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    • 3. 发明授权
    • EUV magnetic contrast lithography mask and manufacture thereof
    • EUV磁对比光刻掩模及其制造
    • US07407729B2
    • 2008-08-05
    • US10912658
    • 2004-08-05
    • Siegfried SchwarzlStefan Wurm
    • Siegfried SchwarzlStefan Wurm
    • G03F1/00
    • G03F1/84B82Y10/00B82Y40/00G03F1/24
    • An EUV Lithography mask, a fabrication method, and use method thereof is provided. A preferred embodiment comprises a substrate, a Bragg reflector disposed upon the substrate, a buffer disposed upon the Bragg reflector, and an absorber layer disposed upon the buffer. The materials in the mask have selected magnetic properties. In a preferred embodiment, the buffer is a hard magnetic material, and the absorber is a soft magnetic material. Another preferred embodiment includes a mask manufacturing method further including a mask step. In a preferred embodiment, an electron mirror microscope is used to inspect the mask by imaging its topography with respect to its magnetic properties in an applied magnetic field.
    • 提供了一种EUV平版印刷掩模,其制造方法及其使用方法。 优选实施例包括衬底,布置在衬底上的布拉格反射器,设置在布拉格反射器上的缓冲器和设置在缓冲器上的吸收层。 掩模中的材料已经选择了磁性。 在优选实施例中,缓冲器是硬磁性材料,吸收体是软磁性材料。 另一个优选实施例包括还包括掩模步骤的掩模制造方法。 在优选实施例中,电子镜显微镜用于通过在施加的磁场中相对于其磁特性对其形貌进行成像来检查掩模。
    • 5. 发明授权
    • Photosensitive coating material for a substrate and process for exposing the coated substrate
    • 用于基材的感光涂层材料和用于曝光涂覆的基材的方法
    • US07029808B2
    • 2006-04-18
    • US10673964
    • 2003-09-29
    • Jenspeter RauSiegfried SchwarzlStefan Wurm
    • Jenspeter RauSiegfried SchwarzlStefan Wurm
    • G03C5/02G03F7/20G03F7/039
    • G03F7/105Y10S430/115Y10S430/134
    • A radiation-sensitive coating material, in addition to a base polymer, has a solvent and a radiation-active substance which forms an acid on irradiation by light (including energetic electrons or ions), a fluorescent substance which alters its fluorescence property subject to a change in the acid content of its surroundings. In a process for exposing a substrate coated with the coating material at least one sensor in the exposure chamber of the exposure apparatus measures the intensity of the change in fluorescence spectrum as a function of time during the exposure operation. From the course of intensity at the time of an individual line of the fluorescence spectrum or the intensity integrated over a wavelength interval it is possible to determine the endpoint of the exposure operation by way of electronic algorithms. Deviations from experimentally determined ideal curves of the intensity course provide information on erroneous functions in the course of coating material application and exposure.
    • 除了基础聚合物之外,辐射敏感性涂层材料具有溶剂和辐射活性物质,其在光照射下(包括能量电子或离子)形成酸,荧光物质改变其荧光性质 改变其周围的酸含量。 在用涂布材料曝光的基材的曝光过程中,曝光装置的曝光室中的至少一个传感器在曝光操作期间测量作为时间的函数的荧光光谱的变化强度。 从荧光光谱的单独行的强度或在波长间隔上积分的强度的过程中,可以通过电子算法确定曝光操作的终点。 与实验确定的强度曲线的偏差提供了涂料应用和曝光过程中错误功能的信息。
    • 8. 发明授权
    • Photolithographic mask having a structure region covered by a thin protective coating of only a few atomic layers and methods for the fabrication of the mask including ALCVD to form the thin protective coating
    • 具有仅由几个原子层覆盖的薄保护涂层的结构区域的光刻掩模和用于制造掩模的方法,包括ALCVD以形成薄的保护涂层
    • US07078134B2
    • 2006-07-18
    • US10442739
    • 2003-05-21
    • Stefan WurmSiegfried Schwarzl
    • Stefan WurmSiegfried Schwarzl
    • G03F1/14G03F1/08G21K5/00
    • G21K1/062B82Y10/00B82Y40/00G03F1/24G03F1/48Y10S430/162
    • A photolithographic mask for patterning a photosensitive material, in particular on a wafer, has at least one structure region for imaging a structure on the photosensitive material, and an absorber structure for absorbing incident radiation. At least one structure region is provided and has at least one thin protective coating of only a few atomic layers made of chemically and mechanically resistive material selected from Al2O3, Ta2O5, ZrO2, and HfO2formed by atomic layer chemical vapor deposition (ALCVD) so that the protective coating constitutes a negligible alteration of nominal or critical dimensions for the structure region, and in which additional absorption or reflection losses are negligibly low. In this way, the photolithographic mask can be cleaned chemically and/or mechanically, without the structure regions being attacked and damaged by the chemical and/or mechanical cleaning media. Furthermore, a plurality of methods are possible for fabricating this photolithographic mask.
