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1. 发明授权

US5322829A Resid hydrotreating catalyst and process 失效
标题翻译：残渣加氢处理催化剂及工艺
公开(公告)号：US5322829A
公开(公告)日：1994-06-21
申请号：US31656
申请日：1993-03-15
申请人： David C. Artes , Simon G. Kukes
发明人： David C. Artes , Simon G. Kukes
IPC分类号： B01J23/755 , B01J23/85 , B01J35/10 , C10G45/08 , B01J23/74 , B01J23/28 , B01J23/88
CPC分类号： C10G45/08 , B01J23/755 , B01J23/85 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/108
摘要： A catalyst and process are disclosed for upgrading heavy feedstocks such as resid. The catalyst comprises a porous inorganic oxide support having an incremental pore volume maximum at a pore radius greater than 50 Angstroms bearing between 0.1 to 5.0 weight percent nickel and having at least 0.4 cc/g of pores having a radius less than 125 Angstroms. An ebullated bed hydroconversion process employing the catalyst also is disclosed.
摘要翻译：公开了一种催化剂和方法，用于改质重质原料如渣油。该催化剂包括多孔无机氧化物载体，其具有在孔半径大于50埃的0.1至5.0重量％的镍之间并具有至少0.4cc / g半径小于125埃的孔的增量孔体积最大值。还公开了采用催化剂的沸腾床加氢转化方法。

2. 发明授权

US4885080A Process for demetallizing and desulfurizing heavy crude oil 失效
标题翻译：重质原油脱金属脱硫工艺
公开(公告)号：US4885080A
公开(公告)日：1989-12-05
申请号：US198767
申请日：1988-05-25
申请人： Ronald E. Brown , Robert J. Hogan , Daniel M. Coombs , Simon G. Kukes
发明人： Ronald E. Brown , Robert J. Hogan , Daniel M. Coombs , Simon G. Kukes
IPC分类号： C10G65/16
CPC分类号： C10G65/16
摘要： A heavy crude oil is fractionated into at least three liquid fractions which include a distillate fraction boiling in the 400.degree. F.-650.degree. F. range and a 650.degree. F.+ boiling range residuum. The distillate cut is hydrodesulfurized and the residuum is hydrodemetallized. The cuts thus hydrotreated, and at least a part of the third liquid fraction, are then combined to form an upgraded synthetic crude oil of relatively low sulfur content and relatively low vanadium and nickel content.
摘要翻译：重质原油分馏成至少三种液体馏分，其中包括在400°F-650°F范围内沸腾的馏出物馏分和650°F +沸点残渣。蒸馏馏分加氢脱硫，渣油加氢脱金属。然后将如此加氢处理的切口和至少一部分第三液体馏分组合以形成相对低的硫含量和相对低的钒和镍含量的升级的合成原油。

3. 发明授权

US4831004A Impregnated alumina-containing material 失效
标题翻译：浸渍的含氧化铝的材料
公开(公告)号：US4831004A
公开(公告)日：1989-05-16
申请号：US212843
申请日：1988-06-29
申请人： Karlheinz K. Brandes , Simon G. Kukes , Thomas Davis
发明人： Karlheinz K. Brandes , Simon G. Kukes , Thomas Davis
IPC分类号： B01J37/20 , C10G45/04
CPC分类号： C10G45/04 , B01J37/20
摘要： A composition of matter is prepared by a process comprising the steps of impregnating a alumina-containing support material with a thiosulfate (preferably ammonium thiosulfate), drying the thus impregnated material, impregnating the dried material with a transition metal compound, drying and calcining the transition metal impregnated material. This composition of matter is used as catalyst composition for hydrogenating unsaturated hydrocarbon compounds, and as catalyst composition for hydrotreating hydrocarbon-containing feed streams (in particular heavy oils) which contain metal and sulfur compounds as impurities.In another embodiment, a hydrotreating process comprises contacting hydrocarbon-containing feed stream (in particular heavy oils), which contains compounds of sulfur and metals, in the presence of a fixed catalyst bed comprising (X) at least one layer of impregnated substantially spherical alumina-containing particles, which have been prepared by a process comprising the steps of impregnating a specific starting material with (NH.sub.4).sub.2 S.sub.2 O.sub.3 and then heating the thus impregnated material at about 500.degree.-900.degree. C. for improved crush strength retention. In a preferred embodiment, the fixed catalyst bed further comprises at least one layer (Y) of catalyst particles comprising a refractory inorganic carrier and at least one hydrogenation promoter. A composition of matter comprising the impregnated, spherical alumina-containing particles described above, and a process for preparing them are also provided.
摘要翻译：通过包括以下步骤的方法制备物质组合物，所述方法包括用硫代硫酸盐（优选硫代硫酸铵）浸渍含氧化铝的载体材料，干燥如此浸渍的材料，用过渡金属化合物浸渍干燥的材料，干燥和煅烧过渡金属浸渍材料。该物质组合物用作用于氢化不饱和烃化合物的催化剂组合物，以及用作加氢处理含有金属和硫化合物作为杂质的含烃进料流（特别是重油）的催化剂组合物。在另一个实施方案中，加氢处理方法包括在固定的催化剂床存在下使包含硫和金属化合物的含烃进料流（特别是重油）与含有（X）至少一层浸渍的基本上为球形的氧化铝其通过包括以下步骤制备的方法制备，所述方法包括用（NH 4）2 S 2 O 3浸渍特定原料，然后在约500-900℃加热如此浸渍的材料，以改善压碎强度保持性。在优选的实施方案中，固定催化剂床还包含至少一层包含耐火无机载体和至少一种氢化促进剂的催化剂颗粒层（Y）。还提供了包含上述浸渍的含球形氧化铝颗粒的物质组合物及其制备方法。

