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1. 发明申请

US20130245173A1 PROCESSING AID FOR THERMOPLASTIC POLYURETHANES 审中-公开
标题翻译：热塑性聚氨酯加工助剂
公开(公告)号：US20130245173A1
公开(公告)日：2013-09-19
申请号：US13892722
申请日：2013-05-13
申请人： Thomas Welker , Ulrich Boes , Frank Menzel , Dieter Kuhn , Uwe Schachtely , Didier Lagneaux , Henri Sautel
发明人： Thomas Welker , Ulrich Boes , Frank Menzel , Dieter Kuhn , Uwe Schachtely , Didier Lagneaux , Henri Sautel
IPC分类号： C08K5/5419
CPC分类号： C08K5/5419 , C08G18/0895 , C08G18/4208 , C08G18/4879 , C08G18/7664 , C08J3/226 , C08J2375/04 , C08J2475/00 , C08K3/36 , C08K9/06 , C08L75/04 , Y10T428/139 , C08L2666/20
摘要： A processing aid is used in the processing of thermoplastic polyurethanes to give various articles including a self-supporting film. The processing aid contains a) 10-50% by weight of hydrophobized, at least partially aggregated, metal oxide particles selected from the group consisting of aluminium oxide, silicon dioxide and mixtures thereof, b) 20-75% by weight of one or more thermoplastic polyurethanes, c) 0.5-25% by weight of one or more isocyanates, d) 0.5-15% by weight of one or more compounds which act as lubricant and dispersant, the sum of the constituents a) to d) amounting to at least 90% by weight, based on a total weight of said processing aid.
摘要翻译：在热塑性聚氨酯的加工中使用加工助剂以产生包括自支撑膜的各种制品。加工助剂包含a）10-50重量％的选自氧化铝，二氧化硅及其混合物的疏水化，至少部分聚集的金属氧化物颗粒，b）20-75重量％的一种或多种热塑性聚氨酯，c）0.5-25重量％的一种或多种异氰酸酯，d）0.5-15重量％的一种或多种充当润滑剂和分散剂的化合物，组分a）至d）的总和相当于至少90重量％，基于所述加工助剂的总重量。

2. 发明申请

US20100092710A1 PROCESSING AID FOR THERMOPLASTIC POLYURETHANES 审中-公开
标题翻译：热塑性聚氨酯加工助剂
公开(公告)号：US20100092710A1
公开(公告)日：2010-04-15
申请号：US12579609
申请日：2009-10-15
申请人： Thomas Welker , Ulrich Boes , Frank Menzel , Dieter Kuhn , Uwe Schachtely , Didier Lagneaux , Henri Sautel
发明人： Thomas Welker , Ulrich Boes , Frank Menzel , Dieter Kuhn , Uwe Schachtely , Didier Lagneaux , Henri Sautel
IPC分类号： B32B1/08 , C08K3/22 , C08L75/04 , C08K5/5419 , C08K5/10 , C08K5/20 , B29B11/10 , B29C47/14
CPC分类号： C08K5/5419 , C08G18/0895 , C08G18/4208 , C08G18/4879 , C08G18/7664 , C08J3/226 , C08J2375/04 , C08J2475/00 , C08K3/36 , C08K9/06 , C08L75/04 , Y10T428/139 , C08L2666/20
摘要： A processing aid is used in the processing of thermoplastic polyurethanes to give various articles including a self-supporting film. The processing aid contains a) 10-50% by weight of hydrophobized, at least partially aggregated, metal oxide particles selected from the group consisting of aluminium oxide, silicon dioxide and mixtures thereof, b) 20-75% by weight of one or more thermoplastic polyurethanes, c) 0.5-25% by weight of one or more isocyanates, d) 0.5-15% by weight of one or more compounds which act as lubricant and dispersant, the sum of the constituents a) to d) amounting to at least 90% by weight, based on a total weight of said processing aid.
摘要翻译：在热塑性聚氨酯的加工中使用加工助剂以产生包括自支撑膜的各种制品。加工助剂包含a）10-50重量％的选自氧化铝，二氧化硅及其混合物的疏水化，至少部分聚集的金属氧化物颗粒，b）20-75重量％的一种或多种热塑性聚氨酯，c）0.5-25重量％的一种或多种异氰酸酯，d）0.5-15重量％的一种或多种充当润滑剂和分散剂的化合物，组分a）至d）的总和相当于至少90重量％，基于所述加工助剂的总重量。

