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1. 发明授权

US10604712B2 Phase behaviors and properties of certain triacylglycerols and fatty acid methyl esters 有权
公开(公告)号：US10604712B2
公开(公告)日：2020-03-31
申请号：US13863105
申请日：2013-04-15
申请人： Trent University
发明人： Suresh Narine , Laziz Bouzidi , Bruce Darling , Mark Baker , Shaojun Li , Ali Mahdevari
IPC分类号： C10L1/19 , C10L10/14
摘要： This application relates to phase behaviors of certain triacylglycerols and fatty acid methyl esters, and how the phase behaviors of these individual components in a biodiesel fuel, as well as their combined mixtures, helps understand the fundamental mechanisms of their crystallization so as to design biodiesel fuels with improved low temperature characteristics.

2. 发明申请

US20160311753A1 Methods of Making Triacylglycerol Polyols from Fractions of Metathesized Natural Oils and Uses Thereof 审中-公开
标题翻译：从分解天然油的馏分制备三酰基甘油多元醇的方法及其用途
公开(公告)号：US20160311753A1
公开(公告)日：2016-10-27
申请号：US15005522
申请日：2016-01-25
申请人： Trent University
发明人： Suresh Narine , Prasanth Kumar Sasidharan Pillai , Shaojun Li , Laziz Bouzidi , Ali Mahdevari
IPC分类号： C07C67/31 , C07C67/52 , C07C67/58 , C08J9/12 , C08G18/36 , C08G18/76 , C08G18/08 , C07C67/475 , C07D301/12
CPC分类号： C07C67/31 , A61K8/85 , A61K2800/10 , A61Q19/00 , C07C67/333 , C07C67/475 , C07C67/52 , C07C67/58 , C07D301/12 , C07D301/16 , C08G18/14 , C08G18/3206 , C08G18/36 , C08G18/7657 , C08G18/7671 , C08G2101/0008 , C08G2101/0025 , C08G2101/0066 , C08G2101/0083 , C08J9/122 , C08J2205/06 , C08J2205/10 , C08J2375/06 , C08L75/04 , C07C69/533 , C07C69/58 , C07C69/675
摘要： Polyols derived from palm oil fractions of metathesized triacylglycerols, and their related physical properties are disclosed. Such metathesized triacylglycerol polyols are also used as a component of polyurethane applications, including polyurethane foams.
摘要翻译：公开了衍生自偏碳酸三酰基甘油的棕榈油馏分的多元醇及其相关的物理性质。这种复分解的三酰基甘油多元醇也用作聚氨酯应用的组分，包括聚氨酯泡沫。

3. 发明申请

US20160075820A1 SYNTHESIS AND MOLECULAR WEIGHT CONTROL OF ALIPHATIC POLYESTER DIOLS 有权
标题翻译：脂肪酸二酯的合成和分子量控制
公开(公告)号：US20160075820A1
公开(公告)日：2016-03-17
申请号：US14854840
申请日：2015-09-15
申请人： Trent University
发明人： Suresh Narine , Shaojun Li , Jesmy Jose , Shegufta Shetranjiwalla , Laziz Bouzidi
IPC分类号： C08G63/16
CPC分类号： C08G63/16 , C08G63/78 , C08G63/90
摘要： The synthesis of certain polyester diols (PEDs) is disclosed. This application also discloses the purification and polymerization kinetics of lipid based PEDs. Molecular weight and distribution controls were achieved by initial and induced stoichiometric imbalance and optimization of the purification protocol. Thermal degradation and thermal transition behavior of the PEDs were also investigated by TGA and DSC.
摘要翻译：公开了某些聚酯二醇（PED）的合成。本申请还公开了基于脂质的PED的纯化和聚合动力学。通过初始和诱导的化学计量不平衡和纯化方案的优化实现分子量和分布对照。还通过TGA和DSC研究了PEDs的热降解和热转变行为。

4. 发明授权

US10125337B2 Branched diesters and methods of making and using the same 有权
公开(公告)号：US10125337B2
公开(公告)日：2018-11-13
申请号：US15352784
申请日：2016-11-16
申请人： TRENT UNIVERSITY
发明人： Suresh Narine , Laziz Bouzidi , Latchmi Raghunanan
IPC分类号： C10M145/22 , C10M129/72 , C07C69/67 , C07C69/73 , C10L1/19 , C10L10/08 , C10M101/02 , C10M105/04 , C10M129/76 , C07C69/675 , C10M105/38 , C10M105/40 , C10M105/42
摘要： The disclosure generally provides branched diester compounds having exceptional low-temperature and flow properties. The disclosure also provides uses of the branched diester compounds in lubricant compositions, for example, as a base oil, and in other applications where their low-temperature and flow properties can be employed beneficially. The disclosure also provides efficient and green methods for making the branched diester compounds.

