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    • 5. 发明授权
    • ReCrNi alloy coating for diffusion barrier
    • ReCrNi合金涂层用于扩散屏障
    • US07192655B2
    • 2007-03-20
    • US10494022
    • 2002-09-13
    • Toshio NaritaShigenari HayashiTakayuki YoshiokaHiroshi Yakuwa
    • Toshio NaritaShigenari HayashiTakayuki YoshiokaHiroshi Yakuwa
    • B32B15/00
    • C23C28/321C23C28/325C23C28/345C23C30/00Y02T50/67Y10T428/12Y10T428/12493Y10T428/12771Y10T428/12847Y10T428/12854Y10T428/12937
    • Disclosed is a ReCrNi alloy coating for diffusion barrier, such as a high-temperature equipment member, consisting essentially of a ternary alloy and having, except for inevitable impurities, an atomic composition of 20% to 80% Re, an atomic composition of 20% to 60% Cr, and an atomic composition of 5% to 40% Ni. Even if the alloy coating for diffusion barrier includes a diffusion layer containing at least one of the group consisting of Al, Si and Cr, a desired alloy composition of the alloy coating for diffusion barrier can be assured by a surface coating process and diffused components from the substrate while substantially preventing the diffusion of the elements of the diffusion layer during a homogenizing heat treatment. The alloy coating for diffusion barrier may include a Re-containing-alloy stress relief layer inserted between the film and the substrate. The ReCrNi alloy coating can suppress the deterioration of the substrate and the coating layer due to the reaction therebetween to provide an extended life span of the equipment member.
    • 公开了用于扩散阻挡层的ReCrNi合金涂层,例如高温设备构件,其基本上由三元合金组成,除了不可避免的杂质外,其原子组成为20%至80%Re,原子组成为20% 至60%的Cr,原子组成为5%至40%的Ni。 即使用于扩散阻挡层的合金涂层包括含有由Al,Si和Cr组成的组中的至少一种的扩散层,也可以通过表面涂覆工艺和扩散组分来确保用于扩散阻挡层的合金涂层的所需合金组成 同时基本上防止在均质化热处理期间扩散层的元件的扩散。 用于扩散阻挡层的合金涂层可以包括插入在膜和衬底之间的Re含合金应力消除层。 ReCrNi合金涂层可以抑制由于它们之间的反应导致的基板和涂层的劣化,从而延长设备的使用寿命。
    • 6. 发明授权
    • Method for forming Re—Cr alloy film or Re-based film through electroplating process
    • 通过电镀工艺形成Re-Cr合金膜或Re基膜的方法
    • US06979392B2
    • 2005-12-27
    • US10501720
    • 2003-01-17
    • Toshio NaritaShigenari HayashiTakayuki YoshiokaHiroshi YakuwaMichiaki Souma
    • Toshio NaritaShigenari HayashiTakayuki YoshiokaHiroshi YakuwaMichiaki Souma
    • C25D3/56
    • C25D3/56
    • Disclosed is a method for forming: a Re—Cr alloy film consisting of Re in the range of greater than 0 (zero) to less than 98% by atomic composition, and the remainder being Cr except inevitable impurities; a Re-based film consisting of 98% or more, by atomic composition, of Re, with the remainder being Cr and inevitable impurities; or a Re—Cr—Ni alloy film consisting of Re in the range of 50 to less than 98% by atomic composition, Cr in the range of 2 to less than 45% by atomic composition, and the remainder being Ni except inevitable impurities. The method comprises performing an electroplating process using an electroplating bath containing an aqueous solution which includes a perrhenate ion and a chromium (III) ion. The present invention allows a Re—Cr alloy, Re-based or Re—Cr—Ni alloy film usable as a corrosion-resistant alloy coating for a high-temperature component or the like to be formed through an electroplating process using an aqueous solution, so as to provide heat/corrosion resistances to the component, even if it has a complicated shape, in a simplified manner at a low cost.
