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1. 发明申请

US20080210567A1 Electrodeposition Material, Process for Providing a Corrosion-Protective Layer of TiO2 on an Electrically Conductive Substrate and Metal Substrate Coated with a Layer of TiO2 审中-公开
标题翻译：电沉积材料，在导电基材和金属基板上涂覆TiO 2的TiO 2的腐蚀保护层的方法
公开(公告)号：US20080210567A1
公开(公告)日：2008-09-04
申请号：US11961095
申请日：2007-12-20
申请人： Subbian Karuppuchamy , Naoki Suzuki , Seishiro Ito , Schweinsberg Matthias , Hans Dolhaine , Frank Wiechmann , Christine Schroeder
发明人： Subbian Karuppuchamy , Naoki Suzuki , Seishiro Ito , Schweinsberg Matthias , Hans Dolhaine , Frank Wiechmann , Christine Schroeder
IPC分类号： C25D3/54
CPC分类号： C25D9/08
摘要： The present invention relates to electrodeposition material for the electrochemical deposition of a corrosion-protective layer of TiO2 on an electrically conductive substrate comprising a titanium compound, a complexing agent, an accelerator, water and optionally organic solvents, buffering agents and one or more additives, characterized in that the titanium compound is titanyl sulfate and/or titanyl oxalate, the complexing agent is selected from the group consisting of citric acid, citrates, tartaric acid, tartrates, lactic acid, lactates, gluconic acid, gluconates, polyhydroxy-polycarbonic acids, ethylenediaminetetraacetate, methylglycinediacetate, iminodisuccinate, nitrilotriacetic acid and nitrilotriacetate, triethanolamine, phosphonic acid and phosphonates, polyaspartic acid and polyaspartates, polyacrylic acid and polyacrylates and the accelerator is selected from the group consisting of H2O2 and organic peroxides. The invention further relates to a process for providing a corrosion-protective layer of TiO2 on an electrically conductive substrate and to a metal substrate coated with a layer of TiO2.
摘要翻译：本发明涉及用于在包含钛化合物，络合剂，促进剂，水和任选的有机溶剂的导电基材上电化学沉积TiO 2的腐蚀保护层的电沉积材料，缓冲剂和一种或多种添加剂，其特征在于钛化合物是硫酸氧钛和/或草酸氧钛，络合剂选自柠檬酸，柠檬酸盐，酒石酸，酒石酸盐，乳酸，乳酸盐，葡萄糖酸，葡糖酸盐，多羟基 - 聚碳酸，乙二胺四乙酸盐，甲基甘氨二乙酸盐，亚氨基二琥珀酸盐，次氮基三乙酸和次氮基三乙酸盐，三乙醇胺，膦酸和膦酸盐，聚天冬氨酸和聚天冬氨酸盐，聚丙烯酸和聚丙烯酸盐，加速剂选自H 2 O 2和有机过氧化物。本发明还涉及一种在导电衬底上和涂覆有TiO 2层的金属衬底上提供TiO 2的防腐蚀层的方法。