5. 发明申请

US20170145146A1 RENEWABLY DERIVED THERMOPLASTIC POLYESTER-BASED URETHANES AND METHODS OF MAKING AND USING THE SAME 审中-公开
公开(公告)号：US20170145146A1
公开(公告)日：2017-05-25
申请号：US15361184
申请日：2016-11-25
申请人： Trent University
发明人： Suresh Narine , Shegufta Shetranjiwalla , Shaojun Li , Laziz Bouzidi
IPC分类号： C08G18/42 , C08G18/76
CPC分类号： C08G18/4238 , C08G18/244 , C08G18/3206 , C08G18/664 , C08G18/73 , C08G18/7671 , C08G2230/00
摘要： The disclosure generally provides high-molecular-weight thermoplastic polyester-based urethanes (TPEUs). In some embodiments, the component monomers of the TPEUs are entirely derived from renewable sources. The disclosure also provides methods of making high-molecular-weight TPEUs, and, in particular, methods for achieving such high molecular weights. The disclosure also provides certain uses of such TPEUs.High molecular weight, semi-crystalline TPEU elastomers were synthesized from polyester diols (PEDs) and 1,7 heptamethylene diisocyanate (HPMDI) both derived from oleic acid. Functional group stoichiometry and polymerization time were used as tools to control molecular weight and optimize the thermal and mechanical properties of the TPEU. A targeted range of PEDs with controlled molecular weights and narrow polydispersity indices were obtained in high yields using an induced stoichiometric imbalance method. The PEDs were reacted with HPMDI with different NCO:OH ratios (1.1 to 2.1) and polymerization times (2 to 24 hours) in order to obtain high molecular weight TPEUs. Solvent-resistant TPEUs, displaying polyethylene-like behavior with controlled polyester and urethane segment phase separation were obtained and characterized by FTIR, 1H-NMR, GPC, DSC, TGA and tensile tests in order to reveal the structure-property relationships. Melting and glass transition temperatures, tensile strength and maximum strain increased with molecular weight approaching saturation values, demonstrating a plateau effect of molecular weight on physical properties. The novel TPEUs showed extensive degradation under hydrothermal ageing in water at 80° C. and achieved a tensile half-life in one day of immersion. The entirely lipid-derived TPEUs exhibited thermal and mechanical properties comparable to commercially available entirely petroleum-based analogues.

6. 发明申请

US20170121623A1 CERTAIN TRIACYLGLYCEROLS AS CRYSTALLIZATION DEPRESSANTS 审中-公开
公开(公告)号：US20170121623A1
公开(公告)日：2017-05-04
申请号：US15337500
申请日：2016-10-28
申请人： TRENT UNIVERSITY
发明人： Suresh Narine , Laziz Bouzidi , Athira Mohanan
IPC分类号： C10L10/14 , C10L1/02 , C10L1/19
CPC分类号： C10L10/14 , C10L1/026 , C10L1/191 , C10L2200/0476 , C10L2270/026 , Y02E50/13
摘要： This application relates to the polymorphism and microstructure of certain triacylglycerols and fatty acid methyl esters, including 1,2-dioleoyl-3-stearoyl glycerol and methyl stearate, and how the properties of these individual components in a biodiesel fuel, as well as their combined mixtures, helps understand the fundamental mechanisms of their crystallization so as to design biodiesel fuels with improved low temperature characteristics.

