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1. 发明授权

US4613691A Preparation of amino acids from unsaturated hydantoins 失效
标题翻译：从不饱和乙内酰脲制备氨基酸
公开(公告)号：US4613691A
公开(公告)日：1986-09-23
申请号：US751581
申请日：1985-07-08
申请人： Stanley B. Mirviss , Mark W. Empie
发明人： Stanley B. Mirviss , Mark W. Empie
IPC分类号： C12P13/04 , C12P13/22 , C12P41/00 , C07C99/08
CPC分类号： C12P13/222 , C12P13/04 , C12P41/00
摘要： Amino acids can be easily prepared by reducing unsaturated hydantoins to the corresponding saturated hydantoins by hydrogenating the unsaturated hydantoin using either Raney Nickel catalyst in the presence of more than a stoichiometric amount of caustic or by using zinc and hydrochloric acid followed by hydrolyzing the resultant composition with at least 3 molar equivalents of an alkali metal hydroxide to produce a racemate of an alpha amino acid. The amino acid in suitable derivative form can then be resolved particularly using a two-phase solvent system. The residual isomer of the amino acid remaining after the resolution process can then be racemized using either pyridoxal-5-phosphate or an aliphatic acid in combination with an aldehyde or a ketone. By these procedures, it is possible to obtain high yields of amino acids.
摘要翻译：氨基酸可以容易地通过将不饱和乙内酰脲还原成相应的饱和乙内酰脲，通过使用阮内镍催化剂在不超过化学计量的苛性碱存在下氢化不饱和乙内酰脲，或者通过使用锌和盐酸，然后水解所得组合物，至少3摩尔当量的碱金属氢氧化物以产生α氨基酸的外消旋体。然后可以使用两相溶剂系统特别地分解合适的衍生物形式的氨基酸。然后可以使用吡哆醛-5-磷酸或与醛或酮的组合的脂族酸，将拆分过程后残留的氨基酸的残余异构体外消旋化。通过这些方法，可以获得高产率的氨基酸。

2. 发明授权

US5939346A Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group 失效
标题翻译：催化剂体系包含含有吸电子基团的芳氧基亚氨基烷氧基
公开(公告)号：US5939346A
公开(公告)日：1999-08-17
申请号：US132736
申请日：1993-10-06
申请人： Tobin J. Marks , Xinmin Yang , Stanley B. Mirviss
发明人： Tobin J. Marks , Xinmin Yang , Stanley B. Mirviss
IPC分类号： B01J31/02 , B01J31/14 , B01J31/22 , C07F5/06 , C08F4/64 , C08F10/00
CPC分类号： B01J31/143 , B01J31/0214 , C07F5/068 , C08F10/00 , B01J2531/48 , B01J31/2295
摘要： Aryloxyaluminoxanes containing the unit ##STR1## where R is unsubstituted or substituted aryl, such as phenyl or naphthyl, are useful as a cocatalysts in Ziegler-Natta and Kaminsky-type olefin polymerization catalysts. They can be formed by reaction of a source of water with an organoaluminum compound containing the desired aryloxy moiety or by reaction of preformed aluminoxane with an organic compound, such as a phenol, containing such a moiety.
摘要翻译：含有R为未取代或取代的芳基（如苯基或萘基）的单元的芳氧基亚氨基烷氧基可用作齐格勒 - 纳塔和卡明斯基型烯烃聚合催化剂中的助催化剂。它们可以通过水源与含有所需芳氧基部分的有机铝化合物的反应或通过预形成的铝氧烷与含有这种部分的有机化合物如苯酚的反应形成。

