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1. 发明授权

US06638679B2 Photosensitive compositions having mixtures of alkoxy and non-alkoxy diazonium salt containing compounds 失效
标题翻译：具有含烷氧基和非烷氧基重氮盐的化合物的混合物的光敏组合物
公开(公告)号：US06638679B2
公开(公告)日：2003-10-28
申请号：US09904205
申请日：2001-07-12
申请人： Stephan J. Platzer , Maria T. Sypek , Paul Perron , Harald Baumann , Melinda Alden
发明人： Stephan J. Platzer , Maria T. Sypek , Paul Perron , Harald Baumann , Melinda Alden
IPC分类号： G03F7021
CPC分类号： G03F7/016 , G03F7/021 , G03F7/0215 , G03F7/0217
摘要： The present invention includes an imageable element, which can be: (a) an imageable element comprising an imaging layer which comprises: an aromatic diazonium salt containing compound having an alkoxy substituent and an aromatic diazonium salt containing compound free of an alkoxy substituent; a polyvinyl acetal binder; and a sheet substrate; or (b) an imageable element comprising an imaging layer which comprises: an aromatic diazonium salt containing compound having an alkoxy substituent and an aromatic diazonium salt containing compound free of an alkoxy substituent; and a sheet substrate. The imaging layer includes a total aromatic diazonium salt containing compound content of at least 10 weight percent. The molar ratio of the aromatic diazonium salt containing compound having an alkoxy substituent to the aromatic diazonium salt containing compound that is free of an alkoxy substituent is from about 1.0:1 to 70:1. Upon imagewise exposure and development, an imaged element is obtained, which is mounted on a dry printing press containing lithographic ink and used to produce printed stock.
摘要翻译：本发明包括可成像元件，其可以是：（a）包含成像层的可成像元件，其包含：含有烷氧基取代基的芳族重氮盐盐化合物和不含烷氧基取代基的含芳族重氮盐的化合物; 聚乙烯醇缩醛粘合剂; 和片基材; 或（b）包含成像层的可成像元件，其包含：含有烷氧基取代基的芳族重氮盐盐化合物和不含烷氧基取代基的含芳族重氮盐盐化合物; 和片状基材。成像层包括含有至少10重量％的化合物含量的总芳族重氮盐。具有烷氧基取代基的含芳族重氮盐的化合物与不含烷氧基取代基的含芳族重氮盐化合物的摩尔比为约1.0:1至70:1。在成像曝光和显影时，获得成像元件，其安装在含有平版印刷油墨的干式印刷机上并用于生产印刷原料。

2. 发明授权

US06861196B2 Photosensitive compositions having mixtures of alkoxy and non-alkoxy diazonium salt containing compounds 失效
标题翻译：具有含烷氧基和非烷氧基重氮盐的化合物的混合物的光敏组合物
公开(公告)号：US06861196B2
公开(公告)日：2005-03-01
申请号：US10664179
申请日：2003-09-17
申请人： Stephan J. Platzer , Maria T. Sypek , Paul Perron , Harald Baumann , Melinda Alden
发明人： Stephan J. Platzer , Maria T. Sypek , Paul Perron , Harald Baumann , Melinda Alden
IPC分类号： G03F7/016 , G03F7/021 , G03F7/30
CPC分类号： G03F7/016 , G03F7/021 , G03F7/0215 , G03F7/0217
摘要： The present invention includes an imageable element, which can be: (a) an imageable element comprising an imaging layer which comprises: an aromatic diazonium salt containing compound having an alkoxy substituent and an aromatic diazonium salt containing compound free of an alkoxy substituent; a polyvinyl acetal binder; and a sheet substrate; or (b) an imageable element comprising an imaging layer which comprises: an aromatic diazonium salt containing compound having an alkoxy substituent and an aromatic diazonium salt containing compound free of an alkoxy substituent; and a sheet substrate. The imaging layer includes a total aromatic diazonium salt containing compound content of at least 10 weight percent. The molar ratio of the aromatic diazonium salt containing compound having an alkoxy substituent to the aromatic diazonium salt containing compound that is free of an alkoxy substituent is from about 1.0:1 to 70:1. Upon imagewise exposure and development, an imaged element is obtained.
摘要翻译：本发明包括可成像元件，其可以是：（a）包含成像层的可成像元件，其包含：含有烷氧基取代基的芳族重氮盐盐化合物和不含烷氧基取代基的含芳族重氮盐的化合物; 聚乙烯醇缩醛粘合剂; 和片基材; 或（b）包含成像层的可成像元件，其包含：含有烷氧基取代基的芳族重氮盐盐化合物和不含烷氧基取代基的含芳族重氮盐盐化合物; 和片状基材。成像层包括含有至少10重量％的化合物含量的总芳族重氮盐。具有烷氧基取代基的含芳族重氮盐的化合物与不含烷氧基取代基的含芳族重氮盐化合物的摩尔比为约1.0:1至70:1。在成像曝光和显影时，获得成像元件。

