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1. 发明授权

US08297975B2 Reaction-curable adhesive composition and dental adhesive kit 有权
标题翻译：可反应固化的粘合剂组合物和牙科粘合剂试剂盒
公开(公告)号：US08297975B2
公开(公告)日：2012-10-30
申请号：US12599821
申请日：2008-05-14
申请人： Takashi Yamamoto , Toshiki Ono , Masami Arata , Tatsuya Ori
发明人： Takashi Yamamoto , Toshiki Ono , Masami Arata , Tatsuya Ori
IPC分类号： A61K6/00 , A61K6/083
CPC分类号： A61K6/09 , A61K6/0017 , A61K6/0023 , A61K6/0038 , A61K6/083 , C08K5/175 , C08K5/18 , C09J11/06 , C08L33/00 , C08L75/16 , C08L31/04 , C08L25/04
摘要： A reaction-curable adhesive composition exhibiting acidity is formed form a weakly acidic to alkaline composition (I) comprising (a) a polymerizable monomer and (b) a compound represented by the following formula (I) and a strongly acidic composition (II) comprising (a) a polymerizable monomer. R1—C6H4—NR2CH2COOR3 (1) wherein R1 and R2 are each independently a hydrogen atom or an alkyl group which may have a functional group, and R3 is a hydrogen atom or a metal atom. The composition containing the polymerizable monomer can be stably stored for a long period of time.
摘要翻译：表现出酸性的反应性固化型粘合剂组合物由弱酸性至碱性组合物（I）形成，其包含（a）可聚合单体和（b）由下式（1）表示的化合物和强酸性组合物（II），包含（a）可聚合单体。 R1-C6H4-NR2CH2COOR3（1）其中R1和R2各自独立地为氢原子或可具有官能团的烷基，R3为氢原子或金属原子。含有可聚合单体的组合物可以长期稳定地储存。

2. 发明申请

US20100292359A1 Reaction-Curable Adhesive Composition and Dental Adhesive Kit 有权
标题翻译：反应可固化粘合剂组合物和牙科粘合剂套件
公开(公告)号：US20100292359A1
公开(公告)日：2010-11-18
申请号：US12599821
申请日：2008-05-14
申请人： Takashi Yamamoto , Toshiki Ono , Masami Arata , Tatsuya Ori
发明人： Takashi Yamamoto , Toshiki Ono , Masami Arata , Tatsuya Ori
IPC分类号： C08F2/46 , A61K6/08
CPC分类号： A61K6/09 , A61K6/0017 , A61K6/0023 , A61K6/0038 , A61K6/083 , C08K5/175 , C08K5/18 , C09J11/06 , C08L33/00 , C08L75/16 , C08L31/04 , C08L25/04
摘要： A reaction-curable adhesive composition exhibiting acidity is formed form a weakly acidic to alkaline composition (I) comprising (a) a polymerizable monomer and (b) a compound represented by the following formula (1) and a strongly acidic composition (II) comprising (a) a polymerizable monomer. R1—C6H4—NR2CH2COOR3 (1) wherein R1 and R2 are each independently a hydrogen atom or an alkyl group which may have a functional group, and R3 is a hydrogen atom or a metal atom. The composition containing the polymerizable monomer can be stably stored for a long period of time.
摘要翻译：表现出酸性的反应性固化型粘合剂组合物由弱酸性至碱性组合物（I）形成，其包含（a）可聚合单体和（b）由下式（1）表示的化合物和强酸性组合物（II），包含（a）可聚合单体。 R1-C6H4-NR2CH2COOR3（1）其中R1和R2各自独立地为氢原子或可具有官能团的烷基，R3为氢原子或金属原子。含有可聚合单体的组合物可以长期稳定地储存。

