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1. 发明授权

US07910749B2 Methods for oxidizing organic compounds 有权
标题翻译：氧化有机化合物的方法
公开(公告)号：US07910749B2
公开(公告)日：2011-03-22
申请号：US11884203
申请日：2006-02-22
申请人： Yasuteru Kajikawa , Naruhisa Hirai , Jun Kuwana
发明人： Yasuteru Kajikawa , Naruhisa Hirai , Jun Kuwana
IPC分类号： C07D493/00 , C07D307/77 , C07C61/00 , C07C51/255 , C07C45/00 , C07C27/00 , C07C35/08 , C07C35/06
CPC分类号： C07C51/265 , B01J31/0247 , B01J31/04 , B01J31/28 , B01J31/40 , B01J2231/70 , C07C29/50 , C07C35/06 , C07C35/08 , C07C45/33 , C07C51/00 , C07C51/313 , C07C2601/08 , C07C2601/14 , C07C2601/20 , Y02P20/584 , C07C49/403 , C07C49/413 , C07C49/395 , C07C63/313 , C07C55/14 , C07C35/205
摘要： A method oxidizes an organic compound with oxygen in the presence of a catalyst, in which the catalyst contains a N-hydroxy- or N-(substituted oxy)-imide compound derivable from at least one selected from a target product, a reaction intermediate, and a reaction byproduct, and the catalyst is produced from at least one component selected from the target product, reaction intermediate, and reaction byproduct each formed as a result of the reaction and is used in the oxidation reaction so as to make up for a loss of the catalyst due to denaturation in the reaction. The method can easily and inexpensively make up for a loss of the catalyst denaturated in the course of reaction.
摘要翻译：一种方法是在催化剂存在下用氧气氧化有机化合物，其中催化剂含有可从选自目标产物，反应中间体中的至少一种的N-羟基或N-（取代的氧）酰亚胺化合物，和反应副产物，催化剂由选自反应产生的目标产物，反应中间体和反应副产物中的至少一种成分产生，并用于氧化反应中以弥补损失的催化剂，由于反应变性。该方法可以容易且廉价地补偿在反应过程中变性的催化剂的损失。

2. 发明申请

US20080269507A1 Methods for Oxidizing Organic Compounds 有权
标题翻译：氧化有机化合物的方法
公开(公告)号：US20080269507A1
公开(公告)日：2008-10-30
申请号：US11884203
申请日：2006-02-22
申请人： Yasuteru Kajikawa , Naruhisa Hirai , Jun Kuwana
发明人： Yasuteru Kajikawa , Naruhisa Hirai , Jun Kuwana
IPC分类号： C07D493/04 , C07C45/33 , C07C35/02 , C07C51/21 , C07C35/08 , C07C35/06 , C07C51/265 , C07D307/89
CPC分类号： C07C51/265 , B01J31/0247 , B01J31/04 , B01J31/28 , B01J31/40 , B01J2231/70 , C07C29/50 , C07C35/06 , C07C35/08 , C07C45/33 , C07C51/00 , C07C51/313 , C07C2601/08 , C07C2601/14 , C07C2601/20 , Y02P20/584 , C07C49/403 , C07C49/413 , C07C49/395 , C07C63/313 , C07C55/14 , C07C35/205
摘要： A method oxidizes an organic compound with oxygen in the presence of a catalyst, in which the catalyst contains a N-hydroxy- or N-(substituted oxy)-imide compound derivable from at least one selected from a target product, a reaction intermediate, and a reaction byproduct, and the catalyst is produced from at least one component selected from the target product, reaction intermediate, and reaction byproduct each formed as a result of the reaction and is used in the oxidation reaction so as to make up for a loss of the catalyst due to denaturation in the reaction. The method can easily and inexpensively make up for a loss of the catalyst denaturated in the course of reaction.
摘要翻译：一种方法是在催化剂存在下用氧气氧化有机化合物，其中催化剂含有可从选自目标产物，反应中间体中的至少一种的N-羟基或N-（取代的氧）酰亚胺化合物，和反应副产物，催化剂由选自反应产生的目标产物，反应中间体和反应副产物中的至少一种成分产生，并用于氧化反应中以弥补损失的催化剂，由于反应变性。该方法可以容易且廉价地补偿在反应过程中变性的催化剂的损失。

