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1. 发明授权

US4243610A Cobalt-gold promoter for ruthenium hydrogenation catalyst as in hydrogenation of unsaturated dinitriles 失效
标题翻译：用于钌氢化催化剂的钴 - 金助催化剂，如在不饱和二腈的氢化中
公开(公告)号：US4243610A
公开(公告)日：1981-01-06
申请号：US92778
申请日：1979-11-08
申请人： Charles A. Drake , Timothy P. Murtha
发明人： Charles A. Drake , Timothy P. Murtha
IPC分类号： B01J23/89 , C07C209/48 , C07C209/70 , C07C85/12
CPC分类号： C07C209/70 , B01J23/8913 , C07C209/48
摘要： Cobalt and gold in a ruthenium hydrogenation catalyst markedly increases the yield of product. A method for hydrogenating branched-chain olefinically unsaturated aliphatic dinitrile employing a ruthenium-cobalt-gold catalyst to produce saturated diamines is set forth.
摘要翻译：钌加氢催化剂中的钴和金显着提高了产品的产率。阐述了使用钌 - 钴 - 金催化剂氢化支链烯属不饱和脂族二腈以制备饱和二胺的方法。

2. 发明授权

US4311859A Catalytic hydrogenation of unsaturated dinitriles 失效
标题翻译：不饱和二腈的催化氢化
公开(公告)号：US4311859A
公开(公告)日：1982-01-19
申请号：US213444
申请日：1980-12-05
申请人： Timothy P. Murtha , Charles A. Drake
发明人： Timothy P. Murtha , Charles A. Drake
IPC分类号： B01J23/46 , C07C209/48 , C07C85/12
CPC分类号： B01J23/464 , C07C209/48
摘要： Unsaturated dinitriles are hydrogenated to saturated diamines using a rhodium catalyst on a silica support having a surface area larger than 275 m.sup.2 /g, a pore volume of from about 1.0 to 1.5 mL/g and an average pore size of from about 100 to about 175 A. The supported rhodium catalyst is prepared by a method which includes the steps of contacting a silica support having the characteristics described above with a solution or dispersion of rhodium or a reducible compound of rhodium, and then subjecting the impregnated silica support to vacuum treatment.
摘要翻译：使用表面积大于275m 2 / g，孔体积为约1.0至1.5mL / g，平均孔径为约100至约175的二氧化硅载体上的铑催化剂将不饱和二腈氢化为饱和二胺 A.负载的铑催化剂通过包括以下步骤的方法制备：将具有上述特征的二氧化硅载体与铑或可还原的铑化合物的溶液或分散体接触，然后使浸渍的二氧化硅载体进行真空处理。

3. 发明授权

US4215019A Ruthenium-cobalt-gold catalyst for hydrogenation of unsaturated dinitriles 失效
标题翻译：用于氢化不饱和二腈的钌 - 钴 - 金催化剂
公开(公告)号：US4215019A
公开(公告)日：1980-07-29
申请号：US960798
申请日：1978-11-14
申请人： Charles A. Drake , Timothy P. Murtha
发明人： Charles A. Drake , Timothy P. Murtha
IPC分类号： B01J23/89 , C07C209/48 , C07C209/70 , B01J21/04 , B01J23/46 , B01J23/52 , B01J23/74
CPC分类号： B01J23/8913 , C07C209/48 , C07C209/70
摘要： Cobalt and gold in a ruthenium hydrogenation catalyst markedly increases the yield of product. A method for hydrogenating branched-chain olefinically unsaturated aliphatic dinitrile employing a ruthenium-cobalt-gold catalyst to produce saturated diamines is set forth.
摘要翻译：钌加氢催化剂中的钴和金显着提高了产品的产率。阐述了使用钌 - 钴 - 金催化剂氢化支链烯属不饱和脂族二腈以制备饱和二胺的方法。