    • 公开了一种用于形成由Re组成的Re-Cr合金膜的方法,所述Re在大于0(零)至小于98%的范围内的原子组成,其余为除了不可避免的杂质之外的Cr; 由Re原子组成为98%以上的Re基膜,其余为Cr和不可避免的杂质; 或由Re组成的Re-Cr-Ni合金膜的原子组成为50〜小于98%的范围,Cr为2〜小于45原子的组成,余量为Ni,不包括不可避免的杂质。 该方法包括使用含有包含高铼酸根离子和铬(III)离子的水溶液的电镀浴进行电镀工艺。 本发明允许通过使用水溶液的电镀工艺形成可用作高温组分等的耐腐蚀合金涂层的Re-Cr合金,Re基或Re-Cr-Ni合金膜, 以便以简单的方式以低成本为零件提供耐热/耐腐蚀性,即使其具有复杂的形状。
    • 7. 发明申请
    • Recrni alloy coating for diffusion barrier
    • 用于扩散屏障的合金涂层
    • US20050037222A1
    • 2005-02-17
    • US10494022
    • 2002-09-13
    • Toshio NaritaShigenari HayashiTakayuki YoshiokaHiroshi Yakuwa
    • Toshio NaritaShigenari HayashiTakayuki YoshiokaHiroshi Yakuwa
    • C23C28/00C23C28/02C23C30/00B32B1/00
    • C23C28/321C23C28/325C23C28/345C23C30/00Y02T50/67Y10T428/12Y10T428/12493Y10T428/12771Y10T428/12847Y10T428/12854Y10T428/12937
    • Disclosed is a ReCrNi alloy coating for diffusion barrier, such as a high-temperature equipment member, consisting essentially of a ternary alloy and having, except for inevitable impurities, an atomic composition of 20 % to 80 % Re, an atomic composition of 20 % to 60 % Cr, and an atomic composition of 5 % to 40 % Ni. Even if the alloy coating for diffusion barrier includes a diffusion layer containing at least one of the group consisting of Al, Si and Cr, a desired alloy composition of the alloy coating for diffusion barrier can be assured by a surface coating process and diffused components from the substrate while substantially preventing the diffusion of the elements of the diffusion layer during a homogenizing heat treatment. The alloy coating for diffusion barrier may include a Re-containing-alloy stress relief layer inserted between the film and the substrate. The ReCrNi alloy coating can suppress the deterioration of the substrate and the coating layer due to the reaction therebetween to provide an extended life span of the equipment member.
    • 公开了一种用于扩散阻挡层的ReCrNi合金涂层,例如高温设备构件,其基本上由三元合金组成,除了不可避免的杂质外,其原子组成为20%至80%Re,原子组成为20% 至60%的Cr,原子组成为5%至40%的Ni。 即使用于扩散阻挡层的合金涂层包括含有由Al,Si和Cr组成的组中的至少一种的扩散层,也可以通过表面涂覆工艺和扩散组分来确保用于扩散阻挡层的合金涂层的所需合金组成 同时基本上防止在均质化热处理期间扩散层的元件的扩散。 用于扩散阻挡层的合金涂层可以包括插入在膜和衬底之间的Re含合金应力消除层。 ReCrNi合金涂层可以抑制由于它们之间的反应导致的基板和涂层的劣化,从而延长设备的使用寿命。
    • 9. 发明申请
    • Method for forming re coating film or re-cr alloy coating film through electroplating
    • 通过电镀形成再涂膜或再Cr合金涂膜的方法
    • US20050126922A1
    • 2005-06-16
    • US10501720
    • 2003-01-17
    • Toshio NaritaShigenari HayashiTakayuki YoshiokaHiroshi YakuwaMichiaki Souma
    • Toshio NaritaShigenari HayashiTakayuki YoshiokaHiroshi YakuwaMichiaki Souma
    • C25D3/56
    • C25D3/56
    • Disclosed is a method for forming: a Re—Cr alloy film consisting of Re in the range of greater than 0 (zero) to less than 98% by atomic composition, and the remainder being Cr except inevitable impurities; a Re-based film consisting of 98% or more, by atomic composition, of Re, with the remainder being Cr and inevitable impurities; or a Re—Cr—Ni alloy film consisting of Re in the range of 50 to less than 98% by atomic composition, Cr in the range of 2 to less than 45% by atomic composition, and the remainder being Ni except inevitable impurities. The method comprises performing an electroplating process using an electroplating bath containing an aqueous solution which includes a perrhenate ion and a chromium (III) ion. The present invention allows a Re—Cr alloy, Re-based or Re—Cr—Ni alloy film usable as a corrosion-resistant alloy coating for a high-temperature component or the like to be formed through an electroplating process using an aqueous solution, so as to provide heat/corrosion resistances to the component, even if it has a complicated shape, in a simplified manner at a low cost.