3. 发明申请

US20080171881A1 Method for Producing Organic Compound and Method for Decomposing Compound Having Dicarboximide Skeleton 失效
标题翻译：生产有机化合物的方法和分解具有二酰亚胺骨架的化合物的方法
公开(公告)号：US20080171881A1
公开(公告)日：2008-07-17
申请号：US11885125
申请日：2006-03-22
申请人： Naruhisa Hirai , Jun Kuwana
发明人： Naruhisa Hirai , Jun Kuwana
IPC分类号： C07D211/22 , C07C233/00 , C07D233/40 , C07D249/12
CPC分类号： C07D251/32 , Y02P20/55
摘要： It is desirable to provide a method for easily removing catalyst-derived impurities from a product of a reaction by the catalysis of a compound having a dicarboximide skeleton and thereby efficiently yielding a target compound with high purity.Disclosed is a method for producing an organic compound through a reaction of a substrate in the presence of a catalyst, the catalyst including a compound having a dicarboximide skeleton represented by following Formula (i): wherein R represents hydrogen atom or a hydroxyl-protecting group. The method includes the step of treating a reaction product with hot water so as to decompose and remove an impurity derived from the catalyst. The temperature of the hot water is preferably 100° C. or higher.
摘要翻译：期望提供一种通过催化具有二羧酰亚胺骨架的化合物从反应产物中容易地除去催化剂衍生的杂质的方法，从而有效地产生高纯度的目标化合物。公开了一种在催化剂存在下通过底物的反应制备有机化合物的方法，所述催化剂包括具有由下式（i）表示的二羧酰亚胺骨架的化合物：其中R表示氢原子或羟基保护基。该方法包括用热水处理反应产物以分解和除去由催化剂衍生的杂质的步骤。热水的温度优选为100℃以上。

4. 发明授权

US07994330B2 Method for producing organic compound and method for decomposing compound having dicarboximide skeleton 失效
标题翻译：生产有机化合物的方法和分解具有二甲酰亚胺骨架的化合物的方法
公开(公告)号：US07994330B2
公开(公告)日：2011-08-09
申请号：US11885125
申请日：2006-03-22
申请人： Naruhisa Hirai , Jun Kuwana
发明人： Naruhisa Hirai , Jun Kuwana
IPC分类号： C07D211/22 , C07D233/40
CPC分类号： C07D251/32 , Y02P20/55
摘要： It is desirable to provide a method for easily removing catalyst-derived impurities from a product of a reaction by the catalysis of a compound having a dicarboximide skeleton and thereby efficiently yielding a target compound with high purity.Disclosed is a method for producing an organic compound through a reaction of a substrate in the presence of a catalyst, the catalyst including a compound having a dicarboximide skeleton represented by following Formula (i): wherein R represents hydrogen atom or a hydroxyl-protecting group. The method includes the step of treating a reaction product with hot water so as to decompose and remove an impurity derived from the catalyst. The temperature of the hot water is preferably 100° C. or higher.
摘要翻译：期望提供一种通过催化具有二羧酰亚胺骨架的化合物从反应产物中容易地除去催化剂衍生的杂质的方法，从而有效地产生高纯度的目标化合物。公开了一种在催化剂存在下通过底物的反应制备有机化合物的方法，所述催化剂包括具有由下式（i）表示的二羧酰亚胺骨架的化合物：其中R表示氢原子或羟基保护基。该方法包括用热水处理反应产物以分解和除去由催化剂衍生的杂质的步骤。热水的温度优选为100℃以上。

