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1. 发明授权

US5227563A Preparation of propylene by dehydration of isopropanol in the presence of a pseudo-boehmite derived gamma alumina catalyst 失效
标题翻译：在假勃姆石衍生的γ氧化铝催化剂存在下，通过异丙醇脱水制备丙烯
公开(公告)号：US5227563A
公开(公告)日：1993-07-13
申请号：US700319
申请日：1991-05-09
申请人： Hiroshi Fukuhara , Fujihisa Matsunaga , Mitsuki Yasuhara , Shintaro Araki , Toshiyuki Isaka
发明人： Hiroshi Fukuhara , Fujihisa Matsunaga , Mitsuki Yasuhara , Shintaro Araki , Toshiyuki Isaka
IPC分类号： B01J21/04 , C07C1/24
CPC分类号： B01J21/04 , C07C1/24 , C07C2521/04 , Y02P20/52
摘要： Propylene can be prepared in high yield and selectivity by dehydrating isopropanol in the presence of a .gamma.-alumina catalyst having a mean pore diameter of from 30 to 150 .ANG. with a standard deviation (.sigma..sub.n) of from 10 to 40 .ANG. based on statistic calculation from pore diameter and pore volume.
摘要翻译：丙烯可以通过在平均孔径为30至150的γ-氧化铝催化剂的存在下脱水异丙醇而制备，基于统计学计算，标准偏差（σ）为10至40安培从孔径和孔体积。

2. 发明授权

US5015786A Preparation of cumene through alkylation of an aromatic compound and preparation of phenol through cumene 失效
标题翻译：通过芳族化合物的烷基化制备枯烯并通过异丙苯制备苯酚
公开(公告)号：US5015786A
公开(公告)日：1991-05-14
申请号：US441477
申请日：1989-11-27
申请人： Shintaro Araki , Fujihisa Matsunaga , Hiroshi Fukuhara
发明人： Shintaro Araki , Fujihisa Matsunaga , Hiroshi Fukuhara
IPC分类号： B01J29/08 , C07C20060101 , C07C2/66 , C07C2/86 , C07C29/145 , C07C37/08 , C07C37/14 , C07C37/16 , C07C37/58 , C07C39/04 , C07C45/53 , C07C409/10
CPC分类号： C07C409/10 , C07C2/66 , C07C2/864 , C07C39/04 , C07C407/00 , C07C45/53 , C07C2529/08 , Y02P20/52
摘要： In a first form, a process is provided for preparing phenol by converting acetone by-produced by the cumene process into isopropanol, and alkylating benzene with the isopropanol and optional propylene, thereby forming phenol without acetone by-product. And cumene is prepared by alkylating benzene in the presence of a zeolite catalyst using isopropanol or a mixture of isopropanol and propylene as an alkylating agent. Further provided is the continuous alkylation of benzene with isopropanol wherein a reaction mixture is divided into first and second portions, with the first portion being recycled to the reactor and the second portion being taken out as a reaction product.

3. 发明授权

US5081321A Preparation of isopropanol 失效
标题翻译：异丙酚的制备
公开(公告)号：US5081321A
公开(公告)日：1992-01-14
申请号：US464315
申请日：1990-01-12
申请人： Hiroshi Fukuhara , Fujihisa Matsunaga , Yasunori Shibuta , Toshihiro Tachi
发明人： Hiroshi Fukuhara , Fujihisa Matsunaga , Yasunori Shibuta , Toshihiro Tachi
IPC分类号： B01J25/02 , B01J8/02 , C07B61/00 , C07C29/145 , C07C31/10
CPC分类号： B01J8/025 , C07C29/145
摘要： Isopropanol is prepared through catalytic hydrogenation of acetone by feeding hydrogen gas and acetone liquid into a reactor having a fixed catalyst bed from its top to form a cocurrent gas/liquid downflow while maintaining the catalyst bed in a trickle bed state. This process can produce isopropanol at a high reaction rate in high yields using a simple reactor.

4. 发明授权

US4923837A Hydrogenation catalyst 失效
标题翻译：氢化催化剂
公开(公告)号：US4923837A
公开(公告)日：1990-05-08
申请号：US286024
申请日：1988-12-19
申请人： Hiroshi Fukuhara , Fujihisa Matsunaga , Yasushi Nakashima
发明人： Hiroshi Fukuhara , Fujihisa Matsunaga , Yasushi Nakashima
IPC分类号： B01J21/16 , B01J23/46 , C07C5/11 , C10G45/52
CPC分类号： B01J23/462 , C07C5/11 , C07C2101/16 , C07C2523/46
摘要： A hydrogenation catalyst which is prepared by adsorbing ruthenium ions on a hydrotalcite (i.e. an anionic clay mineral) and/or a compound capable of conversion to a hydrotalcite structure by hydration, and then reducing said adsorbed ruthenium ions. The catalyst suitable for use in a process by which a monocyclic aromatic hydrocarbon is partially reduced to produce cyclohexene.

