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1. 发明授权

US5470810A Catalyst and method of manufacture 失效
标题翻译：催化剂及其制造方法
公开(公告)号：US5470810A
公开(公告)日：1995-11-28
申请号：US190438
申请日：1994-02-02
申请人： Thomas F. Degnan , Anthony S. Fung , George H. Hatzikos , Gordon J. Kennedy , Jocelyn A. Kowalski
发明人： Thomas F. Degnan , Anthony S. Fung , George H. Hatzikos , Gordon J. Kennedy , Jocelyn A. Kowalski
IPC分类号： B01J29/82 , B01J29/70 , C10G11/05 , C10G35/095 , B01J29/06
CPC分类号： B01J29/7038 , C10G11/05 , B01J2229/26 , B01J2229/36 , B01J2229/42
摘要： This invention relates to the catalyst composition resulting from the addition of phosphorus, and optionally, a matrix material, to a porous crystalline material having the structure of MCM-22, along with the method for making the catalyst composition, and the method for using the catalyst composition in catalytic cracking. It is desirable to improve the hydrothermal stability of the catalysts which are based upon porous crystalline materials having the X-ray structure of MCM-22 to increase the activity that the catalyst maintains after repeated cycles of steaming such as is experienced in the FCC process. It has been found that phosphorus addition to a porous crystalline material having the structure of MCM-22 improves the hydrothermal stability of the resulting catalyst. This improved catalyst is useful in organic conversion processes, e.g., catalytic cracking processes.
摘要翻译：本发明涉及通过向具有MCM-22结构的多孔结晶材料以及制备催化剂组合物的方法中添加磷和任选的基质材料而得到的催化剂组合物，以及使用该方法催化剂组成催化裂化。希望提高基于具有MCM-22的X射线结构的多孔结晶材料的催化剂的水热稳定性，以增加如在FCC方法中经历的重复蒸汽循环之后催化剂维持的活性。已经发现，具有MCM-22结构的多孔结晶材料中的磷添加改善了所得催化剂的水热稳定性。这种改进的催化剂可用于有机转化方法，例如催化裂化方法。

2. 发明授权

US5658454A Hydrocarbon coversion using improved zeolite Beta catalyst 失效
标题翻译：使用改进的沸石β催化剂进行烃转化
公开(公告)号：US5658454A
公开(公告)日：1997-08-19
申请号：US461484
申请日：1995-06-05
申请人： Robert P. L. Absil , Thomas F. Degnan , George H. Hatzikos , Jocelyn A. Kowalski , Thomas Mebrahtu , Grant H. Yokomizo
发明人： Robert P. L. Absil , Thomas F. Degnan , George H. Hatzikos , Jocelyn A. Kowalski , Thomas Mebrahtu , Grant H. Yokomizo
IPC分类号： B01J29/40 , B01J29/70 , B01J37/00 , C10G11/05 , C07C4/06 , C10G47/04
CPC分类号： C10G11/05 , B01J29/7007 , B01J37/0009 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/40 , B01J29/7034 , B01J29/7042
摘要： A catalyst composition which comprises a crystalline metallosilicate having the structure of zeolite Beta, phosphor and a matrix that is substantially free of crystalline aluminum phosphate which has improved resistance to steam deactivation which has higher cracking activity than analogous catalysts prepared without phosphorus. The crystalline metallosilicate be used in the as-synthesized form or in the calcined form. included is the method to produce the catalyst composition and methods for the use of catalysts prepared by the present method in organic conversion processes. Specific embodiments of the invention involve various techniques for preparation of catalyst containing phosphorus and crystalline metallosilicates having the structure of zeolite Beta. Catalysts prepared according to the method of this invention are useful for organic compound, e.g., hydrocarbon compound, conversion processes. Organic compound conversion processes include cracking, hydrocracking, and transalkylation, among others.
摘要翻译：一种催化剂组合物，其包含具有沸石β，磷光体和基本上不含结晶磷酸铝的结构的结晶金属硅酸盐，其具有改善的对蒸汽失活的抗性，其具有比不用磷制备的类似催化剂更高的裂化活性。结晶金属硅酸盐以合成形式或煅烧形式使用。包括制备催化剂组合物的方法和通过本发明方法在有机转化方法中制备的催化剂的使用方法。本发明的具体实施方案涉及用于制备含有β沸石结构的磷的磷和结晶金属硅酸盐的各种技术。根据本发明方法制备的催化剂可用于有机化合物，例如烃化合物，转化方法。有机化合物转化方法包括裂化，加氢裂化和烷基转移等。