3. 发明申请

US20110070563A1 EASILY REMOVABLE DENTAL CURABLE COMPOSITION 有权
标题翻译：易消除牙齿可固化组合物
公开(公告)号：US20110070563A1
公开(公告)日：2011-03-24
申请号：US12989357
申请日：2009-04-24
申请人： Tatsuya Ori , Akari Yamamoto , Masami Arata , Maho Yoshikawa
发明人： Tatsuya Ori , Akari Yamamoto , Masami Arata , Maho Yoshikawa
IPC分类号： A61C5/02
CPC分类号： A61K6/0038 , C08L43/02 , C08L81/06 , C08L23/00
摘要： An easily removable dental curable composition which prevents the fall or leakage of a temporary prosthetic appliance or a root canal filling material which is easily removed by bonding and adhering it to tooth, shows such high flowability that its operation is easy, has a long working time and excellent X-ray contrast properties and sealability and can be easily removed as required, and a filling kit.The dental curable compositon comprises (A) a polymerizable monomer mixture containing a polymerizable monomer having an acid group in the molecule and (B) a polymerization initiator, wherein the component (A) contains (A′) a long-chain polymerizable monomer having a structure with a chain length of 17 or more atoms and/or the composition further comprises (D1) a soft resin material; and when the amount of the component (A′) based on 100 parts by weight of the component (A) is represented by [a′] and the amounts of the components (A), (B) and (D1) based on 100 parts by weight of the total of the components (A) and (B) are represented by (a), (b) and (d1), respectively, the following expressions (1) to (5) are satisfied: 70≦(a)≦99.99 (1) 0.01≦(b)≦30 (2) 1≦[a′]/5+(d1)/1 (3) [a′]≦95 (4) (d1)≦250 (5).
摘要翻译：一种易于移除的牙科用固化性组合物，其防止通过粘结并粘附于牙齿而容易除去的临时假体器具或根管填充材料的下降或泄漏，显示出这样高的流动性，使其操作容易，具有长的加工时间和优异的X射线对比度特性和密封性，并且可以根据需要容易地去除，以及填充试剂盒。牙科用固化性组合物包含（A）含有分子中具有酸基的聚合性单体的聚合性单体混合物和（B）聚合引发剂，其中，成分（A）含有（A'）长链聚合性单体，具有17个或更多个链长的结构和/或组合物还包含（D1）软树脂材料; 并且当基于100重量份组分（A）的组分（A'）的量由[a']表示时，组分（A），（B）和（D1）的量基于100 组分（A）和（B）的总重量分别由（a），（b）和（d1）表示，满足下列表达式（1）至（5）：70＆nlE;（a ）和nlE;（b）＆nlE; 30（2）1＆nlE; [a'] / 5+（d1）/ 1（3）[a']＆nlE; 95（4）（d1） ; 250（5）。

4. 发明授权

US08426488B2 Easily removable dental curable composition 有权
标题翻译：易于移除的牙科治疗组合物
公开(公告)号：US08426488B2
公开(公告)日：2013-04-23
申请号：US12989357
申请日：2009-04-24
申请人： Tatsuya Ori , Akari Yamamoto , Masami Arata , Maho Yoshikawa
发明人： Tatsuya Ori , Akari Yamamoto , Masami Arata , Maho Yoshikawa
IPC分类号： A61K6/083
CPC分类号： A61K6/0038 , C08L43/02 , C08L81/06 , C08L23/00
摘要： An easily removable dental curable composition which prevents the fall or leakage of a temporary prosthetic appliance or a root canal filling material which is easily removed by bonding and adhering it to tooth, shows such high flowability that its operation is easy, has a long working time and excellent X-ray contrast properties and sealability and can be easily removed as required, and a filling kit. The dental curable composition comprises (A) a polymerizable monomer mixture containing a polymerizable monomer having an acid group in the molecule and (B) a polymerization initiator, wherein the component (A) contains (A′) a long-chain polymerizable monomer having a structure with a chain length of 17 or more atoms and/or the composition further comprises (D1) a soft resin material.
摘要翻译：一种易于移除的牙科用固化性组合物，其防止通过粘结并粘附于牙齿而容易除去的临时假体器具或根管填充材料的下降或泄漏，显示出这样高的流动性，使其操作容易，具有长的加工时间和优异的X射线对比度特性和密封性，并且可以根据需要容易地去除，以及填充试剂盒。牙科用固化性组合物包含（A）含有分子内具有酸基的聚合性单体的聚合性单体混合物和（B）聚合引发剂，其中，成分（A）含有（A'）长链可聚合单体，具有17个或更多个链长的结构和/或组合物还包含（D1）软树脂材料。