2. 发明申请

US20070148479A1 Corrosion-protection by electrochemical deposition of metal oxide layers on metal substrates 审中-公开
标题翻译：通过在金属基底上电化学沉积金属氧化物层进行腐蚀保护
公开(公告)号：US20070148479A1
公开(公告)日：2007-06-28
申请号：US11471330
申请日：2006-06-20
申请人： Hiroki Ishikazi , Matthias Schweinsberg , Seishiro Ito , Frank Wiechmann
发明人： Hiroki Ishikazi , Matthias Schweinsberg , Seishiro Ito , Frank Wiechmann
IPC分类号： B32B15/04 , C25D11/00
CPC分类号： C25D9/08 , C25D13/20
摘要： The present invention relates to a process for providing a metal substrate with corrosion-protection and corrosion-resistance, respectively, as well as to the products thus obtainable. Said process comprises coating said metal substrate with a thin layer of at least one metal oxide selected from the group consisting of TiO2, Bi2O3 and ZnO, preferably TiO2, by electrochemically depositing said metal oxide layer on at least one surface of said metal substrate. At the same time, said metal oxide layer may serve as a primer layer for subsequent coating treatment (e.g. coating with organic materials, such as for instance lacquers, varnishes, paints, organic polymers, adhesives, etc.).
摘要翻译：本发明涉及分别提供具有耐腐蚀性和耐腐蚀性的金属基材以及由此获得的产品的方法。所述方法包括用选自TiO 2，Bi 2 O 3 3 / / SUB的至少一种金属氧化物的薄层涂覆所述金属基材 >和ZnO，优选TiO 2，通过在所述金属基底的至少一个表面上电化学沉积所述金属氧化物层。同时，所述金属氧化物层可用作后续涂覆处理的底漆层（例如涂覆有机材料，例如漆，清漆，油漆，有机聚合物，粘合剂等）。

3. 发明申请

US20090192628A1 Bone Substitute Material, Medical Material Comprising the Bone Substitute Material and Method for Manufacturing the Bone Substitute Material 审中-公开
标题翻译：骨替代材料，包含骨替代材料的医疗材料和骨替代材料的制造方法
公开(公告)号：US20090192628A1
公开(公告)日：2009-07-30
申请号：US12065860
申请日：2006-08-31
申请人： Seishiro Ito , Mitsunobu Iwasaki
发明人： Seishiro Ito , Mitsunobu Iwasaki
IPC分类号： A61F2/28 , C25D21/00 , C25D7/00
CPC分类号： A61L27/06 , A61L27/306 , A61L2430/02 , C25D11/026 , C25D11/26
摘要： The object of the present invention is to provide a bone substitute material, medical material containing the bone substitute material and process for producing the bone substitute material wherein the bone material has excellent mechanical strength, biological affinity and biological activity.The present invention provides a bone substitute material comprising a titanium or a titanium alloy and an anodic oxide film of the titanium or titanium alloy, wherein the anodic oxide film is formed on a surface of the titanium or titanium alloy, wherein inorganic compound microparticles are firmly fixed to a surface and/or inside of the anodic oxide film, and wherein the inorganic compound contains at least phosphorus and calcium. The present invention further provides a medical material comprising the bone substitute material and a method for manufacturing the bone substitute material.
摘要翻译：本发明的目的是提供一种骨替代材料，含有骨替代材料的医用材料和骨替代材料的制造方法，其中骨材具有优异的机械强度，生物亲和力和生物活性。本发明提供一种钛或钛合金的骨替代材料和钛或钛合金的阳极氧化膜，其中阳极氧化膜形成在钛或钛合金的表面上，其中无机化合物微粒牢固固定到阳极氧化膜的表面和/或内部，并且其中无机化合物至少含有磷和钙。本发明还提供了包含骨替代材料的医疗材料和用于制造骨替代材料的方法。

