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    • 1. 发明授权
    • Apparatuses and methods for cracking hydrocarbons
    • 碳氢化合物裂化装置和方法
    • US09527054B2
    • 2016-12-27
    • US14274540
    • 2014-05-09
    • UOP LLC
    • Trung PhamLev DavydovLance Awender Baird
    • B01J8/26C10G55/00C10G51/06C10G69/00C10G3/00
    • B01J8/26B01J2208/00991C10G3/42C10G51/06C10G55/00C10G69/00C10G2300/1014C10G2300/1077C10G2300/4056Y02P30/20
    • Methods and apparatuses are provided for cracking a hydrocarbon. The method includes contacting a first hydrocarbon stream with a first cracking catalyst at a first cracking temperature in a first riser to produce a first riser effluent and a first spent catalyst. A second hydrocarbon stream is contacted with a second cracking catalyst at a second cracking temperature in a second riser to produce a second riser effluent and a second spent catalyst, where the second cracking temperature is less than the first cracking temperature. The first riser effluent and the second riser effluent are combined to produce a mixed riser effluent, and the mixed riser effluent is fractionated in a fractionation zone to produce a light cycle oil. The first spent catalyst and the second spent catalyst are combined in a reactor to produce a mixed spent catalyst.
    • 提供了开裂烃的方法和装置。 该方法包括使第一烃流与第一裂解催化剂在第一提升管中以第一裂解温度接触以产生第一提升管流出物和第一废催化剂。 第二烃流在第二提升管中以第二裂解温度与第二裂解催化剂接触以产生第二提升管流出物和第二废催化剂,其中第二裂解温度小于第一裂解温度。 将第一提升管流出物和第二提升管流出物混合以产生混合提升管流出物,并将混合提升管流出物在分馏区中分馏以产生轻循环油。 将第一废催化剂和第二废催化剂在反应器中混合以产生混合的废催化剂。
    • 2. 发明申请
    • METHODS AND APPARATUSES FOR DEOXYGENATING PYROLYSIS OIL
    • 脱氧油的方法和装置
    • US20160145172A1
    • 2016-05-26
    • US14551797
    • 2014-11-24
    • UOP LLC
    • Lance Awender BairdTimothy A. BrandvoldStanley Joseph Frey
    • C07C1/22C07C5/367C07C7/04
    • C07C1/22C07C5/367C07C2521/04C07C2521/06C07C2523/42C07C2523/44C10G3/42C10G3/47Y02P30/20
    • Methods and apparatuses are provided for deoxygenating pyrolysis oil. A method includes contacting a pyrolysis oil with a deoxygenation catalyst in a first reactor at deoxygenation conditions to produce a first reactor effluent. The first reactor effluent has a first oxygen concentration and a first hydrogen concentration, based on hydrocarbons in the first reactor effluent, and the first reactor effluent includes an aromatic compound. The first reactor effluent is contacted with a dehydrogenation catalyst in a second reactor at conditions that deoxygenate the first reactor effluent while preserving the aromatic compound to produce a second reactor effluent. The second reactor effluent has a second oxygen concentration lower than the first oxygen concentration and a second hydrogen concentration that is equal to or lower than the first hydrogen concentration, where the second oxygen concentration and the second hydrogen concentration are based on the hydrocarbons in the second reactor effluent.