3. 发明申请

US20130020744A1 PROCESSING AID FOR THERMOPLASTIC POLYURETHANES 审中-公开
标题翻译：热塑性聚氨酯加工助剂
公开(公告)号：US20130020744A1
公开(公告)日：2013-01-24
申请号：US13577709
申请日：2011-03-21
申请人： Thomas Welker , Frank Menzel , Dieter Kuhn , Uwe Schachtely , Uwe Kinzlinger , Ulrich Boes , Didier Lagneaux , Henri Sautel
发明人： Thomas Welker , Frank Menzel , Dieter Kuhn , Uwe Schachtely , Uwe Kinzlinger , Ulrich Boes , Didier Lagneaux , Henri Sautel
IPC分类号： C08L75/04 , B29C49/04
CPC分类号： C08K3/22 , C08G18/0895 , C08G18/10 , C08J5/18 , C08J2375/04 , C08K9/06 , C08L75/04
摘要： Processing aid comprising a) 10-50% by weight of hydrophobized, at least partially aggregated, metal oxide particles b) 20-75% by weight of one or more thermoplastic polyurethanes, c) 0.5-50 by weight of one or more prepolymers comprising isocyanate groups the sum of the constituents a) to c) amounting to at least 80% by weight, based on the processing aid.
摘要翻译：加工助剂包括a）10-50重量％的疏水化，至少部分聚集的金属氧化物颗粒b）20-75重量％的一种或多种热塑性聚氨酯，c）0.5-50重量％的一种或多种预聚物，其包含基于加工助剂，异氰酸酯基团的组分a）至c）的总和至少为80重量％。

4. 发明授权

US08809424B2 Process for preparing compositions based on a starchy component and on a synthetic polymer 有权
标题翻译：用于制备基于淀粉组分和合成聚合物的组合物的方法
公开(公告)号：US08809424B2
公开(公告)日：2014-08-19
申请号：US13003802
申请日：2009-07-17
申请人： Thierry Feron , Rene Saint Loup , Jerome Gimenez , Didier Lagneaux , Henri Sautel
发明人： Thierry Feron , Rene Saint Loup , Jerome Gimenez , Didier Lagneaux , Henri Sautel
IPC分类号： C08L3/00 , C08L89/00 , D21H19/54
CPC分类号： C08J3/18 , C08J2303/02 , C08J2323/02 , C08L3/02 , C08L23/12 , C08L51/06 , C08L2205/03 , C08L2666/02
摘要： Process for preparing a composition based on a synthetic polymer includes: introducing, into a reactor containing a softened or molten synthetic polymer, a non-plasticized starchy component and a plasticizer of the latter; and kneading the mixture obtained under conditions sufficient to obtain the plasticization of the starchy component by the plasticizer, and a homogeneous mixture of the synthetic polymer and of the plasticized starchy component. The reactor may especially be a co-rotating or counter-rotating single-screw or twin-screw extruder, for example a co-rotating twin-screw extruder. The synthetic polymer may advantageously be chosen from the group including polyethylenes (PE) and polypropylenes (PP), which are functionalized or unfunctionalized, polyamides (PA), thermoplastic polyurethanes (TPU), styrene-ethylene-butylene-styrene (SEBS) copolymers, preferably that are functionalized, amorphous polyethylene terephthalates (PETG) and blends thereof. The resulting compositions have improved characteristics, especially in terms of coloration and of mechanical properties, for example in terms of elongation at break.
摘要翻译：制备基于合成聚合物的组合物的方法包括：向包含软化或熔融的合成聚合物的反应器中引入未增塑的淀粉组分和后者的增塑剂; 并在足以获得由增塑剂增塑淀粉组分的塑化条件下得到的混合物，以及合成聚合物和增塑淀粉组分的均匀混合物。反应器可以特别地是同向旋转或反向旋转的单螺杆或双螺杆挤出机，例如同向旋转双螺杆挤出机。合成聚合物可有利地选自聚乙烯（PE）和聚丙烯（PP），其为官能化或未官能化的聚酰胺（PA），热塑性聚氨酯（TPU），苯乙烯 - 乙烯 - 丁烯 - 苯乙烯（SEBS）共聚物，优选为官能化的无定形聚对苯二甲酸乙二醇酯（PETG）及其共混物。所得组合物具有改进的特性，特别是在着色和机械性能方面，例如在断裂伸长率方面。

