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    • 8. 发明申请
    • METHOD FOR PRODUCING AROMATIC COMPOUND
    • 生产芳香化合物的方法
    • US20100137617A1
    • 2010-06-03
    • US12451537
    • 2008-05-13
    • Hirokazu KuwabaraMasaaki IkedaKazuo Takimiya
    • Hirokazu KuwabaraMasaaki IkedaKazuo Takimiya
    • C07D495/04C07D345/00
    • C07D495/04C07D495/22C07D517/04
    • Disclosed is a method for producing an aromatic compound represented by the general formula (2) below, which is characterized in that a compound represented by the general formula (1) below is reacted with a sulfur compound (at least one member selected from the group consisting of sulfur, hydrogen sulfide, metal hydrosulfides and metal sulfides) or a selenium compound. (In the formula (1), R1 represents a hydrogen atom, a halogen atom, a hydroxyl group, a cyano group, a nitro group, an ester group, an optionally substituted alkyl group having 1-18 carbon atoms or the like; R2 represents a halogen atom; R3 represents a hydrogen atom, C≡C—R1 or R2; and n represents an integer of 0-4. When n is not less than 2, R3's may be the same as or different from each other.) (In the formula (2), R1, R3 and n are as defined in the formula (1); and X represents a sulfur atom or a selenium atom.)
    • 公开了下述通式(2)表示的芳香族化合物的制造方法,其特征在于,将下述通式(1)表示的化合物与硫化合物(选自下述的至少一种 由硫,硫化氢,金属氢硫化物和金属硫化物组成)或硒化合物。 (式(1)中,R 1表示氢原子,卤素原子,羟基,氰基,硝基,酯基,可具有取代基的碳原子数为1〜18的烷基等; R 2 表示卤素原子; R3表示氢原子,C≡C-R1或R2; n表示0-4的整数,当n不小于2时,R 3可以相同或不同) (式(2)中,R 1,R 3,n如式(1)所定义,X表示硫原子或硒原子。
    • 9. 发明授权
    • Method for producing aromatic compound
    • 芳香族化合物的制备方法
    • US09073938B2
    • 2015-07-07
    • US12451537
    • 2008-05-13
    • Hirokazu KuwabaraMasaaki IkedaKazuo Takimiya
    • Hirokazu KuwabaraMasaaki IkedaKazuo Takimiya
    • C07D495/04C07D495/22C07D517/04
    • C07D495/04C07D495/22C07D517/04
    • Disclosed is a method for producing an aromatic compound represented by the general formula (2) below, which is characterized in that a compound represented by the general formula (1) below is reacted with a sulfur compound (at least one member selected from the group consisting of sulfur, hydrogen sulfide, metal hydrosulfides and metal sulfides) or a selenium compound. (In the formula (1), R1 represents a hydrogen atom, a halogen atom, a hydroxyl group, a cyano group, a nitro group, an ester group, an optionally substituted alkyl group having 1-18 carbon atoms or the like; R2 represents a halogen atom; R3 represents a hydrogen atom, C≡C—R1 or R2; and n represents an integer of 0-4. When n is not less than 2, R3's may be the same as or different from each other.) (In the formula (2), R1, R3 and n are as defined in the formula (1); and X represents a sulfur atom or a selenium atom.)
    • 公开了下述通式(2)表示的芳香族化合物的制造方法,其特征在于,将下述通式(1)表示的化合物与硫化合物(选自下述的至少一种 由硫,硫化氢,金属氢硫化物和金属硫化物组成)或硒化合物。 (式(1)中,R 1表示氢原子,卤素原子,羟基,氰基,硝基,酯基,可具有取代基的碳原子数为1〜18的烷基等; R 2 表示卤素原子; R3表示氢原子,C≡C-R1或R2; n表示0-4的整数,当n不小于2时,R 3可以相同或不同) (式(2)中,R 1,R 3,n如式(1)所定义,X表示硫原子或硒原子。