    • 公开了一种用于形成由Re组成的Re-Cr合金膜的方法,所述Re在大于0(零)至小于98%的范围内的原子组成,其余为除了不可避免的杂质之外的Cr; 由Re原子组成为98%以上的Re基膜,其余为Cr和不可避免的杂质; 或由Re组成的Re-Cr-Ni合金膜的原子组成为50〜小于98%的范围,Cr为2〜小于45原子的组成,余量为Ni,不包括不可避免的杂质。 该方法包括使用含有包含高铼酸根离子和铬(III)离子的水溶液的电镀浴进行电镀工艺。 本发明允许通过使用水溶液的电镀工艺形成可用作高温组分等的耐腐蚀合金涂层的Re-Cr合金,Re基或Re-Cr-Ni合金膜, 以便以简单的方式以低成本为零件提供耐热/耐腐蚀性,即使其具有复杂的形状。
    • 10. 发明授权
    • ReCr alloy coating for diffusion barrier
    • ReCr合金涂层用于扩散屏障
    • US07060368B2
    • 2006-06-13
    • US10494015
    • 2002-09-13
    • Toshio NaritaShigenari HayashiTakayuki YoshiokaHiroshi Yakuwa
    • Toshio NaritaShigenari HayashiTakayuki YoshiokaHiroshi Yakuwa
    • B32B15/00
    • C23C28/321C23C28/325C23C28/345C23C28/3455C23C30/00Y02T50/67Y10T428/12771Y10T428/12854Y10T428/12944
    • Disclosed is a ReCr alloy coating for diffusion barrier formed on a substrate, such as a high-temperature equipment member, which comprises an atomic composition of 50% to less than 90% Re, with the remainder consisting essentially of Cr except for inevitable impurities. Even if the alloy coating for diffusion barrier includes a diffusion layer containing at least one of the group consisting of Al, Si and Cr, a desired alloy composition of the alloy coating for diffusion barrier can be assured by a surface coating process and diffused components from the substrate while substantially preventing the diffusion of the elements of the diffusion layer during a homogenizing heat treatment. The alloy coating for diffusion barrier may include a Re-containing-alloy stress relief layer inserted between the film and the substrate. The ReCr—Ni alloy coating can suppress the deterioration of the substrate and the coating layer due to the reaction therebetween to provide an extended life span of the equipment member.
    • 公开了一种用于扩散阻挡层的ReCr合金涂层,其形成在诸如高温设备构件的基底上,其包含50%至小于90%的Re的原子组成,其余余量基本上由Cr除外,不同之处在于不可避免的杂质。 即使用于扩散阻挡层的合金涂层包括含有由Al,Si和Cr组成的组中的至少一种的扩散层,也可以通过表面涂覆工艺和扩散组分来确保用于扩散阻挡层的合金涂层的所需合金组成 同时基本上防止在均质化热处理期间扩散层的元件的扩散。 用于扩散阻挡层的合金涂层可以包括插入在膜和衬底之间的Re含合金应力消除层。 ReCr-Ni合金涂层可以抑制由于其间的反应导致的基板和涂层的劣化,从而延长设备构件的使用寿命。