制造方法。
    • 7. 发明授权
    • Resin composition for press foaming, foam and process for producing the foam
    • 用于压制发泡的树脂组合物,泡沫和用于生产泡沫的方法
    • US08039523B2
    • 2011-10-18
    • US11902566
    • 2007-09-24
    • Katsuhiro YamadaTatsuhiro Nagamatsu
    • Katsuhiro YamadaTatsuhiro Nagamatsu
    • C08J9/00B29C44/34C08F210/02
    • A43B13/04
    • A resin composition for pressure-foam molding, which comprises an ethylene-based copolymer and a foaming agent, wherein the ethylene-based copolymer has monomer units derived from ethylene and monomer units derived from an a-olefin having 3 to 20 carbon atoms, has a melt flow rate of 0.01 to 0.7 g/10 minutes, a molecular weight distribution of 5 or more determined by a gel permeation chromatography, an activation energy of flow of 40 kJ/mol or more, and inflection points of 3 or less on a melting curve within temperature range from 25° C. to the end point of melting obtained by a differential scanning calorimetry; a foam obtained by press foaming; and a process for producing the foam.
    • 一种用于压力发泡成型的树脂组合物,其包含乙烯基共聚物和发泡剂,其中乙烯类共聚物具有源自乙烯的单体单元和衍生自具有3至20个碳原子的α-烯烃的单体单元,具有 熔体流动速率为0.01〜0.7g / 10分钟,通过凝胶渗透色谱法测定的分子量分布为5以上,流动活化能为40kJ / mol以上,拐点为3以下 在25℃至通过差示扫描量热法获得的熔点终点的温度范围内的熔融曲线; 通过压制泡沫获得的泡沫; 和泡沫的制造方法。
    • 10. 发明授权
    • Process for producing uncrosslinked polypropylene-based resin foam sheets and uncrosslinked polypropylene-based resin foam sheets
    • 制造未交联的聚丙烯类树脂发泡体片材和未交联的聚丙烯类树脂发泡体片材的方法
    • US06290884B1
    • 2001-09-18
    • US09363842
    • 1999-07-30
    • Akinobu SakamotoTatsuhiro Nagamatsu
    • Akinobu SakamotoTatsuhiro Nagamatsu
    • B28B150
    • B29C47/165B29C44/3442B29C44/60B29C47/0019B29C47/92B29C2947/92514B29C2947/92895
    • The present invention provides a process for producing uncrosslinked polypropylene-based resin foam sheets which is characterized by using an extrusion foaming apparatus having a gear pump which is interposed between the extruder and the die and which is linked by means of adapters, wherein the pressure (Pg) at the inlet of the gear pump is within the range specified by the following formula (Formula 1) and the extruder is controlled so that the value of Pg is constant. Formula 1 Pc≦Pg(atm)≦Pc+90 Pc=(&khgr;−1)/H &khgr;: theoretical expansion ratio when the foaming agent added is 100% held H: coefficient of solubility of the foaming gas in the resin at the resin temperature in the gear pump inlet (cm3(STP)/cm3·atm) and the like. The present invention makes it possible to produce uncrosslinked polypropylene-based resin foam sheets having fine foam cells and good appearance and being excellent in productivity and extrusion stability as well as in productivity improving effect in the production of high-expansion thin sheets with reducing wavy or corrugated defects at ends of sheets.
    • 本发明提供了一种生产未交联的聚丙烯基树脂发泡片的方法,其特征在于使用具有齿轮泵的挤出发泡装置,所述挤出发泡装置介于挤出机和模头之间,并通过适配器连接,其中压力 齿轮泵入口处的Pg)在下式(式1)所规定的范围内,并且控制挤出机使得Pg的值是恒定的。当加入的发泡剂为100时,理论膨胀比为1 %保持H:齿轮泵入口中树脂温度下发泡气体在树脂中的溶解度系数(cm3(STP)/ cm3))等。本发明使得可以生产未交联的聚丙烯类树脂发泡体 具有细泡沫单元和良好外观的片材,并且生产率和挤出稳定性以及生产率提高效果在高膨胀薄片w 减少片材端部的波纹或波纹缺陷。