4. 发明授权

US4828683A Hydrofining employing a support material for fixed beds 失效
标题翻译：加氢精制采用固定床支撑材料
公开(公告)号：US4828683A
公开(公告)日：1989-05-09
申请号：US011989
申请日：1987-02-06
申请人： Lloyd E. Gardner , Simon G. Kukes
发明人： Lloyd E. Gardner , Simon G. Kukes
IPC分类号： C10G45/12 , B01J23/88 , B01J32/00 , C10G65/04
CPC分类号： B01J32/00 , C10G65/04
摘要： A hydrotreating process comprises contacting a substantially liquid hydrocarbon-containing feed stream, which contains compounds of sulfur and metals (preferably Ni and/or V), in the presence of a fixed catalyst bed comprising at least one layer of substantially spherical alumina-containing particles which have been prepared by heating a specific starting material at about 500.degree.-900.degree. C. for improved crush strength retention. In a preferred embodiment, the fixed catalyst bed further comprises at least one layer (b) of catalyst particles comprising a refractory inorganic carrier and at least one hydrogenation promoter. A fixed catalyst bed comprising layers (a) and (b) is provided.

5. 发明授权

US4820676A Treated alumina material for fixed hydrofining beds and process for its preparation 失效
标题翻译：用于固定加氢精制床的处理氧化铝材料及其制备方法
公开(公告)号：US4820676A
公开(公告)日：1989-04-11
申请号：US199744
申请日：1988-05-26
申请人： Simon G. Kukes , Karlheinz K. Brandes
发明人： Simon G. Kukes , Karlheinz K. Brandes
IPC分类号： B01J35/10 , C10G45/04 , B01J21/04 , B01J23/74 , B01J23/85 , B01J27/053
CPC分类号： C10G45/04 , B01J21/04 , B01J35/00 , B01J35/108 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042
摘要： A process for preparing impregnated substantially spherical alumina-containing particles comprises the steps of impregnating specific starting material with (NH.sub.4).sub.2 SO.sub.4 and then heating the thus impregnated material at about 500.degree.-900.degree. C. for improved crush strength retention. In a preferred embodiment a fixed catalyst bed comprises at least one layer of the alumina-containing particles and at least one layer of catalyst particles comprising a refractory inorganic carrier and at least one hydrogenation promoter.
摘要翻译：制备浸渍的基本上呈球形的含氧化铝颗粒的方法包括以下步骤：用（NH 4）2 SO 4浸渍特定原料，然后在约500-900℃下加热所浸渍的材料，以改善压碎强度保留。在优选的实施方案中，固定的催化剂床包括至少一层含氧化铝的颗粒和至少一层包含耐火无机载体和至少一种氢化促进剂的催化剂颗粒层。

