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1. 发明授权

US09530965B2 Conductive polymer films grafted on organic substrates 有权
标题翻译：导电聚合物膜接枝在有机基底上
公开(公告)号：US09530965B2
公开(公告)日：2016-12-27
申请号：US14331891
申请日：2014-07-15
申请人： Karen K. Gleason , Sung Gap Im
发明人： Karen K. Gleason , Sung Gap Im
IPC分类号： C08G73/06 , B05D3/12 , C08L67/00 , H01L51/00 , B05D1/00 , C08G61/12 , C09D165/00 , C09D179/02 , B05D1/18 , B05D3/10 , G02F1/15
CPC分类号： H01L51/0037 , B05D1/185 , B05D1/60 , B05D3/10 , C08G61/124 , C08G61/125 , C08G61/126 , C09D165/00 , C09D179/02 , G02F2001/1515
摘要： One aspect of the invention relates to a linker-free, one-step method of grafting polymer films onto organic substrates, and the films obtained by such a method. In certain embodiments, the grafted polymer films are conductive. In certain embodiments, said grafting method utilizes the ability for Friedel-Crafts catalyst to form radical cations from organic substrates. In one embodiment, the method provides poly-3,4-ethylenedioxythiophene (PEDOT) thin films grafted to organic substrates. In other embodiments, the method is applicable to the polymerization of other monomers to yield conducting polymers, such as polyanilines, polypyrroles, polyfurans, polythiophenes and their derivatives. Remarkably, the polymer films grafted by the inventive methods show enormous increases in adhesion strength. Further, in certain embodiments, polymer patterns were easily obtained using the inventive methods and soft lithography techniques. In certain embodiments, well-defined high-density line-and-space patterns were successfully obtained. In certain embodiments, e.g., when the polymer film is conducting, the obtained conducting polymer pattern grafted on common organic substrates can be used for integrated circuitry in flexible electronics.
摘要翻译：本发明的一个方面涉及将聚合物膜接枝到有机基底上的无接头的一步法，以及通过这种方法获得的膜。在某些实施方案中，接枝的聚合物膜是导电的。在某些实施方案中，所述接枝方法利用了Friedel-Crafts催化剂从有机底物形成自由基阳离子的能力。在一个实施方案中，该方法提供接枝到有机基底上的聚3,4-亚乙基二氧噻吩（PEDOT）薄膜。在其它实施方案中，该方法适用于其它单体的聚合以产生导电聚合物，例如聚苯胺，聚吡咯，聚呋喃，聚噻吩及其衍生物。显着地，通过本发明方法接枝的聚合物膜显示出粘合强度的巨大增加。此外，在某些实施方案中，使用本发明的方法和软光刻技术容易地获得聚合物图案。在某些实施例中，成功地获得了明确定义的高密度线和空间图案。在某些实施方案中，例如，当聚合物膜导电时，所获得的接枝在共同有机衬底上的导电聚合物图案可用于柔性电子器件中的集成电路。

2. 发明授权

US07176622B2 Organic electro-luminescence device with dielectric layer having antioxidative material and fabricating method thereof 有权
标题翻译：具有抗氧化材料的电介质层的有机电致发光元件及其制造方法
公开(公告)号：US07176622B2
公开(公告)日：2007-02-13
申请号：US10826279
申请日：2004-04-19
申请人： Sung Gap Im
发明人： Sung Gap Im
IPC分类号： H01J1/62 , H01J63/04 , H01J17/24
CPC分类号： H01L51/50 , H01L51/5092 , H01L51/5237 , H01L51/5259
摘要： An organic electro-luminescence (EL) device includes a first electrode formed on a substrate and a second electrode formed to overlap with the first electrode. An organic EL layer is located between the first and second electrodes. A dielectric layer is formed between the second electrode and the EL layer. The dielectric layer contains antioxidative material, formed by a mixture of approximately 50˜75% of an organic material and approximately 25˜50% of an metallic powder. The organic electro-luminescence device demonstrates an increased picture quality and increased luminous efficiency.
摘要翻译：有机电致发光（EL）器件包括形成在衬底上的第一电极和形成为与第一电极重叠的第二电极。有机EL层位于第一和第二电极之间。在第二电极和EL层之间形成介电层。介电层含有抗氧化材料，由约50〜75％的有机材料和约25〜50％的金属粉末的混合物形成。有机电致发光器件表现出增加的图像质量和增加的发光效率。