4. 发明授权

US5217601A Method for impartation of blue color to aluminum or aluminum alloy 失效
标题翻译：用于将蓝色颜色转移到铝或铝合金的方法
公开(公告)号：US5217601A
公开(公告)日：1993-06-08
申请号：US894586
申请日：1992-06-05
申请人： Norio Nakada , Hideo Fukui , Hatsuo Hirono , Seishiro Ito
发明人： Norio Nakada , Hideo Fukui , Hatsuo Hirono , Seishiro Ito
IPC分类号： C25D11/22
CPC分类号： C25D11/22
摘要： Durable and clear blue color of freely controlled density can be expeditiously and efficiently impated to an anodic oxide film of aluminum by a method which comprises forming the anodic oxide film on the aluminum or aluminum alloy, then subjecting the aluminum or aluminum alloy to AC electrolysis in a bath containing an inorganic ferrous salt as a main component thereof thereby inducing deposition of iron in the pores of the oxide film, and subsequently placing the aluminum or aluminum alloy as an anode in a bath containing hexacyano iron (II) acid salt as a main component thereof and subjecting the same to DC electrolysis therein. In the alternative method, the pore-widening treatment is added next to said step of anodic oxidation. The pore-widening treatment is effected by immersing the aluminum or aluminum alloy in sulfuric acid or phosphoric acid or electrolyzing the same in phosphoric acid or a mixed solution of phosphoric acid and sulfuric acid.
摘要翻译：通过包括在铝或铝合金上形成阳极氧化膜，然后对铝或铝合金进行交流电解的方法，可以快速且有效地将耐用且清晰的蓝色的自由控制密度照射到铝的阳极氧化膜上含有无机亚铁盐作为主要成分的浴，由此在氧化膜的孔中引起铁的沉积，随后将铝或铝合金作为阳极置于含有六氰基铁（II）酸盐作为主体的浴中其组分并在其中进行DC电解。在替代方法中，在所述阳极氧化步骤旁边加入扩孔处理。通过将铝或铝合金浸渍在硫酸或磷酸中或在磷酸或磷酸和硫酸的混合溶液中电解，进行扩孔处理。

5. 发明授权

US5120405A Method of coloring aluminum or aluminum alloy material 失效
标题翻译：铝或铝合金材料的着色方法
公开(公告)号：US5120405A
公开(公告)日：1992-06-09
申请号：US663009
申请日：1991-03-01
申请人： Seishiro Ito , Hideo Fukui , Norio Nakada , Hatsuo Hirono
发明人： Seishiro Ito , Hideo Fukui , Norio Nakada , Hatsuo Hirono
IPC分类号： C25D11/18 , C25D11/20 , C25D11/22 , C25D11/24
CPC分类号： C25D11/22 , C25D11/24
摘要： An aluminum or aluminum alloy material is subjected to anodic oxidation, then to a treatment of electrophoresis in a bath containing a hexacyanoferrate (II) or hexacyanoferrate (III), and subsequently to a treatment of immersion in a bath containing at least one metal salt selected from the group consisting of salts of Fe, Ni, Co, Cu, Zn, Cd, Ba, Tl, and Mg and at least one electrolyte selected from the group consisting of sodium sulfate, potassium sulfate, sodium chloride, and potassium chloride. Consequently, a coloring compound formed by the reaction of the aforementioned hexacyanoferrate (II) or hexacyanoferrate (III) with the aforementioned metal salt is deposited in the receding parts of micropores of an anodic oxide coating, with the result that the aluminum or aluminum alloy material is endowed with a durable color.
摘要翻译：对铝或铝合金材料进行阳极氧化，然后在含有六氰基铁酸盐（II）或六氰基铁酸盐（III）的浴中进行电泳处理，随后在包含至少一种选择的金属盐的浴中浸渍处理从由Fe，Ni，Co，Cu，Zn，Cd，Ba，Tl和Mg的盐组成的组中选出的至少一种电解质和选自硫酸钠，硫酸钾，氯化钠和氯化钾的至少一种电解质。因此，通过上述六氰基铁酸盐（II）或六氰基铁酸盐（III）与上述金属盐的反应形成的着色化合物沉积在阳极氧化物涂层的微孔的后退部分中，结果是铝或铝合金材料具有耐用的颜色。

