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    • 3. 发明授权
    • Process for the isomerization of dimethylnaphthalenes
    • 二甲基萘异构化的方法
    • US4777312A
    • 1988-10-11
    • US138249
    • 1987-12-28
    • Steve T. BakasPaul T. Barger
    • Steve T. BakasPaul T. Barger
    • B01J29/22C07C5/22C07C5/27C10G45/64
    • B01J29/22C07C5/2791Y02P20/582
    • Superior isomerization performance is obtained in an isomerization process employing a catalytic composition comprising a Group VIII noble metal and a hydrogen form mordenite incorporated with alumina. The superior isomerization performance is achieved using a catalyst composition having a surface area of at least 580 m.sup.2 /g. A novel method of preparing an isomerization catalyst having a surface area of at least 580 m.sup.2 /g is characterized by contacting a formed catalytic composite with an acidic aqueous solution prior to addition of the Group VIII noble metal. The isomerization process is particularly useful in the isomerization of a dimethylnaphthalene containing feedstock into a product that contains a higher concentration of the 2,6-dimethylnaphthalene isomer than did the feedstock.
    • 在使用包含VIII族贵金属和与氧化铝结合的氢形式丝光沸石的催化组合物的异构化方法中获得了优异的异构化性能。 使用具有至少580m 2 / g的表面积的催化剂组合物来实现优异的异构化性能。 制备具有至少580m 2 / g的表面积的异构化催化剂的新方法的特征在于,在加入第VIII族贵金属之前,使形成的催化剂复合物与酸性水溶液接触。 异构化方法特别可用于将含二甲基萘的原料异构化成含有比原料更高浓度的2,6-二甲基萘异构体的产物。
    • 4. 发明授权
    • Alkylation/transalkylation process
    • 烷基化/烷基转移法
    • US4870222A
    • 1989-09-26
    • US266040
    • 1988-11-02
    • Steve T. BakasPaul T. Barger
    • Steve T. BakasPaul T. Barger
    • B01J29/22C07C5/22C07C5/27C10G45/64
    • B01J29/22C07C5/2791Y02P20/582
    • A process for the production of a monoalkylated aromatic compound which minimizes the production of undesirable alkylating agent oligomers, while producing monoalkylaromatics in high yields. The process entails the combination of an alkylation reaction zone, a separations zone, and a transalkylation reaction zone wherein the alkylation catalyst and transalkylation catalyst are dissimilar and where the alkylation catalyst is comprised of noncrystaline silica-alumina material and the transalkylation catalyst is comprised of an acid-modified crystalline aluminosilicate material that is characterized as having a surface area of at least 580 m.sup.2 /g following acid washing after catalyst particle formulation.
    • 一种制备单烷基化芳族化合物的方法,其使产生不需要的烷基化剂低聚物的产率最小化,同时以高产率制备单烷基芳族化合物。 该方法需要烷基化反应区,分离区和烷基转移反应区的组合,其中烷基化催化剂和烷基转移催化剂是不相似的,其中烷基化催化剂由非晶质二氧化硅 - 氧化铝材料组成,并且烷基转移催化剂由 酸改性的结晶硅铝酸盐材料,其特征在于在催化剂颗粒配制后酸洗后具有至少580m 2 / g的表面积。