    • 用于图案化感光材料,特别是在晶片上的光刻掩模具有用于对感光材料上的结构进行成像的至少一个结构区域和用于吸收入射辐射的吸收体结构。 提供至少一个结构区域,并且具有由化学和机械电阻材料制成的仅几个原子层的至少一个薄保护涂层,其选自Al 2 O 3,Ta 通过原子层化学气相沉积(ALCVD)形成的O 2 O 5,ZrO 2 2和HfO 2 2,使得 保护涂层构成对于结构区域的标称或临界尺寸的可忽略的变化,并且附加的吸收或反射损失可忽略不计。 以这种方式,可以化学和/或机械地清洁光刻掩模,而不会使结构区域被化学和/或机械清洁介质侵蚀和损坏。 此外,制造这种光刻掩模的方法是可能的。
    • 9. 发明申请
    • Photosensitive coating material for a substrate
    • 用于基材的感光涂料
    • US20060147839A1
    • 2006-07-06
    • US11370388
    • 2006-03-06
    • Jenspeter RauSiegfried SchwarzlStefan Wurm
    • Jenspeter RauSiegfried SchwarzlStefan Wurm
    • G03C1/76
    • G03F7/105Y10S430/115Y10S430/134
    • A radiation-sensitive coating material, in addition to a base polymer, has a solvent and a radiation-active substance which forms an acid on irradiation by light (including energetic electrons or ions), a fluorescent substance which alters its fluorescence property subject to a change in the acid content of its surroundings. In a process for exposing a substrate coated with the coating material at least one sensor in the exposure chamber of the exposure apparatus measures the intensity of the change in fluorescence spectrum as a function of time during the exposure operation. From the course of intensity at the time of an individual line of the fluorescence spectrum or the intensity integrated over a wavelength interval it is possible to determine the endpoint of the exposure operation by way of electronic algorithms. Deviations from experimentally determined ideal curves of the intensity course provide information on erroneous functions in the course of coating material application and exposure.
    • 除了基础聚合物之外,辐射敏感性涂层材料具有溶剂和辐射活性物质,其在光照射下(包括能量电子或离子)形成酸,荧光物质改变其荧光性质 改变其周围的酸含量。 在用涂布材料曝光的基材的曝光过程中,曝光装置的曝光室中的至少一个传感器在曝光操作期间测量作为时间的函数的荧光光谱的变化强度。 从荧光光谱的单独行的强度或在波长间隔上积分的强度的过程中,可以通过电子算法确定曝光操作的终点。 与实验确定的强度曲线的偏差提供了涂料应用和曝光过程中错误功能的信息。
    • 10. 发明授权
    • Passivation of multi-layer mirror for extreme ultraviolet lithography
    • 钝化多层镜面进行极紫外光刻
    • US07859648B2
    • 2010-12-28
    • US12624263
    • 2009-11-23
    • Siegfried SchwarzlStefan Wurm
    • Siegfried SchwarzlStefan Wurm
    • G02B1/10G02B5/08
    • G03F7/70958B82Y10/00G03F7/70316G03F7/70916G21K1/062Y10T428/12667
    • A reflector structure suitable for extreme ultraviolet lithography (EUVL) is provided. The structure comprises a substrate having a multi-layer reflector. A capping layer is formed over the multi-layer reflector to prevent oxidation. In an embodiment, the capping layer is formed of an inert oxide, such as Al2O3, HfO2, ZrO2, Ta2O5, Y2O3-stabilized ZrO2, or the like. The capping layer may be formed by reactive sputtering in an oxygen environment, by non-reactive sputtering wherein the materials are sputtered directly from the respective oxide targets, by non-reactive sputtering of the metallic layer followed by full or partial oxidation (e.g., by natural oxidation, by oxidation in oxygen-containing plasmas, by oxidation in ozone (O3), or the like), by atomic level deposition (e.g., ALCVD), or the like.
    • 提供了适用于极紫外光刻(EUVL)的反射器结构。 该结构包括具有多层反射器的基板。 在多层反射器上形成覆盖层以防止氧化。 在一个实施方案中,封盖层由惰性氧化物如Al 2 O 3,HfO 2,ZrO 2,Ta 2 O 5,Y 2 O 3稳定的ZrO 2等形成。 覆盖层可以通过在氧环境中的反应溅射,通过非反应性溅射形成,其中材料直接从相应的氧化物靶溅射,通过金属层的非反应性溅射,然后进行全部或部分氧化(例如,通过 通过在含氧等离子体中氧化,通过氧化在臭氧(O3)等中),通过原子级沉积(例如,ALCVD)等进行自然氧化。