6. 发明授权

US5585189A Pigment dispersion composition 失效
标题翻译：颜料分散体组成
公开(公告)号：US5585189A
公开(公告)日：1996-12-17
申请号：US451152
申请日：1995-05-26
申请人： Hiroshi Inoue , Shigeyasu Inoue , Seishiro Ito
发明人： Hiroshi Inoue , Shigeyasu Inoue , Seishiro Ito
IPC分类号： B05D5/06 , B05D7/14 , C09B67/20 , C09D17/00 , C25D11/18 , B32B15/08 , B32B27/00 , C08K5/47 , C09B67/50 , C23C14/14
CPC分类号： B05D7/14 , C09B67/0066 , C09D17/001 , C25D11/18 , B05D5/06 , Y10T428/31692 , Y10T428/31699
摘要： The present invention discloses a pigment dispersion composition for depositing a multiplicity of pores existing in anodic oxide films formed on a surface of an aluminum or aluminum alloy material by way of electrophoresis for coloration, the pores being preliminarily enlarged to have a diameter of 50 nm to 250 nm. The pigment dispersion composition comprises water, a pigment dispersant and a pigment. The pigment dispersed in the pigment dispersion composition has a median particle size of not greater than 250 nm in a particle-size distribution thereof with not greater than 30% of the pigment particles being impassable through a sieve having a mesh size of 300 nm. The pigment dispersion composition is useful for coloration of the anodic oxide films, and has excellent repeated-coloration characteristics.
摘要翻译：本发明公开了一种颜料分散组合物，用于通过电泳沉积形成在铝或铝合金材料的表面上的阳极氧化膜中存在的多个孔进行着色，预先扩大孔直径为50nm至 250 nm。颜料分散体组合物包含水，颜料分散剂和颜料。分散在颜料分散组合物中的颜料的粒度分布中的中值粒径不大于250nm，不大于30％的颜料颗粒通过网孔大小为300nm的筛子不能通过。颜料分散体组合物可用于阳极氧化膜的着色，并且具有优异的重复着色特性。

7. 发明授权

US5334297A Method for production of colored article of aluminum or aluminum alloy 失效
标题翻译：铝或铝合金彩色制品生产方法
公开(公告)号：US5334297A
公开(公告)日：1994-08-02
申请号：US119559
申请日：1993-09-13
申请人： Norio Nakada , Hideo Fukui , Hatsuo Hirono , Seishiro Ito
发明人： Norio Nakada , Hideo Fukui , Hatsuo Hirono , Seishiro Ito
IPC分类号： C25D11/04 , C25D11/20 , C25D11/22 , C25D13/04
CPC分类号： C25D11/22 , B60N2/4817 , B60N2/4847
摘要： A fast and brightly colored oxide film of aluminum which excels in durability and allows no separation of pigment is produced by using an aqueous dispersion of an organic pigment or carbon black finely divided to a size in the range between 3 and 150 nm, forming on a surface of an aluminum member an anodic oxide film containing pores larger in diameter than the ordinary pores, and causing the organic pigment or carbon black to migrate and deposit in the pores of the oxide film by means of electrophoresis. The formation of the anodic oxide film containing the pores larger in diameter than the ordinary pores is accomplished in the first method by subjecting the aluminum member to anodic oxidation at a high voltage in an aqueous solution of acid. In the second method, the anodic oxide film is subjected either to a treatment of immersion in an aqueous solution of at least one acid selected from among phosphoric acid, sulfuric acid, oxalic acid, and sulfamic acid or to a combination treatment of immersion and AC electrolysis repeated in a prescribed number of cycles in the solution, to enlarge the pores in the anodic oxide film.
摘要翻译：通过使用细分为3〜150nm范围内的有机颜料或炭黑的水性分散体，制造耐久性优异且不会分离颜料的快速且明亮的铝氧化膜，形成在铝构件的表面是含有直径大于普通孔的孔的阳极氧化膜，并且通过电泳使有机颜料或炭黑迁移并沉积在氧化膜的孔中。在第一种方法中，通过使铝构件在酸性水溶液中以高电压进行阳极氧化，实现了直径大于普通孔的阳极氧化膜的形成。在第二种方法中，将阳极氧化膜进行浸渍在选自磷酸，硫酸，草酸，氨基磺酸中的至少一种酸的水溶液中，或浸渍和AC的组合处理在溶液中以规定数量的循环重复电解，以扩大阳极氧化膜中的孔。

