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    • 2. 发明授权
    • Curable aqueous polyurethane dispersions
    • 可固化水性聚氨酯分散体
    • US07169841B2
    • 2007-01-30
    • US10311307
    • 2001-06-26
    • Reinhold SchwalmBernd BruchmannFrank VoellingerErich BeckWolfgang SchrofUwe Meisenburg
    • Reinhold SchwalmBernd BruchmannFrank VoellingerErich BeckWolfgang SchrofUwe Meisenburg
    • C08J3/00C08K3/20C08L75/00C08F8/30C08F283/04
    • C09D175/16C08G18/7837C08G18/8175Y10T428/31551C08G18/0823
    • A curable aqueous polyurethane dispersion substantially comprises a) at least one compound having two free isocyanate groups, at least one allophanate group and at least one C═C double bond capable of free radical polymerization, a carbonyl group or an oxygen atom in the form of an ether function being bonded directly to the double bond, b) at least one compound having at least one group reactive toward isocyanate groups and having a C═C double bond capable of free-radical polymerization, c) if required, at least one compound having at least two groups reactive towards isocyanate groups and selected from hydroxyl, mercapto, primary and/or secondary amino groups, d) at least one compound having at least one group reactive towards isocyanate groups and having at least one acid group, e) at least one basic compound for neutralizing or partially neutralizing the acid groups of the compounds d), and a thermal initiator and is used for coating substrates.
    • 可固化的水性聚氨酯分散体基本上包含a)至少一种具有两个游离异氰酸酯基团的化合物,至少一个脲基甲酸酯基团和至少一个能够自由基聚合的CC双键,羰基或乙醚形式的氧原子 b)至少一种具有至少一个对异氰酸酯基团具有反应性并具有能够进行自由基聚合的CC双键的化合物,c)如果需要,至少一种具有至少两个的化合物 对异氰酸酯基反应并且选自羟基,巯基,伯和/或仲氨基的基团,d)至少一种具有至少一个对异氰酸酯基团具有反应性并具有至少一个酸基团的化合物,e)至少一种碱性化合物 用于中和或部分中和化合物d)的酸基和热引发剂,并用于涂覆基材。
    • 4. 发明授权
    • Method and means of producing cured coating films
    • 生产固化涂膜的方法和方法
    • US06736898B2
    • 2004-05-18
    • US09977163
    • 2001-10-15
    • Wolfgang SchrofReinhold SchwalmErich BeckUwe Meisenburg
    • Wolfgang SchrofReinhold SchwalmErich BeckUwe Meisenburg
    • B05B1700
    • B05D3/061
    • The present invention relates to a method of producing at least one coating film on at least one area of a substrate surface, which comprises at least the following steps in the following order: a) initiating at least one crosslinking reaction in at least one reactive coating formulation; b) applying said at least one reactive coating formulation before the onset of said at least one crosslinking reaction on said at least one area of said substrate surface. The present invention additionally relates to a corresponding means of producing at least one coating film on at least one area of a substrate surface, having at least the following elements: a) at least one storage container for at least one reactive coating formulation, b) at least one exposure unit, preferably a UV exposure unit, more preferably a UV laser, and c) at least one application unit having a nozzle, in particular a spraying head, and/or d) a bell for electrostatic application (ESTA bell), wherein said at least one exposure unit is designed so that the radiation generated in said at least one exposure unit is brought into contact with said at least one reactive coating formulation in said at least one application unit. Also claimed, finally, is a coating film which can be produced by the method of the invention.