3. 发明申请

US20100048830A1 Conductive Polymer Films Grafted on Organic Substrates 有权
标题翻译：导电聚合物膜接枝在有机基板上
公开(公告)号：US20100048830A1
公开(公告)日：2010-02-25
申请号：US12525376
申请日：2008-01-31
申请人： Karen K. Gleason , Sung Gap Im
发明人： Karen K. Gleason , Sung Gap Im
IPC分类号： C08G73/06 , B05D3/12 , C08L67/00
CPC分类号： H01L51/0037 , B05D1/185 , B05D1/60 , B05D3/10 , C08G61/124 , C08G61/125 , C08G61/126 , C09D165/00 , C09D179/02 , G02F2001/1515
摘要： One aspect of the invention relates to a linker-free, one-step method of grafting polymer films onto organic substrates, and the films obtained by such a method. In certain embodiments, the grafted polymer films are conductive. In certain embodiments, said grafting method utilizes the ability for Friedel-Crafts catalyst to form radical cations from organic substrates. In one embodiment, the method provides poly-3,4-ethylenedioxythiophene (PEDOT) thin films grafted to organic substrates. In other embodiments, the method is applicable to the polymerization of other monomers to yield conducting polymers, such as polyanilines, polypyrroles, polyfurans, polythiophenes and their derivatives. Remarkably, the polymer films grafted by the inventive methods show enormous increases in adhesion strength. Further, in certain embodiments, polymer patterns were easily obtained using the inventive methods and soft lithography techniques. In certain embodiments, well-defined high-density line-and-space patterns were successfully obtained. In certain embodiments, e.g., when the polymer film is conducting, the obtained conducting polymer pattern grafted on common organic substrates can be used for integrated circuitry in flexible electronics.
摘要翻译：本发明的一个方面涉及将聚合物膜接枝到有机基底上的无接头的一步法，以及通过这种方法获得的膜。在某些实施方案中，接枝的聚合物膜是导电的。在某些实施方案中，所述接枝方法利用了Friedel-Crafts催化剂从有机底物形成自由基阳离子的能力。在一个实施方案中，该方法提供接枝到有机基底上的聚3,4-亚乙基二氧噻吩（PEDOT）薄膜。在其它实施方案中，该方法适用于其它单体的聚合以产生导电聚合物，例如聚苯胺，聚吡咯，聚呋喃，聚噻吩及其衍生物。显着地，通过本发明方法接枝的聚合物膜显示出粘合强度的巨大增加。此外，在某些实施方案中，使用本发明的方法和软光刻技术容易获得聚合物图案。在某些实施例中，成功地获得了明确定义的高密度线和空间图案。在某些实施方案中，例如，当聚合物膜导电时，所获得的接枝在共同有机衬底上的导电聚合物图案可用于柔性电子器件中的集成电路。