7. 发明申请

US20160312151A1 Methods of Fractionating Metathesized Triacylglycerol Polyols and Uses Thereof 有权
标题翻译：分解三聚甘油三醇多元醇及其用途的方法
公开(公告)号：US20160312151A1
公开(公告)日：2016-10-27
申请号：US15005895
申请日：2016-01-25
申请人： Trent University
发明人： Suresh Narine , Prasanth Kumar Sasidharan Pillai , Shaojun Li , Laziz Bouzidi , Ali Mahdevari
IPC分类号： C11C3/00 , C08G18/08 , C08G18/76 , C11C1/00 , C08G18/36
CPC分类号： C11C3/00 , A61K8/375 , A61K8/85 , A61K2800/10 , A61Q19/00 , C07C67/31 , C07C67/333 , C08G18/14 , C08G18/36 , C08G18/7671 , C08G2101/0008 , C08G2101/0025 , C08G2101/0083 , C08L75/04 , C11C1/005 , C11C3/006 , C07C69/533 , C07C69/675
摘要： Metathesized triacylglycerol polyols, fractionated polyol variants thereof, and their related physical and thermal properties are disclosed.
摘要翻译：公开了三元酰甘油多元醇，其分馏的多元醇变体及其相关的物理和热性能。

8. 发明授权

US09181507B2 Phase behaviors and properties of certain triacylglycerols and fatty acid methyl esters 有权
标题翻译：某些三酰基甘油和脂肪酸甲酯的相行为和性质
公开(公告)号：US09181507B2
公开(公告)日：2015-11-10
申请号：US13863137
申请日：2013-04-15
申请人： TRENT UNIVERSITY
发明人： Suresh Narine , Laziz Bouzidi , Bruce Darling , Mark Baker , Shaojun Li , Ali Mahdevari
IPC分类号： C10L1/19
CPC分类号： C10L1/19 , C10L1/191 , C10L2200/0476 , C10L2230/14
摘要： This application relates to phase behaviors of certain triacylglycerols and fatty acid methyl esters, and how the phase behaviors of these individual components in a biodiesel fuel, as well as their combined mixtures, helps understand the fundamental mechanisms of their crystallization so as to design biodiesel fuels with improved low temperature characteristics.
摘要翻译：本申请涉及某些三酰基甘油和脂肪酸甲酯的相行为，以及生物柴油燃料中这些单独组分的相行为及其组合混合物如何有助于了解其结晶的基本机制，从而设计生物柴油燃料具有改进的低温特性。

9. 发明申请

US20130269241A1 PHASE BEHAVIORS AND PROPERTIES OF CERTAIN TRIACYLGLYCEROLS AND FATTY ACID METHYL ESTERS 有权
标题翻译：某些三乙基胆甾醇和脂肪酸甲酯的相行为和性质
公开(公告)号：US20130269241A1
公开(公告)日：2013-10-17
申请号：US13863137
申请日：2013-04-15
申请人： TRENT UNIVERSITY , ELEVANCE RENEWABLE SCIENCES, INC.
发明人： Suresh Narine , Laziz Bouzidi , Bruce Darling , Mark Baker , Shaojun Li , Ali Mahdevari
IPC分类号： C10L1/19
CPC分类号： C10L1/19 , C10L1/191 , C10L2200/0476 , C10L2230/14
摘要： This application relates to phase behaviors of certain triacylglycerols and fatty acid methyl esters, and how the phase behaviors of these individual components in a biodiesel fuel, as well as their combined mixtures, helps understand the fundamental mechanisms of their crystallization so as to design biodiesel fuels with improved low temperature characteristics.
摘要翻译：本申请涉及某些三酰基甘油和脂肪酸甲酯的相行为，以及生物柴油燃料中这些单独组分的相行为及其组合混合物如何有助于了解其结晶的基本机制，从而设计生物柴油燃料具有改进的低温特性。

10. 发明授权

US10047313B2 Certain triacylglycerols as crystallization depressants 有权
公开(公告)号：US10047313B2
公开(公告)日：2018-08-14
申请号：US15337500
申请日：2016-10-28
申请人： TRENT UNIVERSITY
发明人： Suresh Narine , Laziz Bouzidi , Athira Mohanan
IPC分类号： C10L10/14 , C10L1/02 , C10L1/19
摘要： This application relates to the polymorphism and microstructure of certain triacylglycerols and fatty acid methyl esters, including 1,2-dioleoyl-3-stearoyl glycerol and methyl stearate, and how the properties of these individual components in a biodiesel fuel, as well as their combined mixtures, helps understand the fundamental mechanisms of their crystallization so as to design biodiesel fuels with improved low temperature characteristics.

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