6. 发明授权

US4778587A Hydrotreating process employing a pretreated alumina containing material 失效
标题翻译：使用预处理的含氧化铝材料的加氢处理方法
公开(公告)号：US4778587A
公开(公告)日：1988-10-18
申请号：US52096
申请日：1987-05-20
申请人： Simon G. Kukes , Thomas Davis , Karlheinz K. Brandes
发明人： Simon G. Kukes , Thomas Davis , Karlheinz K. Brandes
IPC分类号： C10G45/04
CPC分类号： C10G45/04
摘要： A composition of matter is prepared by a process comprising the steps of impregnating a alumina-containing support material with a thiocyanate (preferably ammonium thiocyanate), drying the thus impregnated material, impregnating the dried material with a transition metal compound, drying and calcining the transition metal impregnated material. This composition of matter is used as catalyst composition for hydrotreating of hydrocarbon-containing feed streams (in particular heavy oils) which contain metal and sulfur compounds as impurities.In another embodiment, a hydrotreating process comprises contacting hydrocarbon-containing feed stream (in particular heavy oils), which contains compounds of sulfur and metals, in the presence of a fixed catalyst bed comprising (X) at least one layer of impregnated substantially spherical alumina-containing particles which have been prepared by a process comprising the steps of impregnating specific starting material with NH.sub.4 SCN and then heating the thus impregnated material at about 500.degree.-900.degree. C. for improved crush strength retention. In a preferred embodiment, the fixed catalyst bed further comprises at least one layer (Y) of catalyst particles comprising a refractory inorganic carrier and at least one hydrogenation promoter. A composition of matter comprising the impregnated, spherical alumina-containing particles described above, and a process for preparing them are also provided.
摘要翻译：通过包括以下步骤的方法制备物质组合物，所述方法包括用硫氰酸盐（优选硫氰酸铵）浸渍含氧化铝的载体材料，干燥所浸渍的材料，用过渡金属化合物浸渍干燥的材料，干燥和煅烧过渡金属浸渍材料。该物质组合物用作用于加氢处理含有金属和硫化合物作为杂质的含烃进料流（特别是重油）的催化剂组合物。在另一个实施方案中，加氢处理方法包括在固定的催化剂床存在下使包含硫和金属化合物的含烃进料流（特别是重油）与含有（X）至少一层浸渍的基本上为球形的氧化铝通过包括以下步骤制备的颗粒，所述方法包括以下步骤：用NH 4 SCN浸渍特定原料，然后在约500-900℃下加热所浸渍的材料，以改善压碎强度保持性。在优选的实施方案中，固定催化剂床还包含至少一层包含耐火无机载体和至少一种氢化促进剂的催化剂颗粒层（Y）。还提供了包含上述浸渍的含球形氧化铝颗粒的物质组合物及其制备方法。

7. 发明授权

US4705766A Mixture of a molybdenum carboxylate and a molybdenum dithiophosphate or a molybdenum dithiocarbamate for use in a hydrovisbreaking process 失效
标题翻译：钼酸钼和二硫代磷酸钼或二硫代氨基甲酸钼的混合物用于加氢脱硫工艺
公开(公告)号：US4705766A
公开(公告)日：1987-11-10
申请号：US866552
申请日：1986-05-23
申请人： Jerald A. Howell , Simon G. Kukes
发明人： Jerald A. Howell , Simon G. Kukes
IPC分类号： C07C53/126 , C07C61/06 , C07C61/08 , C10G9/00 , C10G47/22 , B01J31/04 , B01J31/12
CPC分类号： C07C53/126 , C07C61/06 , C07C61/08 , C10G47/22 , C10G9/007
摘要： A decomposable molybdenum compound selected from the group consisting of a mixture of a molybdenum dithiophosphate and a molybdenum carboxylate and a mixture of a molybdenum dithiocarbamate and a molybdenum carboxylate is disclosed. The decomposable molybdenum compound may be added, in a hydrovisbreaking process, to a hydrocarbon-containing feed stream prior to contacting the feed stream with hydrogen under suitable hydrovisbreaking conditions.
摘要翻译：公开了一种可分解的钼化合物，其选自二硫代磷酸钼和羧酸钼的混合物以及二硫代氨基甲酸钼和钼酸钼的混合物。在加氢脱硫工艺中，可分解的钼化合物可以在合适的加氢脱硫条件下将进料流与氢气接触之前加入含烃进料流中。