5. 发明申请

US20090258966A1 Dental Composition 审中-公开
标题翻译：牙科组成
公开(公告)号：US20090258966A1
公开(公告)日：2009-10-15
申请号：US12089334
申请日：2006-10-04
申请人： Satoshi Hirayama , Takuji Ikemi , Yasufumi Tsuchiya , Tatsuya Ori , Takashi Yamamoto
发明人： Satoshi Hirayama , Takuji Ikemi , Yasufumi Tsuchiya , Tatsuya Ori , Takashi Yamamoto
IPC分类号： A61K6/00 , C08K3/32
CPC分类号： A61K6/0023 , A61K6/033 , C08L33/00
摘要： An object of the present invention is to provide a dental composition having excellent adhesive effect and simultaneously not causing microleakage.A dental composition of a first embodiment of the present invention includes (A) an acidic-group containing polymerizable monomer, (B) a polymerizable monomer, (C) a filler comprising poly(meth)acrylate particles, (D) a calcium-containing material including tetracalcium phosphate (TTCP) and dicalcium phosphate (DCP), and (E) a polymerization initiator. The component (A) is contained at 16-70 parts by weight based on a total of 100 parts by weight of (A)+(B). The component (B) is contained at 84-30 parts by weight based on a total of 100 parts by weight of (A)+(B). The component (C) is contained at 0.2-297 parts by weight relative to a total of 100 parts by weight of (A)+(B). The component (D) is contained at 0.2-297 parts by weight relative to a total of 100 parts by weight of (A)+(B).
摘要翻译：本发明的目的是提供具有优异粘合效果并同时不引起微渗漏的牙科用组合物。本发明的第一实施方式的牙科用组合物包含（A）含酸性基的可聚合单体，（B）可聚合单体，（C）包含聚（甲基）丙烯酸酯颗粒的填料，（D）含钙包括磷酸四钙（TTCP）和磷酸二钙（DCP）的材料和（E）聚合引发剂。基于（A）+（B）的总计100重量份，组分（A）含量为16-70重量份。基于总计100重量份的（A）+（B），组分（B）含有84-30重量份。相对于总计100重量份的（A）+（B），组分（C）的含量为0.2-297重量份。组分（D）相对于总计100重量份的（A）+（B）为0.2-297重量份。

6. 发明授权

US08362105B2 Dental curable composition and kit for such dental curable composition 有权
标题翻译：用于这种牙科固化组合物的牙科固化组合物和试剂盒
公开(公告)号：US08362105B2
公开(公告)日：2013-01-29
申请号：US12063200
申请日：2006-08-08
申请人： Tatsuya Ori , Haruka Nishitani , Yuya Yamamoto , Takashi Yamamoto
发明人： Tatsuya Ori , Haruka Nishitani , Yuya Yamamoto , Takashi Yamamoto
IPC分类号： A61K6/08 , A61F2/00
CPC分类号： A61K6/0038 , C08L33/00
摘要： A dental curable composition has a curing time of 30 seconds to 120 minutes and includes a compound having an acidic group in the molecule (A), a polymerizable monomer (B), an organic amine compound (C) and a sulfur-containing reducing compound (D). In the dental curable composition, the content of the component (A) is 0.01 to 80 parts by weight, the content of the component (B) is 21 to 99.8 parts by weight, the content of the component (C) is 0.01 to 30 parts by weight and the content of the component (D) is 0 to 30 parts by weight. The composition may be cured at a relatively low temperature close to the body temperature without using a peroxide-based polymerization initiator, and has good sealing properties and adhesion.
摘要翻译：牙科用固化性组合物的固化时间为30秒〜120分钟，包括分子（A）中具有酸性基团的化合物，可聚合单体（B），有机胺化合物（C）和含硫还原化合物（D）。在牙科用固化性组合物中，成分（A）的含量为0.01〜80重量份，（B）成分为21〜99.8重量份，成分（C）的含量为0.01〜30 重量份，成分（D）的含量为0〜30重量份。组合物可以在接近体温的较低温度下固化，而不使用过氧化物基聚合引发剂，并且具有良好的密封性和粘附性。