5. 发明申请

US20110118390A1 PROCESS FOR PREPARING COMPOSITIONS BASED ON A STARCHY COMPONENT AND ON A SYNTHETIC POLYMER 有权
标题翻译：基于淀粉组分和合成聚合物制备组合物的方法
公开(公告)号：US20110118390A1
公开(公告)日：2011-05-19
申请号：US13003802
申请日：2009-07-17
申请人： Thierry Feron , Rene Saint Loup , Jerome Gimenez , Didier Lagneaux , Henri Sautel
发明人： Thierry Feron , Rene Saint Loup , Jerome Gimenez , Didier Lagneaux , Henri Sautel
IPC分类号： C08L3/04
CPC分类号： C08J3/18 , C08J2303/02 , C08J2323/02 , C08L3/02 , C08L23/12 , C08L51/06 , C08L2205/03 , C08L2666/02
摘要： Process for preparing a composition based on a synthetic polymer includes: introducing, into a reactor containing a softened or molten synthetic polymer, a non-plasticized starchy component and a plasticizer of the latter; and kneading the mixture obtained under conditions sufficient to obtain the plasticization of the starchy component by the plasticizer, and a homogeneous mixture of the synthetic polymer and of the plasticized starchy component. The reactor may especially be a co-rotating or counter-rotating single-screw or twin-screw extruder, for example a co-rotating twin-screw extruder. The synthetic polymer may advantageously be chosen from the group including polyethylenes (PE) and polypropylenes (PP), which are functionalized or unfunctionalized, polyamides (PA), thermoplastic polyurethanes (TPU), styrene-ethylene-butylene-styrene (SEBS) copolymers, preferably that are functionalized, amorphous polyethylene terephthalates (PETG) and blends thereof. The resulting compositions have improved characteristics, especially in terms of coloration and of mechanical properties, for example in terms of elongation at break.
摘要翻译：制备基于合成聚合物的组合物的方法包括：向包含软化或熔融的合成聚合物的反应器中引入未增塑的淀粉组分和后者的增塑剂; 并在足以获得由增塑剂增塑淀粉组分的塑化条件下得到的混合物，以及合成聚合物和增塑淀粉组分的均匀混合物。反应器可以特别地是同向旋转或反向旋转的单螺杆或双螺杆挤出机，例如同向旋转双螺杆挤出机。合成聚合物可有利地选自聚乙烯（PE）和聚丙烯（PP），其为官能化或未官能化的聚酰胺（PA），热塑性聚氨酯（TPU），苯乙烯 - 乙烯 - 丁烯 - 苯乙烯（SEBS）共聚物，优选为官能化的无定形聚对苯二甲酸乙二醇酯（PETG）及其共混物。所得组合物具有改进的特性，特别是在着色和机械性能方面，例如在断裂伸长率方面。