8. 发明授权

US4687757A Hydrofining catalyst composition and process for its preparation 失效
标题翻译：加氢精制催化剂组合物及其制备方法
公开(公告)号：US4687757A
公开(公告)日：1987-08-18
申请号：US843489
申请日：1986-03-24
申请人： Stephen L. Parrott , Simon G. Kukes , Karlheinz K. Brandes
发明人： Stephen L. Parrott , Simon G. Kukes , Karlheinz K. Brandes
IPC分类号： B01J23/28 , C10G45/04 , C10G45/12 , C10G47/16 , B01J21/04 , B01J21/06 , B01J27/051
CPC分类号： C10G45/04 , B01J23/28
摘要： A composition of matter comprising alumina, at least one compound of titanium and at least one compound of molybdenum is prepared either by the steps of impregnating an alumina support material with an aqueous solution of at least one titanium compound, drying, impregnating the Ti-impregnated material with an aqueous solution of at least one molybdenum compound, drying and calcining; or by the steps of impregnating an alumina support material with an aqueous solution of at least one titanium compound and at least one molybdenum compound, drying and calcining. The compositions of matter of this invention are useful as catalysts for hydrotreating substantially liquid hydrocarbon-containing feed streams (particularly heavy oils) which also contain compounds of nickel, vanadium and sulfur.
摘要翻译：包含氧化铝，至少一种钛化合物和至少一种钼化合物的物质组合物可以通过以下步骤制备：用至少一种钛化合物的水溶液浸渍氧化铝载体材料，干燥，浸渍Ti浸渍材料与至少一种钼化合物的水溶液，干燥和煅烧; 或通过用至少一种钛化合物和至少一种钼化合物的水溶液浸渍氧化铝载体材料的步骤，干燥和煅烧。本发明的物质组合物可用作加氢处理基本上液体含烃的进料流（特别是重油）的催化剂，其还含有镍，钒和硫化合物。

9. 发明授权

US4609638A Demetallization of hydrocarbon containing feed streams 失效
标题翻译：含烃进料流的脱金属化
公开(公告)号：US4609638A
公开(公告)日：1986-09-02
申请号：US745552
申请日：1985-06-17
申请人： Simon G. Kukes , Gil R. Hawley
发明人： Simon G. Kukes , Gil R. Hawley
IPC分类号： B01J27/185 , C10G45/02 , C10G45/06 , B01J27/14
CPC分类号： C10G45/02 , B01J27/1853 , C10G45/06
摘要： Metals contained in a hydrocarbon containing feed stream are removed by contacting the hydrocarbon containing feed stream under suitable demetallization conditions with hydrogen and a catalyst composition comprising zirconium phosphate, cobalt phosphate and iron phosphate. The life and activity of the catalyst composition may be increased by introducing a decomposable metal compound selected from the group consisting of the metals of Group V-B, Group VI-B, Group VII-B and Group VIII of the Periodic Table into the hydrocarbon containing feed stream prior to contacting the hydrocarbon containing feed stream with the catalyst composition.
摘要翻译：通过在合适的脱金属条件下将含烃进料流与氢和包含磷酸锆，磷酸钴和磷酸铁的催化剂组合物接触来除去含烃进料流中的金属。催化剂组合物的寿命和活性可以通过将选自由VB组，VI-B族，VII-B族和VIII族元素周期表的金属组成的组中的可分解的金属化合物引入到含烃进料中在将含烃进料流与催化剂组合物接触之前的流。

10. 发明授权

US4588706A Phosphorus containing hydrofining catalysts 失效
标题翻译：含磷氢化催化剂
公开(公告)号：US4588706A
公开(公告)日：1986-05-13
申请号：US748112
申请日：1985-06-24
申请人： Simon G. Kukes , Stephen L. Parrott
发明人： Simon G. Kukes , Stephen L. Parrott
IPC分类号： B01J27/188 , C10G45/08 , B01J27/19
CPC分类号： B01J27/188 , C10G45/08
摘要： A catalyst composition is prepared by dissolving a suitable oxygen containing compound of a Group VIB metal (preferably Mo), a suitable compound of a Group VIII metal (preferably Ni) and phosphorous acid in water, mixing this solution with an alumina containing support material, and calcining this mixture. This catalyst composition is used primarily for hydrotreating of hydrocarbon feed stream, which contain nitrogen and sulfur impurities, particularly heavy cycle oils.
摘要翻译：通过将VIB族金属（优选Mo），适合的VIII族金属（优选Ni）和亚磷酸的合适的化合物溶解在水中来制备催化剂组合物，将该溶液与含氧化铝的载体材料混合，并煅烧该混合物。该催化剂组合物主要用于加氢处理含有氮和硫杂质的烃进料流，特别是重循环油。

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