3. 发明授权

US4351780A Process for preparing isopropylphenyl/phenyl phosphate 失效
标题翻译：制备异丙基苯基/苯基磷酸酯的方法
公开(公告)号：US4351780A
公开(公告)日：1982-09-28
申请号：US214553
申请日：1980-12-09
申请人： Silvio L. Giolito , Stanley B. Mirviss
发明人： Silvio L. Giolito , Stanley B. Mirviss
IPC分类号： C07F9/12 , C07F9/09
CPC分类号： C07F9/12
摘要： Monoisopropylphenyl/phenyl phosphate containing mixtures are prepared by, (1) alkylating phenol with propylene to C.sub.3 /.phi. ratio of less than 0.30 with a p-toluene sulfonic acid catalyst, (2) removing unreacted phenol as distillate to yield a distilland having a C.sub.3 /.phi. ratio above 0.3 and thereafter, (3) phosphorylating the distilland to yield a triaryl phosphate mixture having a reduced 2,6-diisopropylphenyl phosphate content.
摘要翻译：通过以下方法制备含有单异丙基苯基/苯基磷酸酯的混合物：（1）用对甲苯磺酸催化剂将丙烯与C3 / phi比小于0.30的苯酚烷基化，（2）除去作为馏出物的未反应的苯酚，得到具有C3 / phi比高于0.3，此后，（3）使蒸馏物磷酸化，得到具有还原的2,6-二异丙基苯基磷酸酯含量的磷酸三芳基酯混合物。

4. 发明授权

US5001249A Catalytic process for preparing dialkyl phosphorodithioic acids 失效
标题翻译：用于制备二烷基二硫代磷酸的催化方法
公开(公告)号：US5001249A
公开(公告)日：1991-03-19
申请号：US162989
申请日：1988-03-16
申请人： Stanley B. Mirviss
发明人： Stanley B. Mirviss
IPC分类号： C07B61/00 , B01J31/02 , C07F9/165 , C07F9/17
CPC分类号： C07F9/165
摘要： The formation of dialkyl phosphorodithioic acids by reacting phosphorus pentasulfide with an alcohol is catalyzed by using an organosulfur halide catalyst for the reaction. Representative classes of organosulfur halide catalysts include the sulfonium halides, the sulfoxonium halides, and polymeric sulfur halide materials.

5. 发明授权

US4766250A Racemization catalyst for amino acids 失效
标题翻译：用于氨基酸的外消旋化催化剂
公开(公告)号：US4766250A
公开(公告)日：1988-08-23
申请号：US53906
申请日：1987-07-10
申请人： Stanley B. Mirviss
发明人： Stanley B. Mirviss
IPC分类号： C07B57/00 , C07C45/64 , C07C47/575 , C08L27/00
CPC分类号： C07B57/00
摘要： There is disclosed a process for the racemization of amino acids and derivatives thereof. The racemization process of the present invention uses an aromatic aldehyde-containing polymer made from the reaction of a hydroxyaromatic aldehyde with a chloromethylated vinylbenzene polymer under reaction conditions to form an aromatic aldehyde-containing polymer wherein the aldehydic moiety is linked to the polymer through an ether linkage. There is also disclosed a process for the production of the racemization catalyst. Another embodiment of the invention comprises a process for the promotion of the racemization reaction wherein a tertiary amine-containing resin is used as a promoting agent.
摘要翻译：公开了氨基酸及其衍生物的外消旋化的方法。本发明的外消旋化方法使用在反应条件下由羟基芳族醛与氯甲基化的乙烯基苯聚合物反应制备的含芳族醛的聚合物，形成含芳族醛的聚合物，其中醛部分通过醚连接到聚合物上连锁。还公开了外消旋化催化剂的制造方法。本发明的另一个实施方案包括促进外消旋反应的方法，其中使用含叔胺的树脂作为促进剂。

6. 发明授权

US4103096A Preparation of meta-alkylphenols 失效
标题翻译：亚甲基苯酚的制备
公开(公告)号：US4103096A
公开(公告)日：1978-07-25
申请号：US841626
申请日：1977-10-13
申请人： Silvio L. Giolito , Stanley B. Mirviss
发明人： Silvio L. Giolito , Stanley B. Mirviss
IPC分类号： C07C37/00 , C07C39/06
CPC分类号： C07C37/00
摘要： Meta-alkylphenols are prepared by the isomerization of nonmeta-alkylphenols in the presence of trifluoromethane sulfonic acid. Ortho-isomer-containing alkylphenols are isomerized to increase their meta-isomer content and reduce their ortho-isomer content.