    • 提供了用于脱氧裂解油的方法和装置。 一种方法包括在脱氧条件下在第一反应器中使热解油与脱氧催化剂接触以产生第一反应器流出物。 基于第一反应器流出物中的烃,第一反应器流出物具有第一氧浓度和第一氢气浓度,并且第一反应器流出物包括芳族化合物。 将第一反应器流出物与第二反应器中的脱氢催化剂接触,在脱氧第一反应器流出物的同时保留芳族化合物以产生第二反应器流出物。 第二反应器流出物具有低于第一氧浓度的第二氧浓度和等于或低于第一氢浓度的第二氢浓度,其中第二氧浓度和第二氢浓度基于第二氧浓度 反应器流出物。
    • 3. 发明申请
    • APPARATUSES AND METHODS FOR CRACKING HYDROCARBONS
    • 破碎油料的装置和方法
    • US20150322355A1
    • 2015-11-12
    • US14274540
    • 2014-05-09
    • UOP LLC
    • Trung PhamLev DavydovLance Awender Baird
    • C10G51/06B01J8/26C10G55/00
    • B01J8/26B01J2208/00991C10G3/42C10G51/06C10G55/00C10G69/00C10G2300/1014C10G2300/1077C10G2300/4056Y02P30/20
    • Methods and apparatuses are provided for cracking a hydrocarbon. The method includes contacting a first hydrocarbon stream with a first cracking catalyst at a first cracking temperature in a first riser to produce a first riser effluent and a first spent catalyst. A second hydrocarbon stream is contacted with a second cracking catalyst at a second cracking temperature in a second riser to produce a second riser effluent and a second spent catalyst, where the second cracking temperature is less than the first cracking temperature. The first riser effluent and the second riser effluent are combined to produce a mixed riser effluent, and the mixed riser effluent is fractionated in a fractionation zone to produce a light cycle oil. The first spent catalyst and the second spent catalyst are combined in a reactor to produce a mixed spent catalyst.
    • 提供了开裂烃的方法和装置。 该方法包括使第一烃流与第一裂解催化剂在第一提升管中以第一裂解温度接触以产生第一提升管流出物和第一废催化剂。 第二烃流在第二提升管中以第二裂解温度与第二裂解催化剂接触以产生第二提升管流出物和第二废催化剂,其中第二裂解温度小于第一裂解温度。 将第一提升管流出物和第二提升管流出物混合以产生混合提升管流出物,并将混合提升管流出物在分馏区中分馏以产生轻循环油。 将第一废催化剂和第二废催化剂在反应器中混合以产生混合的废催化剂。
    • 5. 发明申请
    • METHODS AND SYSTEMS FOR DEOXYGENATING BIOMASS-DERIVED PYROLYSIS OIL WITH A RECYCLE COLUMN
    • 用循环柱去除生物质衍生的热解油的方法和系统
    • US20150159093A1
    • 2015-06-11
    • US14101842
    • 2013-12-10
    • UOP LLC
    • Lance Awender BairdTimothy A. BrandvoldPraneeth Dayanthe Edirisinghe
    • C10G3/00
    • C10G3/50C10G33/00Y02P30/20
    • Methods and systems for deoxygenating a biomass-derived pyrolysis oil are provided. An exemplary method includes combining a biomass-derived pyrolysis oil stream with a heated low-molecular weight fraction low-oxygen-pyoil diluent recycle stream to form a heated diluted pyoil feed stream, which is contacted with a first deoxygenating catalyst in the presence of hydrogen at first hydroprocessing conditions effective to form a low-oxygen biomass-derived pyrolysis oil effluent. A low-molecular weight fraction low-oxygen-pyoil diluent recycle stream is formed by contacting the low-oxygen biomass-derived pyrolysis oil effluent with a fractionation column to separate a low molecular weight fraction low-oxygen-pyoil diluent recycle stream at a cutpoint of about 225° C. or less. The low-molecular weight fraction low-oxygen-pyoil diluent recycle stream is then heated prior to combination with the biomass-derived pyrolysis oil stream.
    • 提供了用于脱氧生物质衍生的热解油的方法和系统。 一种示例性方法包括将生物质衍生的热解油流与加热的低分子量馏分低氧 - 稀土稀释剂循环流组合以形成加热的稀释的原料流,其在氢气存在下与第一脱氧催化剂接触 首先加氢处理条件有效地形成低氧生物质衍生的裂解油流出物。 通过使低氧生物质衍生的热解油流出物与分馏塔接触来形成低分子量级分的低氧 - 稀土稀释剂循环流,以在切断点处分离低分子量级分的低氧 - 稀释剂再循环流 约225℃或更低。 然后在与生物质衍生的热解油流组合之前加热低分子量级分的低氧 - 稀土稀释剂再循环物流。