5. 发明申请

US20100331569A1 PROCESS FOR PRODUCTION OF OXYGEN-CONTAINING ORGANIC COMPOUND 失效
标题翻译：生产含氧有机化合物的方法
公开(公告)号：US20100331569A1
公开(公告)日：2010-12-30
申请号：US12919494
申请日：2009-02-27
申请人： Minoru Takano , Naruhisa Hirai , Yasutaka Ishii
发明人： Minoru Takano , Naruhisa Hirai , Yasutaka Ishii
IPC分类号： C07C51/50
CPC分类号： C07C45/33 , B01J27/053 , B01J37/0201 , C07C29/50 , C07C45/36 , C07C51/00 , C07C51/265 , C07C2603/74 , Y02P20/55 , C07C35/37 , C07C47/542 , C07C49/417 , C07C63/04
摘要： Disclosed is a process for the production of an oxygen-containing organic compound by oxidizing an organic compound with molecular oxygen in a liquid phase in the presence both of a catalytic nitrogen-containing cyclic compound and a catalyst including a solid superacid and, supported thereon, a transition metal compound, in which the nitrogen-containing cyclic compound contains, as a ring constituent, a skeleton represented by following Formula (1), wherein X represents an —OR group, and wherein R represents hydrogen atom or a hydroxyl-protecting group. The process gives the oxygen-containing organic compound in a high yield and enables easy recovery and reuse of the catalyst.
摘要翻译：本发明公开了一种在含有催化含氮环状化合物和含有固体超强酸的催化剂存在的条件下，通过在液相中用分子氧氧化有机化合物来制备含氧有机化合物的方法，其中含氮环状化合物含有作为环成分的由下式（1）表示的骨架的过渡金属化合物，其中X表示-OR基，其中R表示氢原子或羟基保护基。该方法以高产率提供含氧有机化合物，并且能够容易地回收和再利用催化剂。

6. 发明授权

US07741514B2 Catalyst comprising N-substituted cyclic imide compound and process for producing organic compound using the catalyst 失效
标题翻译：包含N-取代的环状酰亚胺化合物的催化剂和使用该催化剂制备有机化合物的方法
公开(公告)号：US07741514B2
公开(公告)日：2010-06-22
申请号：US11504019
申请日：2006-08-15
申请人： Yasutaka Ishii , Tatsuya Nakano , Takahiro Iwahama , Naruhisa Hirai
发明人： Yasutaka Ishii , Tatsuya Nakano , Takahiro Iwahama , Naruhisa Hirai
IPC分类号： C07C63/00 , C07C51/16 , C07C51/00 , C07D207/00
CPC分类号： C07C45/34 , B01J23/34 , B01J23/75 , B01J31/0247 , B01J31/2208 , B01J2231/348 , B01J2231/42 , B01J2531/72 , B01J2531/845 , C07C45/00 , C07C45/33 , C07C45/36 , C07C51/265 , C07C51/313 , C07D207/46 , C07D209/48 , C07D215/54 , Y02P20/55 , C07C49/403 , C07C49/78 , C07C65/32 , C07C63/26 , C07C63/04 , C07C55/14
摘要： A catalyst of the invention includes an imide compound having a N-substituted cyclic imide skeleton represented by following Formula (I): wherein R is a hydroxyl-protecting group. Preferred R is a hydrolyzable protecting group. R may be a group obtained from an acid by eliminating an OH group therefrom. Such acids include, for example, carboxylic acids, sulfonic acids, carbonic acid, carbamic acid, sulfuric acid, nitric acid, phosphoric acids and boric acids. The catalyst may include the imide compound and a metallic compound in combination. In the presence of the catalyst, (A) a compound capable of forming a radical is allowed to react with (B) a radical scavenging compound and thereby yields an addition or substitution reaction product of the compound (A) and the compound (B) or a derivative thereof. This catalyst can produce an organic compound with a high selectivity in a high yield as a result of, for example, an addition or substitution reaction under mild conditions.
摘要翻译：本发明的催化剂包括具有由下式（I）表示的N-取代的环状酰亚胺骨架的酰亚胺化合物：其中R是羟基保护基。优选的R是可水解的保护基团。 R可以是从酸中除去OH基团而获得的基团。这些酸包括例如羧酸，磺酸，碳酸，氨基甲酸，硫酸，硝酸，磷酸和硼酸。催化剂可以组合包括酰亚胺化合物和金属化合物。在催化剂存在下，使（A）能够形成自由基的化合物与（B）自由基清除化合物反应，从而得到化合物（A）和化合物（B）的加成或取代反应产物，或其衍生物。作为例如在温和条件下的添加或取代反应的结果，该催化剂可以以高产率生产高选择性的有机化合物。