3. 发明授权

US4886731A Multilayer photopolymeric printing plates with photoreactive diazo compounds and photopolymerizable compositions 失效
标题翻译：具有光反应性重氮化合物和可光聚合组合物的多层光聚合印刷版
公开(公告)号：US4886731A
公开(公告)日：1989-12-12
申请号：US351262
申请日：1989-05-10
申请人： Maria T. Sypek , Thomas P. Rorke
发明人： Maria T. Sypek , Thomas P. Rorke
IPC分类号： G03F7/095 , G03C1/52 , G03C1/60 , G03C1/70 , G03C1/94
CPC分类号： G03F7/0955
摘要： Photopolymeric printing plates wherein an electrochemically etched, anodized and silicated aluminum plate has a plurality of coatings applied thereon and wherein at least one of the coatings include a solvent soluble diazo therein.
摘要翻译：光聚合印刷版，其中电化学蚀刻的阳极氧化和硅酸盐的铝板具有涂覆在其上的多个涂层，并且其中至少一个涂层包括溶剂可溶的重氮。

4. 发明授权

US5543262A Benzanthrone polymerization gate in photopolymerizable compositions 失效
标题翻译：可光聚合组合物中的苯甲酮聚合门
公开(公告)号：US5543262A
公开(公告)日：1996-08-06
申请号：US393969
申请日：1995-02-24
申请人： Maria T. Sypek , John R. Delude , Paul A. Perron
发明人： Maria T. Sypek , John R. Delude , Paul A. Perron
IPC分类号： G03F7/004 , C08F2/50 , G03F7/00 , G03F7/021 , G03F7/027 , G03F7/038 , G03F7/09 , G03F7/016 , G03F7/30
CPC分类号： G03F7/091 , Y10S430/117 , Y10S430/118 , Y10S430/119 , Y10S430/12 , Y10S430/121 , Y10S430/122 , Y10S430/123 , Y10S430/124
摘要： A light sensitive composition which is capable of photopolymerization which includes a photopolymerizable compound a free radical generating component and a benzanthrone or substituted benzanthrone which substantially prevents photopolymerization when the light sensitive composition is exposed to actinic radiation below a threshold amount but permits photopolymerization when the light sensitive composition is exposed to actinic radiation above a threshold amount. This achieves a gate effect which eliminates or decreases unwanted partial exposure in the nonimage areas and hence improves reproduction quality.
摘要翻译：能够光聚合的光敏组合物，其包含可光聚合化合物，自由基产生组分和苯醌或取代苯醌，当光敏组合物暴露于低于阈值量的光化辐射时，其基本上防止光聚合，但当光敏组合物暴露于高于阈值量的光化辐射。这实现了在非图像区域中消除或减少不期望的部分曝光并因此提高再现质量的栅极效应。

5. 发明申请

US20110020750A1 LITHOGRAPHIC IMAGING AND PRINTING WITH WET, POSITIVE-WORKING PRINTING MEMBERS 审中-公开
标题翻译：印刷成像和印刷，印刷工作印刷会员
公开(公告)号：US20110020750A1
公开(公告)日：2011-01-27
申请号：US12508690
申请日：2009-07-24
申请人： Maria T. Sypek , Brian Smith
发明人： Maria T. Sypek , Brian Smith
IPC分类号： G03F7/039 , G03F7/004 , G03F7/20
CPC分类号： B41C1/1008 , B41C2210/02 , B41C2210/08 , B41C2210/24 , B41C2210/262 , B41C2210/266
摘要： Embodiments of the present invention involve printing members that avoid ablation imaging mechanisms and, as a result, crosslinked topmost layers. Topmost layers as described herein exhibit good thermal stability and durability during printing, but can be cleaned (and thereby removed from unimaged areas) with water or aqueous cleaning fluids following imaging. It is found, in some embodiments, that the viability of certain topmost layers can be critically dependent on the nature of the underlying substrate, e.g., in terms of texture and/or surface volume.
摘要翻译：本发明的实施例涉及避免消融成像机构的打印部件，结果是交联的最上层。如本文所述的最上层在印刷过程中表现出良好的热稳定性和耐久性，但是可以在成像后用水或含水清洁液清洁（从而从非成像区域除去）。在一些实施方案中，发现某些最顶层的活力可能严重依赖于下层基质的性质，例如在织构和/或表面体积方面。