7. 发明授权

US3931365A Color improvement of phosphate esters 失效
标题翻译：磷酸酯的颜色改善
公开(公告)号：US3931365A
公开(公告)日：1976-01-06
申请号：US535887
申请日：1974-12-23
申请人： Silvio L. Giolito , Stanley B. Mirviss
发明人： Silvio L. Giolito , Stanley B. Mirviss
IPC分类号： C07F9/02 , C07F9/12 , C08K5/523
CPC分类号： C08K5/523 , C07F9/025 , C07F9/12
摘要： A method for decolorizing and stabilizing alkylphenyl esters of phosphoric acid which comprises contacting the esters with an effective amount of a water soluble salt of a reduced form of sulfur for a sufficient length of time to decolorize and stabilize the esters against subsequent color formation.
摘要翻译：一种使磷酸烷基苯基酯脱色和稳定的方法，该方法包括使酯与有效量的还原硫形式的水溶性盐接触足够长的时间以使酯脱色并稳定酯以防止随后的颜色形成。

8. 发明授权

US5391793A Aryloxyaluminoxanes 失效
标题翻译：芳氧基乳酰胺
公开(公告)号：US5391793A
公开(公告)日：1995-02-21
申请号：US969920
申请日：1992-11-02
申请人： Tobin J. Marks , Xinmin Yang , Stanley B. Mirviss
发明人： Tobin J. Marks , Xinmin Yang , Stanley B. Mirviss
IPC分类号： B01J31/02 , B01J31/14 , B01J31/22 , C07F5/06 , C08F10/00
CPC分类号： B01J31/143 , B01J31/0214 , C07F5/068 , C08F10/00 , B01J2531/48 , B01J31/2295
摘要： Aryloxyaluminoxanes containing the unit ##STR1## where R is unsubstituted or substituted aryl, such as phenyl or naphthyl, are useful as a cocatalysts in Ziegler-Natta and Kaminsky-type olefin polymerization catalysts. They can be formed by reaction of a source of water with an organoaluminum compound containing the desired aryloxy moiety or by reaction of preformed aluminoxane with an organic compound, such as a phenol, containing such a moiety.
摘要翻译：其中R是未取代的或取代的芳基（如苯基或萘基）的单元“IMAGE”，可用作Ziegler-Natta和Kaminsky型烯烃聚合催化剂中的助催化剂。它们可以通过水源与含有所需芳氧基部分的有机铝化合物的反应或通过预形成的铝氧烷与含有这种部分的有机化合物如苯酚的反应形成。

9. 发明授权

US4845271A Process for the preparation of omega-unsaturated carboxylic acids 失效
标题翻译：制备ω-不饱和羧酸的方法
公开(公告)号：US4845271A
公开(公告)日：1989-07-04
申请号：US7041
申请日：1987-01-27
申请人： Stanley B. Mirviss
发明人： Stanley B. Mirviss
IPC分类号： C07C17/16 , C07C51/347 , C07C51/353
CPC分类号： C07C51/347 , C07C17/16 , C07C51/353
摘要： An improved method for the synthesis of omega-unsaturated carboxylic acids is disclosed which precludes double bond migration or hydrogenation in order to prepare a high purity product necessary for high resolution in forming a resist by electron beam microlithography. This result can be obtained by a coupling reaction between a Grignard reagent of an unsaturated organochloride compound as defined in the application with a halo magnesium salt of a long chain organic acid.
摘要翻译：公开了一种用于合成ω-不饱和羧酸的改进方法，其排除双键迁移或氢化，以便通过电子束微光刻法制备高分辨率形成抗蚀剂所需的高纯度产物。该结果可以通过本申请中定义的不饱和有机氯化物化合物的格氏试剂与长链有机酸的卤代镁盐的偶联反应获得。

10. 发明授权

US4582903A Synthesis of unsaturated hydantoins with an inexpensive catalyst 失效
标题翻译：用廉价的催化剂合成不饱和乙内酰脲
公开(公告)号：US4582903A
公开(公告)日：1986-04-15
申请号：US641888
申请日：1984-08-17
申请人： Stanley B. Mirviss
发明人： Stanley B. Mirviss
IPC分类号： C07D233/96 , C07D413/10
CPC分类号： C07D233/96
摘要： Alkylidene or arylidene substituted hydantoins are produced by condensation of an aromatic or aliphatic aldehyde with hydantoin in the presence of at least one basic salt of an inorganic acid. The desired products are obtained in high yields.
摘要翻译：亚烷基或亚芳基取代的乙内酰脲通过在无机酸的至少一种碱性盐的存在下将芳族或脂族醛与乙内酰脲缩合来制备。以高产率获得所需的产品。

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