7. 发明申请

US20070191634A1 Methods for producing aromatic carboxylic acids 失效
标题翻译：芳香羧酸的制备方法
公开(公告)号：US20070191634A1
公开(公告)日：2007-08-16
申请号：US10594212
申请日：2005-02-23
申请人： Naruhisa Hirai , Masahiko Terada
发明人： Naruhisa Hirai , Masahiko Terada
IPC分类号： C07C51/16 , C07C51/255 , C07F15/00
CPC分类号： C07C51/265 , C07C51/00 , Y02P20/55 , C07C63/26
摘要： A method of this invention produces an aromatic carboxylic acid, by oxidizing an aromatic compound B with oxygen in the presence of a catalytic nitrogen-containing cyclic compound A to thereby yield a corresponding aromatic carboxylic acid, the aromatic compound B having one or more hydrocarbon groups alone as substituents on its aromatic ring, and the catalytic nitrogen-containing cyclic compound A having a skeleton represented by following Formula (i): wherein X represents oxygen atom or an —OR group, and wherein R represents hydrogen atom or a hydroxyl-protecting group, as a constitutive member of its ring. The method includes the step of carrying out a reaction at a concentration of the aromatic compound B in the reaction system of 3.0 percent by weight or less, while continuously feeding the catalytic nitrogen-containing cyclic compound A, the aromatic compound B, a reaction solvent, and oxygen to a reactor and continuously extracting a reaction mixture from the reactor. This method can produce aromatic carboxylic acids with industrially good productivity without the need for special reaction facilities and without undergoing many steps.
摘要翻译：本发明的方法通过在催化性含氮环状化合物A的存在下用氧气化芳香族化合物B，得到芳香族羧酸，得到相应的芳香族羧酸，该芳香族化合物B具有一个以上的烃基单独作为其芳环上的取代基，和具有由下式（i）表示的骨架的催化含氮环状化合物A：其中X表示氧原子或-OR基团，其中R表示氢原子或羟基保护基组，作为其环的组成成员。该方法包括在反应体系中进行浓度为3.0重量％以下的芳族化合物B的浓度的反应的工序，同时连续进料含有催化剂的含氮环状化合物A，芳香族化合物B，反应溶剂，和氧气进入反应器并从反应器中连续提取反应混合物。该方法可以产生工业上良好生产率的芳族羧酸，而不需要特殊的反应设备，并且不经历许多步骤。

8. 发明授权

US08410308B2 Process for production of oxygen-containing organic compound 失效
标题翻译：含氧有机化合物的制备方法
公开(公告)号：US08410308B2
公开(公告)日：2013-04-02
申请号：US12919494
申请日：2009-02-27
申请人： Minoru Takano , Naruhisa Hirai , Yasutaka Ishii
发明人： Minoru Takano , Naruhisa Hirai , Yasutaka Ishii
IPC分类号： C07C51/50
CPC分类号： C07C45/33 , B01J27/053 , B01J37/0201 , C07C29/50 , C07C45/36 , C07C51/00 , C07C51/265 , C07C2603/74 , Y02P20/55 , C07C35/37 , C07C47/542 , C07C49/417 , C07C63/04
摘要： Disclosed is a process for the production of an oxygen-containing organic compound by oxidizing an organic compound with molecular oxygen in a liquid phase in the presence both of a catalytic nitrogen-containing cyclic compound and a catalyst including a solid superacid and, supported thereon, a transition metal compound, in which the nitrogen-containing cyclic compound contains, as a ring constituent, a skeleton represented by following Formula (1), wherein X represents an —OR group, and wherein R represents hydrogen atom or a hydroxyl-protecting group. The process gives the oxygen-containing organic compound in a high yield and enables easy recovery and reuse of the catalyst.
摘要翻译：本发明公开了一种在含有催化含氮环状化合物和含有固体超强酸的催化剂存在的条件下，通过在液相中用分子氧氧化有机化合物来制备含氧有机化合物的方法，其中含氮环状化合物含有作为环成分的由下式（1）表示的骨架的过渡金属化合物，其中X表示-OR基，其中R表示氢原子或羟基保护基。该方法以高产率提供含氧有机化合物，并且能够容易地回收和再利用催化剂。