4. 发明申请

US20150079282A1 Conductive Polymer Films Grafted on Organic Substrates 有权
标题翻译：导电聚合物膜接枝在有机基板上
公开(公告)号：US20150079282A1
公开(公告)日：2015-03-19
申请号：US14331891
申请日：2014-07-15
申请人： Karen K. Gleason , Sung Gap Im
发明人： Karen K. Gleason , Sung Gap Im
IPC分类号： H01L51/00
CPC分类号： H01L51/0037 , B05D1/185 , B05D1/60 , B05D3/10 , C08G61/124 , C08G61/125 , C08G61/126 , C09D165/00 , C09D179/02 , G02F2001/1515
摘要： One aspect of the invention relates to a linker-free, one-step method of grafting polymer films onto organic substrates, and the films obtained by such a method. In certain embodiments, the grafted polymer films are conductive. In certain embodiments, said grafting method utilizes the ability for Friedel-Crafts catalyst to form radical cations from organic substrates. In one embodiment, the method provides poly-3,4-ethylenedioxythiophene (PEDOT) thin films grafted to organic substrates. In other embodiments, the method is applicable to the polymerization of other monomers to yield conducting polymers, such as polyanilines, polypyrroles, polyfurans, polythiophenes and their derivatives. Remarkably, the polymer films grafted by the inventive methods show enormous increases in adhesion strength. Further, in certain embodiments, polymer patterns were easily obtained using the inventive methods and soft lithography techniques. In certain embodiments, well-defined high-density line-and-space patterns were successfully obtained. In certain embodiments, e.g., when the polymer film is conducting, the obtained conducting polymer pattern grafted on common organic substrates can be used for integrated circuitry in flexible electronics.
摘要翻译：本发明的一个方面涉及将聚合物膜接枝到有机基底上的无接头的一步法，以及通过这种方法获得的膜。在某些实施方案中，接枝的聚合物膜是导电的。在某些实施方案中，所述接枝方法利用了Friedel-Crafts催化剂从有机底物形成自由基阳离子的能力。在一个实施方案中，该方法提供接枝到有机基底上的聚3,4-亚乙基二氧噻吩（PEDOT）薄膜。在其它实施方案中，该方法适用于其它单体的聚合以产生导电聚合物，例如聚苯胺，聚吡咯，聚呋喃，聚噻吩及其衍生物。显着地，通过本发明方法接枝的聚合物膜显示出粘合强度的巨大增加。此外，在某些实施方案中，使用本发明的方法和软光刻技术容易地获得聚合物图案。在某些实施例中，成功地获得了明确定义的高密度线和空间图案。在某些实施方案中，例如，当聚合物膜导电时，所获得的接枝在共同有机衬底上的导电聚合物图案可用于柔性电子器件中的集成电路。

5. 发明授权

US06998487B2 Double-spiro organic compounds and organic electroluminescent devices using the same 有权
标题翻译：双螺状有机化合物和使用其的有机电致发光器件
公开(公告)号：US06998487B2
公开(公告)日：2006-02-14
申请号：US10099781
申请日：2002-03-14
申请人： Kong Kyeom Kim , Sehwan Son , Seokhee Yoon , Jae soon Bae , Youn-Gu Lee , Sung Gap Im , Jieun Kim , Jae Chol Lee
发明人： Kong Kyeom Kim , Sehwan Son , Seokhee Yoon , Jae soon Bae , Youn-Gu Lee , Sung Gap Im , Jieun Kim , Jae Chol Lee
IPC分类号： C07D211/00
CPC分类号： H01L51/0058 , C07C13/72 , C07C17/12 , C07C17/35 , C07C25/22 , C07C47/546 , C07C211/54 , C07C211/61 , C07C2603/14 , C07C2603/18 , C07C2603/24 , C07C2603/42 , C07C2603/96 , C07C2603/97 , C07D209/82 , C07D209/86 , C07D209/88 , C07D235/18 , C07D241/42 , C07D263/57 , C07D277/66 , C07D333/08 , C07D333/18 , C07D409/04 , C07D409/10 , C07D409/14 , C07D471/04 , C07D487/04 , C07F5/025 , C09K11/06 , C09K2211/1003 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1037 , C09K2211/1044 , C09K2211/1092 , H01L51/0052 , H01L51/006 , H01L51/0067 , H01L51/0068 , H01L51/0069 , H01L51/0071 , H01L51/008 , H01L51/5012 , H01L51/5048 , H01L51/5088 , H01L51/5092 , H05B33/14 , Y10S428/917
摘要： Disclosed are double-spiro organic compounds and an organic electroluminescence (EL) device using the same. The double-spiro organic compounds are configured to have at least three planar and substantially linear moieties, such that one planar moiety is located between two neighboring planar moieties and that the intervening planar moiety shares an atom with each of the two neighboring planar moieties. The double-spiro compounds generally have high melting point above about 300 degree C. and low crystallinity, which provide thermal stability to the organic EL devices. These organic compounds have good sublimability. They also have light-emitting, hole-injecting, hole-transporting, electron injection, electron-transporting properties and characteristics, which are favorable in the organic EL devices.
摘要翻译：公开了双螺环有机化合物和使用其的有机电致发光（EL）装置。双螺环有机化合物被配置为具有至少三个平面和基本上线性的部分，使得一个平面部分位于两个相邻的平面部分之间，并且插入的平面部分与两个相邻的平面部分中的每一个共享原子。双螺环化合物通常具有高于约300℃的高熔点和低结晶度，其为有机EL器件提供热稳定性。这些有机化合物具有良好的升华性。它们还具有在有机EL器件中有利的发光，空穴注入，空穴传输，电子注入，电子传输性能和特性。