    • 本发明涉及在基材表面的至少一个区域上生产至少一种涂膜的方法,该方法至少包括以下顺序的至少一个步骤:a)在至少一种反应性涂料中引发至少一种交联反应 制剂; b)在所述至少一个交联反应开始之前在所述基材表面的所述至少一个区域上施用所述至少一种反应性涂料制剂。本发明还涉及相应的方法, 至少一个基材表面的区域,至少具有以下元素:a)至少一个用于至少一种反应性涂料配方的储存容器,b)至少一个曝光单元,优选UV曝光单元,更优选UV激光 ,和c)至少一个具有喷嘴,特别是喷头的应用单元和/和用于静电施加的钟(ESTA钟)),其中所述至少一个曝光单元 t被设计成使得在所述至少一个曝光单元中产生的辐射与所述至少一个施加单元中的所述至少一个反应性涂料配方接触。最后还要求一种涂膜,其可以由 本发明的方法。
    • 5. 发明授权
    • Method of producing cured coating films
    • 生产固化涂膜的方法
    • US06344244B1
    • 2002-02-05
    • US09433547
    • 1999-11-04
    • Wolfgang SchrofReinhold SchwalmErich BeckUwe Meisenburg
    • Wolfgang SchrofReinhold SchwalmErich BeckUwe Meisenburg
    • C08F248
    • B05D3/061
    • The present invention relates to a method of producing at cast one coating film on at least one area of a substrate surface, which comprises at least the following steps in the following order: a) initiating at least one crosslinking reaction in at least one reactive coating formulation; b) applying said at least one reactive coating formulation before the onset of said at least one crosslinking reaction on said at least one area of said substrate surface. The present invention additionally relates to a corresponding means of producing at least one coating film on at least one area of a substrate surface, having at least the following elements: a) at least one storage container for at least one reactive coating formulation, b) at least one exposure unit, preferably a UV exposure unit, more preferably a UV laser, and c) at least one application unit having a nozzle, in particular a spraying head, and/or d) a bell for electrostatic application (ESTA bell), wherein said at least one exposure unit is designed so that the radiation generated in said at least one exposure unit is brought into contact with said at least one reactive coating formulation in said at least one application unit. Also claimed, finally, is a coating film which can be produced by the method of the invention.
    • 本发明涉及一种在基材表面的至少一个区域上生产浇铸的一个涂膜的方法,该方法至少包括以下顺序的以下步骤:a)在至少一种反应性涂料中引发至少一种交联反应 制剂; b)在所述至少一个交联反应开始之前,在所述基材表面的所述至少一个区域上施用所述至少一种反应性涂料制剂。 本发明还涉及在衬底表面的至少一个区域上产生至少一个涂膜的相应方法,其至少具有以下元素:a)至少一个用于至少一种反应性涂料配方的储存容器,b) 至少一个曝光单元,优选UV曝光单元,更优选UV激光,以及c)至少一个具有喷嘴,特别是喷头的应用单元和/或用于静电应用的钟(ESTA钟)),其中 所述至少一个曝光单元被设计成使得在所述至少一个曝光单元中产生的辐射与所述至少一个应用单元中的所述至少一个反应性涂料配方接触。 最后还要求的是可以通过本发明的方法生产的涂膜。
    • 8. 发明申请
    • PROCESS FOR PREPARING (METH)ACRYLATES OF C10-ALCOHOL MIXTURES
    • 制备C10-醇混合物(甲基)丙烯酸酯的方法
    • US20100317887A1
    • 2010-12-16
    • US12867511
    • 2009-02-26
    • Uwe MeisenburgFrank HoeferReinhold SchwalmNick GruberLothar Karrer
    • Uwe MeisenburgFrank HoeferReinhold SchwalmNick GruberLothar Karrer
    • C07C67/62
    • C07C67/08C07C67/54C07C69/54
    • Process for preparing (meth)acrylates of C10-alcohol mixtures, by reacting (meth)acrylic acid with an isomer mixture of C10-alcohols composed of 2-propylheptanol as the main isomer and at least one of the C10-alcohols 2-propyl-4-methylhexanol, 2-propyl-5-methylhexanol, 2-isopropylheptanol, 2-isopropyl-4-methylhexanol, 2-isopropyl-5-methylhexanol and/or 2-propyl-4,4-dimethylpentanol, in the presence of at least one acidic catalyst and of at least one polymerization inhibitor and in the presence of a solvent which forms an azeotrope with water, the azeotrope is distilled off and condensed, and the condensate splits into an aqueous phase and an organic phase, wherein a) the esterification is performed in a reactor with a circulation evaporator and b) in the presence of a solvent, and c) the crude product is purified by subsequent purifying distillation.
    • 通过使(甲基)丙烯酸与由2-丙基庚醇组成的C 10醇的异构体混合物作为主要异构体和至少一种C10-醇2-丙基 - 丙烯酸的至少一种来制备C10-醇混合物的(甲基)丙烯酸酯的方法, 4-甲基己醇,2-丙基-5-甲基己醇,2-异丙基庚醇,2-异丙基-4-甲基己醇,2-异丙基-5-甲基己醇和/或2-丙基-4,4-二甲基戊醇,在至少 一种酸性催化剂和至少一种聚合抑制剂,并且在与水形成共沸物的溶剂的存在下,蒸馏出共沸物并冷凝,并且冷凝物分解成水相和有机相,其中a)酯化 在具有循环蒸发器的反应器中进行,和b)在溶剂存在下进行,和c)通过随后的纯化蒸馏纯化粗产物。