3. 发明授权

US5457078A Manufacture of improved zeolite Beta catalyst 失效
标题翻译：改良沸石β催化剂的制造
公开(公告)号：US5457078A
公开(公告)日：1995-10-10
申请号：US158325
申请日：1993-11-29
申请人： Robert P. L. Absil , Thomas F. Degnan , George H. Hatzikos , Jocelyn A. Kowalski , Thomas Mebrahtu , Grant H. Yokomizo
发明人： Robert P. L. Absil , Thomas F. Degnan , George H. Hatzikos , Jocelyn A. Kowalski , Thomas Mebrahtu , Grant H. Yokomizo
IPC分类号： B01J29/40 , B01J29/70 , B01J37/00 , C10G11/05 , B01J29/06 , B01J27/14
CPC分类号： C10G11/05 , B01J29/7007 , B01J37/0009 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/40 , B01J29/7034 , B01J29/7042
摘要： A catalyst composition which comprises a crystalline metallosilicate having the structure of zeolite Beta, phosphorus, and a matrix that is substantially free of crystalline aluminum phosphate which has improved resistance to steam deactivation and which has higher cracking activity than analogous catalysts prepared without phosphorus. The crystalline metallosilicate may be used in the as-synthesized form or in the calcined form. Also included is the method to produce the catalyst composition and methods for the use of catalysts prepared by the present method in organic conversion processes. Specific embodiments of the invention involve various techniques for preparation of catalysts containing phosphorus and crystalline metallosilicates having the structure of zeolite Beta. Catalysts prepared according to the method of this invention are useful for organic compound, e.g., hydrocarbon compound, conversion processes. Organic compound conversion processes include cracking, hydrocracking, and transalkylation, among others.
摘要翻译：一种催化剂组合物，其包含具有沸石β，磷的结构的结晶金属硅酸盐和基本上不含结晶磷酸铝的基质，其具有改善的对蒸汽失活的抗性，并且具有比不含磷制备的类似催化剂更高的裂化活性。结晶金属硅酸盐可以以合成形式或以煅烧形式使用。还包括制备催化剂组合物的方法和使用通过本发明方法制备的催化剂在有机转化方法中的方法。本发明的具体实施方案涉及用于制备含有β沸石结构的含有磷的结晶金属硅酸盐的催化剂的各种技术。根据本发明方法制备的催化剂可用于有机化合物，例如烃化合物，转化方法。有机化合物转化方法包括裂化，加氢裂化和烷基转移等。

4. 发明授权

US5185310A Activating silicoaluminophosphate compositions 失效
标题翻译：活化硅铝磷酸盐组合物
公开(公告)号：US5185310A
公开(公告)日：1993-02-09
申请号：US829149
申请日：1992-01-31
申请人： Thomas F. Degnan , Sharon B. McCullen , Kirk D. Schmitt , George H. Hatzikos
发明人： Thomas F. Degnan , Sharon B. McCullen , Kirk D. Schmitt , George H. Hatzikos
IPC分类号： B01J29/85
CPC分类号： B01J29/85 , B01J2229/42
摘要： A method of activating silicoaluminophosphate (SAPO) compositions by contacting as-synthesized SAPO with hydrated alumina and water, followed by heating to at least 425.degree. C., preferably in nitrogen and then air.
摘要翻译：通过将合成的SAPO与水合氧化铝和水接触，然后加热至至少425℃，优选在氮气中然后空气来活化硅铝磷酸盐（SAPO）组合物的方法。

5. 发明授权

US5573657A Hydrogenation process 失效
标题翻译：氢化过程
公开(公告)号：US5573657A
公开(公告)日：1996-11-12
申请号：US309288
申请日：1994-09-20
申请人： Thomas F. Degnan , Richard C. Dougherty , George H. Hatzikos , Stuart S. Shih , Tsoung Y. Yan
发明人： Thomas F. Degnan , Richard C. Dougherty , George H. Hatzikos , Stuart S. Shih , Tsoung Y. Yan
IPC分类号： B01J29/04 , C10G45/00 , C10G45/54
CPC分类号： B01J29/043 , B01J29/0325 , C10G45/00 , B01J2229/42 , C10G2400/10
摘要： A hydrogenation process for reducing the unsaturation of lubricants uses a catalyst which is based on an ultra-large pore crystalline material. The crystalline material has pores of at least 13 .ANG. diameter arranged in a uniform manner and exhibits unusually large sorption capacity demonstrated by its benzene adsorption capacity of greater than about 15 grams benzene/100 grams (50 torr and 25.degree. C.). A preferred form of the catalyst has a hexagonal structure which exhibits a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 .ANG.. The hydrogenation catalysts based on these materials are capable of reducing the unsaturation in poly alpha olefin lubricants to a low level.
摘要翻译：用于降低润滑剂的不饱和度的氢化方法使用基于超大孔结晶材料的催化剂。结晶材料具有均匀排列的至少13安培直径的孔，并且通过苯吸附能力大于约15克苯/ 100克（50托和25℃）表现出非常大的吸附能力。催化剂的优选形式具有六角形结构，其显示六方电子衍射图，其可以以大于约18安培的d100值进行索引。基于这些材料的氢化催化剂能够将聚α-烯烃润滑剂的不饱和度降低至低水平。