6. 发明申请

US20100311874A1 METHOD FOR PREPARING THERMOPLASTIC COMPOSITIONS BASED ON PLASTICIZED STARCH AND RESULTING COMPOSITIONS 审中-公开
标题翻译：基于增塑淀粉和成分组合物制备热塑性组合物的方法
公开(公告)号：US20100311874A1
公开(公告)日：2010-12-09
申请号：US12864511
申请日：2009-01-29
申请人： Leon Mentink , Didier Lagneaux , Jerome Gimenez
发明人： Leon Mentink , Didier Lagneaux , Jerome Gimenez
IPC分类号： C08L3/02 , C08L3/00
CPC分类号： C08G18/3218 , C08G18/3206 , C08G18/6484 , C08K5/0016 , C08K5/053 , C08K5/29 , C08L3/02 , C08L51/003 , C08L51/06 , C08L2666/24 , C08L2666/26
摘要： A starch-based composition includes: (a) at least 51% by weight of a plasticized amylaceous composition including starch and a plasticizer for the starch, obtained by thermomechanically mixing granular starch and a plasticizer for the starch, (b) at most 49% by weight of at least one non-amylaceous polymer, and (c) a bonding agent having a molecular mass of less than 5000, including at least two functions, at least one which is capable of reacting with the plasticizer and at least another of which is capable of reacting with the starch and/or the non-amylaceous polymer, these amounts being expressed with respect to solids and relative to the sum of (a) and (b), a method for preparing such a composition and a thermoplastic composition obtained by heating such a composition.
摘要翻译：淀粉类组合物包括：（a）通过热淀粉混合淀粉和淀粉增塑剂获得的至少51重量％的增塑淀粉组合物，包括淀粉和淀粉增塑剂，（b）至多49％的至少一种非淀粉性聚合物，和（c）分子量小于5000的粘合剂，包括至少两种官能团，至少一种能够与增塑剂和至少另一种功能物质反应的粘合剂能够与淀粉和/或非淀粉质聚合物反应，这些量相对于固体并相对于（a）和（b）的总和表示，制备这种组合物的方法和获得的热塑性组合物通过加热这种组合物。

7. 发明申请

US20080114093A1 Thermoplastic Polyurethanes Containing A Salt Of Zirconium Phosphate 失效
标题翻译：含有磷酸锆盐的热塑性聚氨酯
公开(公告)号：US20080114093A1
公开(公告)日：2008-05-15
申请号：US11869319
申请日：2007-10-09
申请人： Didier Lagneaux , Vicky M.J. Bertels , Robert Jansen
发明人： Didier Lagneaux , Vicky M.J. Bertels , Robert Jansen
IPC分类号： C08K3/32 , C08J3/22
CPC分类号： C08G18/7664 , C08K3/014 , C08K3/32 , C08L75/04 , C08L2666/20
摘要： Thermoplastic polyurethane (TPU) compositions are disclosed comprising TPU polymer, polyisocyanate, and a salt of zirconium phosphate. The compositions have enhanced thermal properties, good processability, and good hydrolysis resistance. Processes are also disclosed to combine the ingredients by melt mixing or to prepare the compositions in-situ as the TPU is being polymerized.
摘要翻译：公开了包含TPU聚合物，多异氰酸酯和磷酸锆盐的热塑性聚氨酯（TPU）组合物。该组合物具有增强的热性能，良好的加工性能和良好的耐水解性。还公开了通过熔融混合来组合这些成分的方法或者在TPU被聚合时原位制备组合物。

8. 发明授权

US08916628B2 Thermoplastic compositions based on soluble starch and method for preparing such compositions 有权
标题翻译：基于可溶性淀粉的热塑性组合物及其制备方法
公开(公告)号：US08916628B2
公开(公告)日：2014-12-23
申请号：US12864510
申请日：2009-01-29
申请人： Leon Mentink , Didier Lagneaux , Jerome Gimenez
发明人： Leon Mentink , Didier Lagneaux , Jerome Gimenez
IPC分类号： C08B37/00 , C08L3/02 , C08L5/16 , C08G18/76 , C08G18/08 , C08G18/64 , C08L75/04 , C08K5/29 , C08L3/04
CPC分类号： C08G18/7657 , C08G18/0895 , C08G18/6484 , C08K5/29 , C08L3/02 , C08L3/04 , C08L75/04 , C08L2666/20 , C08L2666/26
摘要： A novel starch-based composition includes: (a) at least 45% by weight of at least one soluble starch, (b) at most 55% by weight of at least one non-biodegradable, non-amylaceous polymer, and (c) a bonding agent carrying at least two functional groups capable of reacting with molecules carrying functions including an active hydrogen, these amounts being expressed with respect to solids and relative to the sum of (a) and (b). A method for preparing such a starch-based composition and a thermoplastic composition prepared by heating such a composition are also described.
摘要翻译：一种新型的基于淀粉的组合物包括：（a）至少45重量％的至少一种可溶性淀粉，（b）至多55重量％的至少一种不可生物降解的非淀粉质聚合物，和（c）携带至少两个能够与包含活性氢的功能分子反应的官能团的粘合剂，这些量相对于固体和相对于（a）和（b）的总和表示。还描述了制备这种基于淀粉的组合物的方法和通过加热这种组合物制备的热塑性组合物。