4. 发明授权

US4383940A Catalysts for hydrogenation of unsaturated dinitriles 失效
标题翻译：不饱和二腈的氢化催化剂
公开(公告)号：US4383940A
公开(公告)日：1983-05-17
申请号：US326108
申请日：1981-11-30
申请人： Timothy P. Murtha , Charles A. Drake
发明人： Timothy P. Murtha , Charles A. Drake
IPC分类号： B01J23/46 , B01J35/10 , C07C209/48 , B01J21/08
CPC分类号： C07C209/48 , B01J23/464 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J35/1061
摘要： Unsaturated dinitriles are hydrogenated to saturated diamines using a rhodium catalyst on a silica support having a surface area larger than 275 m.sup.2 /g, a pore volume of from about 1.0 to 1.5 mL/g and an average pore size of from about 100 to about 175 A. The supported rhodium catalyst is prepared by a method which includes the steps of contacting a silica support having the characteristics described above with a solution or dispersion of rhodium or a reducible compound of rhodium, and then subjecting the impregnated silica support to vacuum treatment.
摘要翻译：使用表面积大于275m 2 / g，孔体积为约1.0至1.5mL / g，平均孔径为约100至约175的二氧化硅载体上的铑催化剂将不饱和二腈氢化为饱和二胺 A.负载的铑催化剂通过包括以下步骤的方法制备：将具有上述特征的二氧化硅载体与铑或可还原的铑化合物的溶液或分散体接触，然后使浸渍的二氧化硅载体进行真空处理。

5. 发明授权

US06784332B1 Processes employing hydrocarbon conversion catalyst 失效
标题翻译：使用烃转化催化剂的方法
公开(公告)号：US06784332B1
公开(公告)日：2004-08-31
申请号：US09691494
申请日：2000-10-18
申请人： James B. Kimble , Charles A. Drake , Jianhua Yao , An-hsiang Wu
发明人： James B. Kimble , Charles A. Drake , Jianhua Yao , An-hsiang Wu
IPC分类号： C07C510
CPC分类号： B01J29/40 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C10G35/095
摘要： A hydrocarbon conversion process comprising contacting a hydrocarbon stream such as, for example, gasoline, with a catalyst composition to effect the conversion of the hydrocarbon to olefins and C6 to C8 aromatic hydrocarbons such as toluene and xylenes. The catalyst composition comprises a zeolite, a promoter and optionally a binder.
摘要翻译：烃转化方法包括使烃流例如汽油与催化剂组合物接触，以使碳氢化合物转化为烯烃和C 6至C 8芳族烃如甲苯和二甲苯。催化剂组合物包含沸石，助催化剂和任选的粘合剂。

6. 发明授权

US06593503B1 Process for making aromatic hydrocarbons using an acid treated zeolite 失效
标题翻译：使用酸处理的沸石制备芳烃的方法
公开(公告)号：US06593503B1
公开(公告)日：2003-07-15
申请号：US08695482
申请日：1996-08-12
申请人： An-hsiang Wu , Charles A. Drake , Ralph J. Melton
发明人： An-hsiang Wu , Charles A. Drake , Ralph J. Melton
IPC分类号： C07C600
CPC分类号： C07C6/10 , C07C2529/40 , C07C15/02
摘要： A catalyst composition and a process for converting a hydrocarbon stream such as, for example, gasoline to C6 to C8 aromatic hydrocarbons such as toluene and xylenes are disclosed. The catalyst composition includes an alumina, a silica, and a metal wherein the weight ratio of aluminum to silicon is in the range of from about 0.002:1 to about 0.6:1. The process includes contacting a hydrocarbon stream with the catalyst composition under a condition sufficient to effect the conversion of a hydrocarbon to a C6 to C8 aromatic hydrocarbon. Also disclosed is a process for producing the catalyst composition which includes: (1) contacting a zeolite with an effective amount of an acid under a condition sufficient to effect a reduction in aluminum content of the zeolite to produce an acid-leached zeolite; and (2) impregnating the acid-leached zeolite with an effective amount of a metal compound under a condition sufficient to effect the production of a metal-promoted zeolite.
摘要翻译：公开了一种催化剂组合物和将烃流例如汽油转化为C 6至C 8芳族烃如甲苯和二甲苯的方法。催化剂组合物包括氧化铝，二氧化硅和金属，其中铝与硅的重量比在约0.002:1至约0.6:1的范围内。该方法包括使烃流与催化剂组合物在足以使碳氢化合物转化为C 6至C 8芳族烃的条件下接触。还公开了一种生产催化剂组合物的方法，其包括：（1）在足以使沸石的铝含量降低以产生酸浸出的沸石的条件下使沸石与有效量的酸接触; 和（2）在足以产生金属促进的沸石的条件下，用有效量的金属化合物浸渍酸浸出的沸石。