7. 发明申请

US20090137697A1 Dental Curable Composition and Kit for Such Dental Curable Composition 有权
标题翻译：牙科可固化组合物和用于这种牙科可固化组合物的试剂盒
公开(公告)号：US20090137697A1
公开(公告)日：2009-05-28
申请号：US12063200
申请日：2006-08-08
申请人： Tatsuya Ori , Haruka Nishitani , Yuya Yamamoto , Takashi Yamamoto
发明人： Tatsuya Ori , Haruka Nishitani , Yuya Yamamoto , Takashi Yamamoto
IPC分类号： A61K6/00
CPC分类号： A61K6/0038 , C08L33/00
摘要： A dental curable composition has a curing time of 30 seconds to 120 minutes and includes a compound having an acidic group in the molecule (A), a polymerizable monomer (B), an organic amine compound (C) and a sulfur-containing reducing compound (D). In the dental curable composition, the content of the component (A) is 0.01 to 80 parts by weight, the content of the component (B) is 21 to 99.8 parts by weight, the content of the component (C) is 0.01 to 30 parts by weight and the content of the component (D) is 0 to 30 parts by weight. The composition may be cured at a relatively low temperature close to the body temperature without using a peroxide-based polymerization initiator, and has good sealing properties and adhesion.
摘要翻译：牙科用固化性组合物的固化时间为30秒〜120分钟，包括分子（A）中具有酸性基团的化合物，可聚合单体（B），有机胺化合物（C）和含硫还原化合物（D）。在牙科用固化性组合物中，成分（A）的含量为0.01〜80重量份，（B）成分为21〜99.8重量份，成分（C）的含量为0.01〜30 重量份，成分（D）的含量为0〜30重量份。组合物可以在接近体温的较低温度下固化，而不使用过氧化物基聚合引发剂，并且具有良好的密封性和粘附性。

8. 发明申请

US20120213832A1 REMOVABLE DENTAL CURABLE COMPOSITION 审中-公开
标题翻译：可去除牙齿可固化组合物
公开(公告)号：US20120213832A1
公开(公告)日：2012-08-23
申请号：US13503577
申请日：2010-10-22
申请人： Tatsuya Ori , Haruka Nishitani , Sayuri Iwasaki , Yuya Yamamoto , Chidzuru Nishimoto
发明人： Tatsuya Ori , Haruka Nishitani , Sayuri Iwasaki , Yuya Yamamoto , Chidzuru Nishimoto
IPC分类号： A61K9/14 , A61K33/18 , A61K31/05 , A61K6/083 , A61K31/4425 , A61K31/14 , A61K31/155 , A61P31/04 , A61K31/79 , A61K31/02
CPC分类号： A61K6/083 , A61K6/0023 , A61K6/0052 , C08L33/04
摘要： A dental curable composition comprises (A) a polymerizable monomer and (B) an organic amine-based polymerization initiator, wherein (A′) a long-chain polymerizable monomer having a chain length of 17 or more atoms is contained in the component (A) and/or (C) a soft resin material are/is contained in the composition, and when the amount (parts by weight) based on 100 parts by weight of the component (A) of the component (A′) is represented by [a′] and the amounts (parts by weight) based on 100 parts by weight of the total of the components (A) and (B) of the components (A), (B) and (C) are represented by (a), (b) and (c), respectively, 70≦(a)≦99.99, 0.01≦(b)≦5 30, 1≦[a′]/5+(c)/1, 0≦[a′]≦95, and 0≦(c)≦250.
摘要翻译：牙科用固化性组合物包含（A）可聚合单体和（B）有机胺基聚合引发剂，其中（A'）含有17个或更多个链长的长链可聚合单体包含在组分（A ）和/或（C）组合物中含有软质树脂材料，并且当基于100重量份组分（A'）的组分（A）的量（重量份）表示为（A），（B）和（C）的组分（A）和（B）的总计100重量份的[a']和量（重量份）由（a ），（b）和（c）分别为70和100;（a）＆nlE; 99.99,0.01和nlE;（b）＆nlE; 5,30,1和nlE; [a'] / 5+（c）/ 1,0， a']＆nlE; 95和0＆nlE;（c）＆nlE; 250。