6. 发明授权

US06984462B2 Organic electroluminescent devices using double-spiro organic compounds 有权
标题翻译：使用双螺旋有机化合物的有机电致发光器件
公开(公告)号：US06984462B2
公开(公告)日：2006-01-10
申请号：US10718083
申请日：2003-11-19
申请人： Kong Kyeom Kim , Sehwan Son , Seokhee Yoon , Jae soon Bae , Youn-Gu Lee , Sung Gap Im , Jieun Kim , Jae Chol Lee
发明人： Kong Kyeom Kim , Sehwan Son , Seokhee Yoon , Jae soon Bae , Youn-Gu Lee , Sung Gap Im , Jieun Kim , Jae Chol Lee
IPC分类号： H05B33/14
CPC分类号： H01L51/0058 , C07C13/72 , C07C17/12 , C07C17/35 , C07C25/22 , C07C47/546 , C07C211/54 , C07C211/61 , C07C2603/14 , C07C2603/18 , C07C2603/24 , C07C2603/42 , C07C2603/96 , C07C2603/97 , C07D209/82 , C07D209/86 , C07D209/88 , C07D235/18 , C07D241/42 , C07D263/57 , C07D277/66 , C07D333/08 , C07D333/18 , C07D409/04 , C07D409/10 , C07D409/14 , C07D471/04 , C07D487/04 , C07F5/025 , C09K11/06 , C09K2211/1003 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1037 , C09K2211/1044 , C09K2211/1092 , H01L51/0052 , H01L51/006 , H01L51/0067 , H01L51/0068 , H01L51/0069 , H01L51/0071 , H01L51/008 , H01L51/5012 , H01L51/5048 , H01L51/5088 , H01L51/5092 , H05B33/14 , Y10S428/917
摘要： Disclosed are double-spiro organic compounds and an organic electroluminescence (EL) device using the same. The double-spiro organic compounds are configured to have at least three planar and substantially linear moieties, such that one planar moiety is located between two neighboring planar moieties and that the intervening planar moiety shares an atom with each of the two neighboring planar moieties. The double-spiro compounds generally have high melting point above about 300 degree C. and low crystallinity, which provide thermal stability to the organic EL devices. These organic compounds have good sublimability. They also have light-emitting, hole-injecting, hole-transporting, electron injection, electron-transporting properties and characteristics, which are favorable in the organic EL devices.
摘要翻译：公开了双螺环有机化合物和使用其的有机电致发光（EL）装置。双螺环有机化合物被配置为具有至少三个平面和基本上线性的部分，使得一个平面部分位于两个相邻的平面部分之间，并且插入的平面部分与两个相邻的平面部分中的每一个共享原子。双螺环化合物通常具有高于约300℃的高熔点和低结晶度，其为有机EL器件提供热稳定性。这些有机化合物具有良好的升华性。它们还具有在有机EL器件中有利的发光，空穴注入，空穴传输，电子注入，电子传输性能和特性。

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