6. 发明授权

US5393717A Regeneration of noble metal containing zeolite catalysts via partial removal of carbonaceous deposits 失效
标题翻译：通过部分去除碳质沉积物再生含贵金属的沸石催化剂
公开(公告)号：US5393717A
公开(公告)日：1995-02-28
申请号：US63203
申请日：1993-05-18
申请人： Minas R. Apelian , Anthony S. Fung , George H. Hatzikos , Clinton R. Kennedy , Chung-Hur Lee , Thomas R. Kiliany , Poh K. Ng , David A. Pappal
发明人： Minas R. Apelian , Anthony S. Fung , George H. Hatzikos , Clinton R. Kennedy , Chung-Hur Lee , Thomas R. Kiliany , Poh K. Ng , David A. Pappal
IPC分类号： B01J29/90 , B01J38/14 , C10G35/095 , C10G45/64 , B01J29/38 , C10G47/18 , C10G35/95
CPC分类号： B01J38/14 , B01J29/90 , C10G35/095 , C10G45/64
摘要： There is provided a process for regenerating a coked catalyst comprising a zeolite and a noble metal such as platinum. The process involves treating the coked catalyst under somewhat mild oxidation conditions, whereby a sufficient portion of the coke is removed from the catalyst to restore the hydrocarbon sorption properties of the zeolite component to the level observed in the non-coked form. Surprisingly, the original activity of the catalyst is substantially restored, even though a substantial amount of coke remains on the regenerated catalyst.
摘要翻译：提供了一种再生包含沸石和贵金属如铂的焦化催化剂的方法。该方法包括在稍微温和的氧化条件下处理焦化催化剂，由此从催化剂中除去足够的焦炭部分以将沸石组分的烃吸附性能恢复到以非焦化形式观察到的水平。令人惊奇的是，即使在再生催化剂上残留有大量的焦炭，催化剂的原始活性也被大大恢复。

7. 发明授权

US5833840A Hydrocarbon conversion process using zeolite Beta catalyst 失效
标题翻译：使用沸石β催化剂的烃转化方法
公开(公告)号：US5833840A
公开(公告)日：1998-11-10
申请号：US463149
申请日：1995-06-05
申请人： Robert P. L. Absil , George H. Hatzikos
发明人： Robert P. L. Absil , George H. Hatzikos
IPC分类号： B01J29/40 , B01J29/70 , B01J37/00 , C10G11/05 , C10G11/02
CPC分类号： C10G11/05 , B01J29/7007 , B01J37/0009 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/40 , B01J29/7034 , B01J29/7042
摘要： A catalyst composition which comprises a crystalline metallosilicate having the structure of zeolite Beta, phosphorus and a matrix that is substantially free of crystalline aluminum phosphate which has improved resistance to steam deactivation at which has higher cracking activity than analogous catalysts prepared without phosphorus. The crystalline metallosilicate may be used in the as-synthesized form or in the calcined form. Also included is the method to produce the catalyst composition and methods for the use of catalysts prepared by the present method in organic conversion processes. Specific embodiments of the invention involve various techniques for preparation of catalyst containing phosphorus and crystalline metallosilicates having the structure of zeolite Beta. Catalysts prepared according to the method of this invention are useful for organic compound, e.g., hydrocarbon compound, conversion processes. Organic compound conversion processes include cracking, hydrocracking, and transalkylation, among others.
摘要翻译：一种催化剂组合物，其包含结晶金属硅酸盐，其具有β沸石结构，磷和基本上不含结晶磷酸铝的基质，其具有改善的对蒸汽失活的抗性，其具有比不用磷制备的类似催化剂更高的裂化活性。结晶金属硅酸盐可以以合成形式或以煅烧形式使用。还包括制备催化剂组合物的方法和使用通过本发明方法制备的催化剂在有机转化方法中的方法。本发明的具体实施方案涉及用于制备含有β沸石结构的磷的磷和结晶金属硅酸盐的各种技术。根据本发明方法制备的催化剂可用于有机化合物，例如烃化合物，转化方法。有机化合物转化方法包括裂化，加氢裂化和烷基转移等。

