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    • 3. 发明授权
    • Silicone rubber composition and silicone rubber-processed fabric
    • 硅橡胶组合物和硅橡胶加工织物
    • US5296298A
    • 1994-03-22
    • US978338
    • 1992-11-18
    • Tetsuo FujimotoYasuji Matsumoto
    • Tetsuo FujimotoYasuji Matsumoto
    • C08L83/05C08K5/09C08K5/5419C08K5/5425C08K5/5435C08L83/04C08L83/07D06M13/02D06M13/50D06M13/503D06M13/51D06M13/513D06M15/643D06M15/693D06M101/00D06M101/08D06M101/16D06M101/30D06M101/32D06M101/34D06N3/12B32B25/02
    • D06N3/128C08K5/5435C08L83/04D06M13/513D06M15/643D06M15/693C08G77/12C08G77/20Y10T428/31663Y10T428/31725Y10T428/31786
    • A silicone rubber composition comprising(A) 100 parts by weight of a polyorganosiloxane having, per molecule, at least two structural units represented by the following formula:(R.sup.1).sub.a (R.sup.2).sub.b SiO.sub.(4-(a+b))/2 (I)(B) a polyorganohydrogensiloxane comprising structural units shown by the following formula:(R.sup.3).sub.c H.sub.d SiO(4-(c+d))/2 (II)and having at least three silicon-bonded hydrogen atoms per molecule, the amount of component (B) being such that the number of silicon-bonded hydrogen atoms in component (B) is from 0.5 to 4.0 per R.sup.1 group in the structural units shown by formula (I) of component (A),(C) from 0.1 to 10 parts by weight of a compound selected from the group consisting of an organosilicon compound having, per molecule, at least one silicon-bonded hydrogen atoms and at least one group represented by the following formula: ##STR1## and an acrylic- or methacrylic-functional silane coupling agent, (D) from 0.1 to 10 parts by weight of an epoxyalkylalkoxysilane represented by the following formula:X-Q.sup.3 -Si(R.sup.6).sub.f (OR.sup.7).sub.3-f (IV)(E) from 0 to 5 parts by weight of an aluminum chelate compound, and(F) platinum and/or a platinum compound in an amount of from 1 to 100 ppm of the polyorganosiloxane, component (A), in terms of the amount of platinum atoms.All groups and subscripts are identified in the specification.
    • 一种硅橡胶组合物,其包含(A)100重量份的聚有机硅氧烷,每分子具有由下式表示的至少两个结构单元:(R1)a(R2)bSiO(4-(a + b))/ 2 (I)(B)包含由下式表示的结构单元的聚有机氢硅氧烷:(R3)cHdSiO(4-(c + d))/ 2(II),每分子具有至少三个与硅键合的氢原子, (B)的组分(B)中与硅键合的氢原子的数量在组分(A),(C)的式(I)所示的结构单元中的每个R 1基团为0.5-4.0,为0.1 至10重量份选自具有每分子至少一个与硅键合的氢原子的至少一个基团的有机硅化合物和由下式表示的至少一个基团的化合物:(*化学结构*)(III) 和丙烯酸或甲基丙烯酸官能的硅烷偶联剂,(D)0.1-10重量份的环氧烷基烷氧基硅烷代表 由下式表示:0至5重量份的铝螯合化合物的X-Q3-Si(R6)f(OR7)3-f(IV)(E),和(F)铂和/或铂 化合物的量为1〜100ppm的聚有机硅氧烷(A)成分,以铂原子计。 所有组和下标均在规范中标识。
    • 8. 发明授权
    • Curable polyorganosiloxane compositions
    • 可固化的聚有机硅氧烷组合物
    • US4788240A
    • 1988-11-29
    • US868216
    • 1986-05-28
    • Tetsuo Fujimoto
    • Tetsuo Fujimoto
    • C08K5/00C08L83/04
    • C08K5/0041
    • Polyorganosiloxane compositions comprising:(A) a polyorganosiloxane having two or more of the following unit, in the molecule, represented by the formula: ##EQU1## wherein, R.sup.1 represents an alkenyl radical; R.sup.2 represents a substituted or unsubstituted monovalent hydrocarbon radical having no unsaturated aliphatic bond; a is an integer of 1 of 2; b is an integer of 0 to 2; and a+b is an integer of 1 to 3;(B) a polyorganohydrogensiloxane, having units represented by the formula: ##EQU2## wherein, R.sup.3 represents a substituted or unsubstituted monovalent hydrocarbon radical; c is an integer of 0 to 2; d is an integer of 1 or 2; and c+d is an integer of 1 to 3,and having at least three hydrogen atoms bonded to silicon atoms in a molecule, in an amount such that the number of the hydrogen atoms bonded to silicon atoms may be 0.5 to 4.0 per R.sup.1 radical contained in polyorganosiloxane (A);(C) a catalyst selected from the group consisting of platinum and platinum compounds, in an amount of 1 to 100 ppm in terms of platinum atom relative to polyorganosiloxane (A); and(D) anthraquinone dyes and/or azo dyes, wherein the amount is from 1 to 2,000 ppm relative to polyorganosiloxane (A).
    • 聚有机硅氧烷组合物,其包含:(A)分子中具有两个或更多个以下单元的聚有机硅氧烷,由下式表示:其中,R 1表示烯基; R2表示不具有不饱和脂肪键的取代或未取代的一价烃基; a是2的整数; b为0〜2的整数; a + b为1〜3的整数。 (B)具有由下式表示的单元的聚有机氢硅氧烷:其中,R3表示取代或未取代的单价烃基; c为0〜2的整数, d为1或2的整数; 并且c + d为1〜3的整数,并且在分子中具有与硅原子键合的至少3个氢原子,其量使得与硅原子键合的氢原子数可以为每个R 1基团0.5〜4.0 包含在聚有机硅氧烷(A)中; (C)选自铂和铂化合物的催化剂,相对于聚有机硅氧烷(A),其铂原子数为1〜100ppm。 和(D)蒽醌染料和/或偶氮染料,其中相对于聚有机硅氧烷(A)的量为1至2,000ppm。