7. 发明授权

US06420295B1 Hydrocarbon conversion catalyst composition and process therefor and therewith 失效
标题翻译：烃转化催化剂组合物及其工艺及其
公开(公告)号：US06420295B1
公开(公告)日：2002-07-16
申请号：US09634492
申请日：2000-08-08
申请人： An-hsiang Wu , Charles A. Drake
发明人： An-hsiang Wu , Charles A. Drake
IPC分类号： B01J2940
CPC分类号： B01J37/0203 , B01J29/061 , B01J29/40 , B01J37/086 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C10G35/095
摘要： A catalyst composition, a process for producing the catalyst composition, and a hydroconversion process for converting a fluid stream comprising at least one saturated hydrocarbon to C6 to C8 aromatic hydrocarbons such as benzene, toluene, and xylenes are disclosed. The catalyst composition comprises a zeolite and a promoter. The process for producing the composition comprises the steps of: (1) combining a zeolite with a complexing ligand and a promoter compound under a condition sufficient to produce a modified zeolite; and (2) heating the modified zeolite to produce a promoted zeolite. The hydroconversion process comprises contacting a fluid stream with the catalyst composition under a condition sufficient to effect the conversion of a saturated hydrocarbon to a C6 to C8 aromatic hydrocarbon.
摘要翻译：公开了一种催化剂组合物，用于制备催化剂组合物的方法和用于将包含至少一种饱和烃的流体流转化为C 6至C 8芳族烃如苯，甲苯和二甲苯的加氢转化方法。催化剂组合物包含沸石和助催化剂。制备组合物的方法包括以下步骤：（1）在足以产生改性沸石的条件下将沸石与络合配体和助催化剂化合物结合; 和（2）加热改性沸石以产生促进的沸石。加氢转化方法包括在足以使饱和烃转化为C6至C8芳族烃的条件下使流体物流与催化剂组合物接触。

8. 发明授权

US06395949B1 Acid treated zeolite containing phosphorus used as a catalyst in processes for converting hydrocarbons, and use of binary hydrocarbon mixtures as diluents in processes for converting hydrocarbons 失效
标题翻译：含有磷的酸处理沸石在用于转化烃的方法中用作催化剂，并且在转化烃的方法中使用二元烃混合物作为稀释剂
公开(公告)号：US06395949B1
公开(公告)日：2002-05-28
申请号：US09627103
申请日：2000-07-27
申请人： Charles A. Drake , Jianhua Yao
发明人： Charles A. Drake , Jianhua Yao
IPC分类号： C07C402
CPC分类号： C10G35/095 , B01J27/182 , B01J29/40 , C10G2400/22 , C10G2400/30
摘要： A method of increasing total diluent conversion in a process for the conversion of cracked gasoline and a first diluent comprising iso-pentane to aromatics and light olefins by contacting the cracked gasoline, the first diluent and a second diluent comprising either propane or 1-hexene with a zeolite catalyst containing phosphorus. The zeolite catalyst comprises a calcined, acid-leached zeolite and phosphorus. Also described is a method of making such catalyst.
摘要翻译：一种在裂化汽油转化方法中提高总稀释剂转化率的方法，以及将包含异戊烷的第一稀释剂与芳族化合物和轻质烯烃转化的方法，该方法是将裂化汽油，第一稀释剂和包含丙烷或1-己烯的第二稀释剂与含磷的沸石催化剂。沸石催化剂包括煅烧的，酸浸的沸石和磷。还描述了制备这种催化剂的方法。