9. 发明申请

US20060281629A1 Catalyst comprising N-substituted cyclic imide compound and process for producing organic compound using the catalyst 失效
标题翻译：包含N-取代的环状酰亚胺化合物的催化剂和使用该催化剂制备有机化合物的方法
公开(公告)号：US20060281629A1
公开(公告)日：2006-12-14
申请号：US11504019
申请日：2006-08-15
申请人： Yasutaka Ishii , Tatsuya Nakano , Takahiro Iwahama , Naruhisa Hirai
发明人： Yasutaka Ishii , Tatsuya Nakano , Takahiro Iwahama , Naruhisa Hirai
IPC分类号： B01J31/00 , C07C51/16 , C07C51/255
CPC分类号： C07C45/34 , B01J23/34 , B01J23/75 , B01J31/0247 , B01J31/2208 , B01J2231/348 , B01J2231/42 , B01J2531/72 , B01J2531/845 , C07C45/00 , C07C45/33 , C07C45/36 , C07C51/265 , C07C51/313 , C07D207/46 , C07D209/48 , C07D215/54 , Y02P20/55 , C07C49/403 , C07C49/78 , C07C65/32 , C07C63/26 , C07C63/04 , C07C55/14
摘要： A catalyst of the invention includes an imide compound having a N-substituted cyclic imide skeleton represented by following Formula (I): wherein R is a hydroxyl-protecting group. Preferred R is a hydrolyzable protecting group. R may be a group obtained from an acid by eliminating an OH group therefrom. Such acids include, for example, carboxylic acids, sulfonic acids, carbonic acid, carbamic acid, sulfuric acid, nitric acid, phosphoric acids and boric acids. The catalyst may include the imide compound and a metallic compound in combination. In the presence of the catalyst, (A) a compound capable of forming a radical is allowed to react with (B) a radical scavenging compound and thereby yields an addition or substitution reaction product of the compound (A) and the compound (B) or a derivative thereof. This catalyst can produce an organic compound with a high selectivity in a high yield as a result of, for example, an addition or substitution reaction under mild conditions.
摘要翻译：本发明的催化剂包括具有由下式（I）表示的N-取代的环状酰亚胺骨架的酰亚胺化合物：其中R是羟基保护基。优选的R是可水解的保护基团。 R可以是从酸中除去OH基团而获得的基团。这些酸包括例如羧酸，磺酸，碳酸，氨基甲酸，硫酸，硝酸，磷酸和硼酸。催化剂可以组合包括酰亚胺化合物和金属化合物。在催化剂存在下，使（A）能够形成自由基的化合物与（B）自由基清除化合物反应，从而得到化合物（A）和化合物（B）的加成或取代反应产物，或其衍生物。作为例如在温和条件下的添加或取代反应的结果，该催化剂可以以高产率生产高选择性的有机化合物。

10. 发明申请

US20060241293A1 Process for production n,n',n"- trisubstituted isocyanuric acids 审中-公开
标题翻译：生产n，n'，n“ - 三取代异氰脲酸的方法
公开(公告)号：US20060241293A1
公开(公告)日：2006-10-26
申请号：US10568597
申请日：2004-08-12
申请人： Naruhisa Hirai
发明人： Naruhisa Hirai
IPC分类号： C07D251/32
CPC分类号： C07D251/34 , Y02P20/55
摘要： A process produces an N,N′,N″-trisubstituted isocyanuric acid represented by following Formula (4): wherein R is a hydroxyl-protecting group, by heating an N-substituted carbamic acid derivative represented by following Formula (1): wherein R has the same meaning as defined above; and Z is a group represented by following Formula (2) or (3): wherein R′ is a hydrocarbon group or a heterocyclic group having a carbon atom at the bonding site with the adjacent oxygen atom, wherein the heating is carried out at a temperature in a range of 95° C. to 145° C. where Z is the group represented by Formula (3). This process can easily and conveniently produce the N,N′,N″-trisubstituted isocyanuric acid in a high yield.
摘要翻译：通过加热下式（1）表示的N-取代氨基甲酸衍生物，得到下述式（4）表示的N，N'，N“ - 三取代异氰脲酸：其中，R为羟基保护基，其中R具有与上述相同的含义; Z为由下式（2）或（3）表示的基团：其中R'为与相邻氧原子键合位置具有碳原子的烃基或杂环基，其中加热在温度在95℃至145℃的范围内，其中Z是由式（3）表示的基团。该方法可以容易且方便地以高收率产生N，N'，N“ - 三取代的异氰脲酸。

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