8. 发明授权

US5710085A Manufacture of improved zeolite beta catalyst 失效
标题翻译：改进沸石β催化剂的制造
公开(公告)号：US5710085A
公开(公告)日：1998-01-20
申请号：US463143
申请日：1995-06-05
申请人： Robert P. L. Absil , George H. Hatzikos
发明人： Robert P. L. Absil , George H. Hatzikos
IPC分类号： B01J29/40 , B01J29/70 , B01J37/00 , C10G11/05 , B01J29/06
CPC分类号： C10G11/05 , B01J29/7007 , B01J37/0009 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/40 , B01J29/7034 , B01J29/7042
摘要： A catalyst composition which comprises a crystalline metallosilicate having the structure of zeolite Beta, phosphorus and a matrix that is substantially free of crystalline aluminum phosphate which has improved resistance to steam deactivation and which has higher cracking activity than analogous catalysts prepared without phosphorus. The crystalline metallosilicate may be used in the as-synthesized form or in the calcined form. Also included is the method to produce the catalyst composition and methods for the use of catalysts prepared by the present method in organic conversion processes. Specific embodiments of the invention involve various techniques for preparation of catalysts containing phosphorus and crystalline metallosilicates having the structure of zeolite Beta. Catalysts prepared according to the method of this invention are useful for organic compound, e.g., hydrocarbon compound, conversion processes. Organic compound conversion processes include cracking, hydrocracking, and transalkylation, among others.
摘要翻译：一种催化剂组合物，其包含结晶金属硅酸盐，其具有β沸石结构，磷和基本上不含结晶磷酸铝的基质，其具有改善的对蒸汽失活的抗性，并且具有比不用磷制备的类似催化剂更高的裂化活性。结晶金属硅酸盐可以以合成形式或以煅烧形式使用。还包括制备催化剂组合物的方法和使用通过本发明方法制备的催化剂在有机转化方法中的方法。本发明的具体实施方案涉及用于制备含有β沸石结构的含有磷的结晶金属硅酸盐的催化剂的各种技术。根据本发明方法制备的催化剂可用于有机化合物，例如烃化合物，转化方法。有机化合物转化方法包括裂化，加氢裂化和烷基转移等。

9. 发明授权

US5256277A Paraffin isomerization process utilizing a catalyst comprising a mesoporous crystalline material 失效
标题翻译：使用包含介孔结晶材料的催化剂的石蜡异构化方法
公开(公告)号：US5256277A
公开(公告)日：1993-10-26
申请号：US734991
申请日：1991-07-24
申请人： Kenneth J. Del Rossi , George H. Hatzikos , Albin Huss, Jr.
发明人： Kenneth J. Del Rossi , George H. Hatzikos , Albin Huss, Jr.
IPC分类号： B01J29/04 , C10G35/06 , C10G45/64 , C10G35/085 , C10G35/095
CPC分类号： C10G45/64 , B01J29/042 , B01J29/043 , C10G35/065 , B01J2229/42 , B01J29/045
摘要： Paraffins, especially paraffins in the C.sub.4 -C.sub.8 range, are isomerized to iso-paraffins over an isomerization catalyst comprising a noble metal such as platinum on a support material comprising an inorganic, non-layered, porous, crystalline phase aluminosilicate material with pores of at least 13 .ANG. and which exhibits, after calcination, an X-ray diffraction pattern with at least one peak at a d-spacing greater than 18 .ANG.. These materials have a high surface area and sorption capacity marked by a benzene adsorption capacity of greater than about 15 grams benzene per 100 grams at 50 torr and 25.degree. C. In its preferred form, the support material has a uniform, hexagonal arrangement of pores with diameters of at least about 13 .ANG. and a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 .ANG. which corresponds to at least one peak in the X-ray diffraction pattern.
摘要翻译：链烷烃，特别是C4-C8范围内的链烷烃，在包含贵金属如铂的异构化催化剂上异构化成异链烷烃，载体材料包含无机，非层状，多孔，结晶相的硅铝酸盐材料，孔隙为至少13个ANGSTROM，并且其在煅烧后显示具有大于18安培的d间距的至少一个峰的X射线衍射图。这些材料具有高的表面积和吸附能力，其标记为在50托和25℃下每100克苯吸附能力大于约15克苯。在其优选形式中，载体材料具有均匀的六边形排列的孔其直径至少约为13安格姆和六角形电子衍射图案，其可以用对应于X射线衍射图中的至少一个峰的d100值大于约18的折射率进行索引。

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