9. 发明授权

US08129443B2 Polymerizable composition, cured object obtained therefrom, and composite material 有权
标题翻译：可聚合组合物，由其获得的固化物和复合材料
公开(公告)号：US08129443B2
公开(公告)日：2012-03-06
申请号：US10506090
申请日：2001-07-17
申请人： Tatsuya Ori , Yasukazu Saimi , Masayuki Asai
发明人： Tatsuya Ori , Yasukazu Saimi , Masayuki Asai
IPC分类号： A61K6/08 , A61F6/02 , C08K3/22 , B32B5/16
CPC分类号： A61K6/083 , C08F2/44 , C08K3/22 , Y10S977/919 , Y10T428/2998 , C08L33/00
摘要： There are provided a novel polymerizable composition having an X-ray contrast property and excellent transparency, a cured product thereof, and a composite material comprising powder of the cured product. More specifically, there are provided a polymerizable composition comprising (A) an inorganic oxide having an X-ray contrast property and an average particle diameter of 100 nm or smaller, (B) a surface modifier, (C) a polymerizable compound and (D) a polymerization initiator, a cured product obtained by polymerizing these components, and a composite material comprising powder of the cured product.
摘要翻译：提供了具有X射线对比性和优异的透明度的新型聚合性组合物，其固化物，以及包含固化物的粉末的复合材料。更具体地，提供了一种聚合性组合物，其包含（A）具有X射线对比度和平均粒径为100nm以下的无机氧化物，（B）表面改性剂，（C）可聚合化合物和（D ）聚合引发剂，通过聚合这些组分获得的固化产物和包含固化产物的粉末的复合材料。

10. 发明申请

US20050123762A1 Polymerizable composition, cured object obtained therefrom, and composite material 有权
标题翻译：可聚合组合物，由其获得的固化物和复合材料
公开(公告)号：US20050123762A1
公开(公告)日：2005-06-09
申请号：US10506090
申请日：2001-07-17
申请人： Tatsuya Ori , Yasukazu Saimi , Masayuki Asai
发明人： Tatsuya Ori , Yasukazu Saimi , Masayuki Asai
IPC分类号： A61K6/083 , C08F2/44 , C08K3/22 , B32B5/16
CPC分类号： A61K6/083 , C08F2/44 , C08K3/22 , Y10S977/919 , Y10T428/2998 , C08L33/00
摘要： There are provided a novel polymerizable composition having an X-ray contrast property and excellent transparency, a cured product thereof, and a composite material comprising powder of the cured product. More specifically, there are provided a polymerizable composition comprising (A) an inorganic oxide having an X-ray contrast property and an average particle diameter of 100 nm or smaller, (B) a surface modifier, (C) a polymerizable compound and (D) a polymerization initiator, a cured product obtained by polymerizing these components, and a composite material comprising powder of the cured product.
摘要翻译：提供了具有X射线对比性和优异的透明度的新型聚合性组合物，其固化物，以及包含固化物的粉末的复合材料。更具体地，提供了一种聚合性组合物，其包含（A）具有X射线对比度和平均粒径为100nm以下的无机氧化物，（B）表面改性剂，（C）可聚合化合物和（D ）聚合引发剂，通过聚合这些组分获得的固化产物和包含固化产物的粉末的复合材料。

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