6. 发明授权

US5286594A Photographic elements utilizing a single photosensitive layer containing a photopolymerizable compound, photoinitiator, diazonium compound and barrier material encapsulated pigment particles 失效
标题翻译：使用含有可光聚合化合物，光引发剂，重氮化合物和阻隔材料的单一感光层的照相元件包封的颜料颗粒
公开(公告)号：US5286594A
公开(公告)日：1994-02-15
申请号：US897319
申请日：1992-06-11
申请人： Maria T. Sypek , Paul A. Perron , Gary V. Grosclaude
发明人： Maria T. Sypek , Paul A. Perron , Gary V. Grosclaude
IPC分类号： B41N1/04 , B41N3/03 , G03F7/00 , G03F7/004 , G03F7/021 , G03F7/027 , G03F7/028 , G03F7/038 , G03F7/095 , G03F7/105 , G03F7/11 , G03F7/09
CPC分类号： G03F7/027 , G03F7/004 , G03F7/0955 , G03F7/105
摘要： Photopolymeric printing plates are presented wherein an electrochemically etched and anodized, silicated aluminum substrate has a single photosensitive coating thereon composed of a photopolymerizable combination which includes a photopolymerizable pigment dispersion, a photosensitive lithographic diazonium resin, multifunctional acrylate oligomer, multifunctional acrylate monomer, photopolymerizable binder and photoinitiator to yield a non-tacky, mar resistant, easily developed durable plate. In a preferred embodiment, an additional aqueous, non-photosensitive overcoat is applied over the initial coating to retard oxygen inhibition.
摘要翻译：提出了一种光电聚合印刷板，其中电化学蚀刻和阳极氧化的硅酸铝基板在其上具有由光聚合组合构成的单一感光涂层，其包含可光聚合的颜料分散体，光敏平版印刷重氮树脂，多官能丙烯酸酯低聚物，多官能丙烯酸酯单体，可光聚合的粘合剂和光引发剂产生非粘性，耐磨损，易开发的耐用板。在优选的实施方案中，在初始涂层上施加另外的水性非光敏外涂层以延缓氧的抑制。

7. 发明申请

US20170021656A1 LITHOGRAPHIC IMAGING AND PRINTING WITH NEGATIVE-WORKING PHOTORESPONSIVE PRINTING MEMBERS 审中-公开
标题翻译：具有负离子功能的打印成像的平面成像和打印
公开(公告)号：US20170021656A1
公开(公告)日：2017-01-26
申请号：US14808106
申请日：2015-07-24
申请人： Kevin Ray , Maria T. Sypek , Travis Softic , Thuan Nguyen , Michael Karp , Oren Etziony , Geula Zegnioyev
发明人： Kevin Ray , Maria T. Sypek , Travis Softic , Thuan Nguyen , Michael Karp , Oren Etziony , Geula Zegnioyev
IPC分类号： B41N1/14 , B41C1/10
CPC分类号： B41N1/14 , B41C1/1008 , B41C2210/04 , B41C2210/08 , B41C2210/24 , B41C2210/266
摘要： Negative-working, IR-sensitive printing plates utilize a radiation-sensitive composition having a component polymerizable by a free-radical mechanism, at least part of which comprises or consists essentially of a non-particulate, aliphatic urethane acrylic oligomer that is infinitely water-dilutable but not water-soluble.
摘要翻译：负性工作的IR敏感印版利用具有通过自由基机理可聚合的成分的辐射敏感组合物，其至少一部分包含或基本上由非微粒状的脂族聚氨酯丙烯酸低聚物组成，可稀释但不溶于水。

8. 发明授权

US5340681A Method for preparing photographic elements having single photosensitive layer containing photopolymerizable compound, photoinitiator, diazonium compound and barrier material encapsulated pigment particles; and negative image formation process 失效
标题翻译：制备具有含有光聚合化合物，光引发剂，重氮化合物和阻隔材料包封的颜料颗粒的单一光敏层的照相元件的方法。和负图像形成过程
公开(公告)号：US5340681A
公开(公告)日：1994-08-23
申请号：US148757
申请日：1993-11-05
申请人： Maria T. Sypek , Paul A. Perron , Gary V. Grosclaude
发明人： Maria T. Sypek , Paul A. Perron , Gary V. Grosclaude
IPC分类号： G03F7/004 , G03F7/027 , G03F7/095 , G03F7/105 , G03F7/021 , G03F7/30
CPC分类号： G03F7/004 , G03F7/027 , G03F7/0955 , G03F7/105
摘要： Photopolymeric printing plates are presented wherein and electrochemically etched and anodized, silicated aluminum substrate has a single photosensitive coating thereon composed of a photopolymerizable combination which includes a photopolymerizable pigment dispersion, a photosensitive lithographic diazonium resin, multifunctional acrylate oligomer, multifunctional acrylate monomer, photopolymerizable binder and photoinitiator to yield a non-tacky, mar resistant, easily developed durable plate. In a preferred embodiment, an additional aqueous, non-photosensitive overcoat is applied over the initial coating to retard oxygen inhibition.
摘要翻译：提供了光聚合印刷板，其中电化学蚀刻和阳极氧化，硅酸铝基板在其上具有由可光聚合的组合组成的单一感光涂层，其包含可光聚合的颜料分散体，光敏平版印刷重氮树脂，多官能丙烯酸酯低聚物，多官能丙烯酸酯单体，可光聚合的粘合剂和光引发剂产生非粘性，耐磨损，易开发的耐用板。在优选的实施方案中，在初始涂层上施加另外的水性非光敏外涂层以延缓氧的抑制。

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