9. 发明申请

US20120289629A1 METHOD FOR PREPARING THERMOPLASTIC COMPOSITIONS OF PLASTICIZED STARCH, AND SUCH COMPOSITIONS 审中-公开
标题翻译：制备热塑性淀粉的热塑性组合物的方法及其组合物
公开(公告)号：US20120289629A1
公开(公告)日：2012-11-15
申请号：US13522123
申请日：2011-01-14
申请人： René Saint-Loup , Jérôme Gimenez , Didier Lagneaux
发明人： René Saint-Loup , Jérôme Gimenez , Didier Lagneaux
IPC分类号： C08L3/00
CPC分类号： C08L3/02 , C08G18/00 , C08G18/6484 , C08J3/005 , C08J3/18 , C08J2303/02 , C08J2323/02 , C08K5/0025 , C08L23/02 , C08L23/10 , C08L23/12 , C08L2666/06 , C08L2666/04 , C08L51/06
摘要： The present invention relates to a method for preparing novel thermoplastic amylaceous compositions, as well as to such thermoplastic amylaceous compositions.
摘要翻译：本发明涉及一种制备新型热塑性淀粉组合物的方法，以及这种热塑性淀粉组合物。

10. 发明申请

US20110086949A1 STARCH-CONTAINING THERMOPLASTIC OR ELASTOMER COMPOSITIONS, AND METHOD FOR PREPARING SUCH COMPOSITIONS 审中-公开
标题翻译：含淀粉酶的热塑性弹性体或弹性体组合物及其制备方法
公开(公告)号：US20110086949A1
公开(公告)日：2011-04-14
申请号：US12997842
申请日：2009-06-12
申请人： Léon Mentink , Jérôme Gimenez , Didier Lagneaux
发明人： Léon Mentink , Jérôme Gimenez , Didier Lagneaux
IPC分类号： C08L3/02 , C08L3/04 , C08L3/06 , C08L3/10 , B82Y30/00
CPC分类号： C08L3/00 , B82Y30/00 , C08J3/226 , C08J5/005 , C08J2303/02 , C08J2403/00 , C08L3/02 , C08L3/06 , C08L35/06 , C08L2666/02 , C08L2666/26 , C08L2666/04
摘要： A thermoplastic and/or elastomer composition includes: at least 50 wt % and 99.95 wt % at most of a starchy composition (a) including at least one starch; at least 0.05 wt % and 50 wt % at most of a nanometric product (b) including particles having at least one dimension of 0.1 to 500 nanometers and selected from mixed products containing at least one lamellar clay and at least one cationic oligomer or cationic synthetic polymer, organic, mineral or mixed nanotubes, organic, mineral or mixed nanocrystals and nanocrystallites, organic, mineral or mixed nanobeads and nanospheres customized into clusters or agglomerated, and mixtures of these nanometric products, the percentage being expressed in dry weight and added to the sum in dry weight of (a) and (b); and at least one non-starchy polymer (c).
摘要翻译：热塑性和/或弹性体组合物包括：至多包含至少一种淀粉的淀粉组合物（a）的至少50wt％和99.95wt％; 至少0.05重量％和最多50重量％的纳米产品（b），其包括具有至少一个维度为0.1至500纳米的颗粒，并且选自含有至少一个层状粘土和至少一种阳离子低聚物或阳离子合成物聚合物，有机，矿物或混合纳米管，有机，矿物或混合的纳米晶体和纳米晶体，定制成簇或聚集的有机，矿物或混合纳米珠和纳米球，以及这些纳米产品的混合物，其百分比以干重表示并添加到（a）和（b）的干重合计; 和至少一种非淀粉质聚合物（c）。

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