8. 发明授权

US06200446B1 Electrophoretic coloring composition 失效
标题翻译：电泳着色组合物
公开(公告)号：US06200446B1
公开(公告)日：2001-03-13
申请号：US08776663
申请日：1997-01-30
申请人： Hiroshi Inoue , Shigeyasu Inoue , Seishiro Ito
发明人： Hiroshi Inoue , Shigeyasu Inoue , Seishiro Ito
IPC分类号： C25D1300
CPC分类号： C25D11/22 , C25D11/18 , Y10T428/31678
摘要： A pigment dispersion composition for fill-in coloration of an aluminum or aluminum alloy oxide film is provided, which comprises at least a pigment, a pigment dispersant, a water-soluble organic solvent, water, and a water-soluble amine and/or a derivative thereof. Pigment particles of the pigment dispersion composition are filled in micropores of the aluminum oxide film to a great depth, so that a vivid color film having excellent weatherability and fastness can be provided. In addition, the composition offers a high adaptability for repetitive coloration, and allows pigment deposited on the film surface other than in the micropores to be washed away by simple immersion in still water or running water.
摘要翻译：提供一种用于铝或铝合金氧化物膜的填色着色的颜料分散组合物，其至少包含颜料，颜料分散剂，水溶性有机溶剂，水和水溶性胺和/或其衍生物。颜料分散组合物的颜料颗粒被深入地填充到氧化铝膜的微孔中，从而可以提供具有优异的耐候性和耐牢度的生动的彩色膜。此外，该组合物对于重复着色提供高适应性，并且允许沉积在除了微孔之外的膜表面上的颜料通过简单地浸入静水或流水中而被冲走。

9. 发明授权

US4721740A Dispersion-improved carbon black compounded rubber composition 失效
标题翻译：分散改善的炭黑复合橡胶组合物
公开(公告)号：US4721740A
公开(公告)日：1988-01-26
申请号：US883225
申请日：1986-07-08
申请人： Michitaka Takeshita , Mitsuo Kiboku , Seishiro Ito , Tatsuhiko Ihara
发明人： Michitaka Takeshita , Mitsuo Kiboku , Seishiro Ito , Tatsuhiko Ihara
IPC分类号： C08L7/00 , B60C1/00 , C08K3/04 , C08K9/00 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L101/00 , C09C1/56 , C09C3/04
CPC分类号： C09C3/048 , C08K3/04 , C08K9/00 , C01P2006/12 , C01P2006/22 , C01P2006/90
摘要： A dispersion improved carbon black compounded rubber composition comprises a rubber component and a reinforcing carbon black in an amount of from 30 to 150 parts by weight with respect to 100 parts by weight of the rubber component. The rubber component is selected from a group consisting of a natural rubber, synthetic isoprene rubber and a mixture thereof, or a blend of this rubber component with a diene base synthetic rubber other than this rubber component. The reinforcing carbon black has a specific surface area of from 70 to 200 m.sup.2 /g when measured by a nitrogen adsorption method and a DBP value of from 80 to 130 ml/100 g, and is obtained by introducing mainly phenolic hydroxide groups into the surface of the carbon black through plasma treatment at low temperatures or by introducing carboxyl groups and the phenolic hydroxide groups thereinto through plasma treating at low temperatures and neutralizing the thus introduced acid groups.
摘要翻译：分散改善的炭黑复合橡胶组合物包含相对于100重量份橡胶组分为30至150重量份的橡胶组分和增强炭黑。橡胶组分选自天然橡胶，合成异戊二烯橡胶及其混合物，或该橡胶组分与除该橡胶组分以外的二烯基合成橡胶的共混物。当通过氮吸附法和DBP值为80-130ml / 100g测量时，增强炭黑具有70至200m 2 / g的比表面积，并且主要将酚醛氢氧化物基团引入表面的炭黑通过在低温下进行等离子体处理或通过在低温下进行等离子体处理而引入羧基和氢氧化物基团，并中和由此引入的酸基团。

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