9. 发明授权

US06235954B1 Hydrocarbon hydrogenation catalyst and process 失效
公开(公告)号：US06235954B1
公开(公告)日：2001-05-22
申请号：US09408824
申请日：1999-09-29
申请人： An-hsiang Wu , Charles A. Drake
发明人： An-hsiang Wu , Charles A. Drake
IPC分类号： C07C505
CPC分类号： C10G45/34 , B01J29/076 , C07C5/03 , C07C2529/076
摘要： A catalyst composition and process for preparing such catalyst composition which can be useful in contacting a hydrocarbon-containing fluid which contains a highly unsaturated hydrocarbon such as 1,3-butadiene, in the presence of hydrogen, with such catalyst composition in a hydrogenation zone under a hydrogenation condition effective to hydrogenate such highly unsaturated hydrocarbon to a less unsaturated hydrocarbon such as n-butene is disclosed. Such process for preparing a catalyst composition includes (1) combining a zeolite, a Group VIB metal, and an inorganic support to form a modified zeolite; (2) calcining such modified zeolite under a calcining condition to produce a calcined, modified zeolite; and (3) contacting such calcined, modified zeolite with a carburizing agent under a carburizing condition to provide such catalyst composition.

10. 发明授权

US6124515A Catalytic conversion of a saturated hydrocarbon to an aromatic hydrocarbon 失效
标题翻译：将饱和烃催化转化成芳烃
公开(公告)号：US6124515A
公开(公告)日：2000-09-26
申请号：US404669
申请日：1999-09-23
申请人： An-hsiang Wu , Charles A. Drake
发明人： An-hsiang Wu , Charles A. Drake
IPC分类号： B01J29/06 , B01J29/40 , B01J37/02 , B01J37/08 , C10G35/095 , C07C2/52 , C07C6/00 , C10G35/06
CPC分类号： B01J37/0203 , B01J29/061 , B01J29/40 , B01J37/086 , C10G35/095 , B01J2229/26 , B01J2229/36 , B01J2229/42
摘要： A catalyst composition, a process for producing the catalyst composition, and a hydroconversion process for converting a fluid stream comprising at least one saturated hydrocarbon to C.sub.6 to C.sub.8 aromatic hydrocarbons such as benzene, toluene, and xylenes are disclosed. The catalyst composition comprises a zeolite and a promoter. The process for producing the composition comprises the steps of: (1) combining a zeolite with a complexing ligand and a promoter compound under a condition sufficient to produce a modified zeolite; and (2) heating the modified zeolite to produce a promoted zeolite. The hydroconversion process comprises contacting a fluid stream with the catalyst composition under a condition sufficient to effect the conversion of a saturated hydrocarbon to a C.sub.6 to C.sub.8 aromatic hydrocarbon.
摘要翻译：公开了一种催化剂组合物，用于制备催化剂组合物的方法和用于将包含至少一种饱和烃的流体流转化为C 6至C 8芳族烃如苯，甲苯和二甲苯的加氢转化方法。催化剂组合物包含沸石和助催化剂。制备组合物的方法包括以下步骤：（1）在足以产生改性沸石的条件下将沸石与络合配体和助催化剂化合物结合; 和（2）加热改性沸石以产生促进的沸石。加氢转化方法包括在足以使饱和烃转化为C6至C8芳族烃的条件下使流体物流与催化剂组合物接触。

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