5. 发明授权

US5180871A Process for producing phenols 失效
标题翻译：酚类生产方法
公开(公告)号：US5180871A
公开(公告)日：1993-01-19
申请号：US839683
申请日：1992-02-24
申请人： Fujihisa Matsunaga , Hiroshi Fukuhara , Mitsuki Yasuhara
发明人： Fujihisa Matsunaga , Hiroshi Fukuhara , Mitsuki Yasuhara
IPC分类号： C07C5/10 , C07C5/367 , C07C37/06 , C07C37/07 , C07C39/06 , C07C45/34
CPC分类号： C07C5/367 , C07C37/06 , C07C37/07 , C07C45/34 , C07C5/10 , C07C2101/14
摘要： A process for producing a phenol from the steps of:(a) partially hydrogenating a benzene, followed by separating the reaction mixture into respective components of a cyclohexene, a cyclohexane and a benzene;(b) oxidizing or hydrating the separated a cyclohexene into oxygen-containing compounds of a cyclohexane;(c) dehydrogenating the oxygen-containing compounds of a cyclohexane into a phenol;(d) dehydrogenating the cyclohexane separated in step (a) to convert the cyclohexane into a benzene; and(e) returning a part or all of hydrogen formed in steps (c) and (d) back to step (a).
摘要翻译：一种从以下步骤生产苯酚的方法：（a）部分氢化苯，然后将反应混合物分离成环己烯，环己烷和苯的各组分; （b）将分离的环己烯氧化或水合成环己烷的含氧化合物; （c）将环己烷的含氧化合物脱氢成苯酚; （d）使在步骤（a）中分离的环己烷脱氢以将环己烷转化为苯; 和（e）将步骤（c）和（d）中形成的氢气的一部分或全部返回到步骤（a）。

6. 发明授权

US5017729A Phenol preparation process and propylene recovery therefrom 失效
标题翻译：苯酚制备方法和丙烯回收
公开(公告)号：US5017729A
公开(公告)日：1991-05-21
申请号：US402528
申请日：1989-09-05
申请人： Hiroshi Fukuhara , Fujihisa Matsunaga
发明人： Hiroshi Fukuhara , Fujihisa Matsunaga
IPC分类号： C07C1/24 , C07C11/06 , C07C37/08 , C07C37/58 , C07C39/04 , C07C45/53 , C07C409/10
CPC分类号： C07C409/10 , C07C1/24 , C07C11/06 , C07C39/04 , C07C407/00 , C07C45/53
摘要： Phenol is produced in a recycle manner by (a) reacting benzene with propylene to synthesize cumene, (b) oxidizing the cumene of step (a) into cumene hydroperoxide, (c) acid cleaving cumene hydroperoxide into phenol and acetone, (d) hydrogenating the acetone of step (c) into isopropanol, (e) dehydrating the isopropanol of step (d) into propylene, and (f) recycling the propylene of step (e) to step (a). It is also possible to take propylene from step (e). The acetone by-product produced upon preparation of phenol is converted into propylene which is useful by itself for any other uses or recycled to the phenol producing process.

7. 发明授权

US4929762A Process for producing a phenol and/or a cyclohexanone 失效
标题翻译：苯酚和/或环己酮的制备方法
公开(公告)号：US4929762A
公开(公告)日：1990-05-29
申请号：US318117
申请日：1989-03-02
申请人： Fujihisa Matsunaga , Hiroshi Fukuhara
发明人： Fujihisa Matsunaga , Hiroshi Fukuhara
IPC分类号： B01J32/00 , B01J21/16 , B01J23/40 , B01J31/40 , C07B61/00 , C07C27/00 , C07C37/06 , C07C37/07 , C07C39/04 , C07C45/00 , C07C45/62 , C07C49/403 , C07C67/00
CPC分类号： C07C45/002 , C07C37/06 , C07C37/07 , C07C45/62 , B01J21/18 , B01J23/42 , B01J23/44 , B01J23/462 , Y02P20/52
摘要： A phenol and/or a cyclohexanone is prepared by dehydrogenation of cyclohexenone and/or a cyclohexenol in liquid phase under the presence of a solid catalyst comprising a platinum-group metal loaded on a carrier. The solid catalyst comprises a carrier selected from activated carbon and hydrotalcites.

8. 发明授权

US4996372A Process for oxidizing 2,6-diisopropylnaphthalene 失效
标题翻译：氧化2,6-二异丙基萘的方法
公开(公告)号：US4996372A
公开(公告)日：1991-02-26
申请号：US473105
申请日：1990-02-02
申请人： Kenji Saeki , Hiroshi Fukuhara , Tokinori Agoo , Toru Taguchi , Hisaya Miki , Yutaka Haneda , Sadao Yoshimoto
发明人： Kenji Saeki , Hiroshi Fukuhara , Tokinori Agoo , Toru Taguchi , Hisaya Miki , Yutaka Haneda , Sadao Yoshimoto
IPC分类号： C07C27/12 , C07C37/08 , C07C39/14 , C07C67/08 , C07C69/16 , C07C407/00 , C07C409/08
CPC分类号： C07C409/08 , C07C37/08 , C07C407/00 , C07C67/08
摘要： In a process for producing 2,6-dihydroxynaphthalene from 2,6-diisopropylnaphthalene, 2,6-diisopropylnaphthalene is oxidized in the presence of a specific proportion of a basic compound to hydroxylate or hydroperoxylate 2,6-diisopropylnaphthalene in a high conversion, and the resulting intermediate is then subjected to acid cleavage in the presence of hydrogen peroxide to produce 2,6-dihydroxynaphthalene in a high yield. The yield of 2,6-dihydroxynaphthalene increases by subjecting the reaction mixture containing the above intermediate to a purifying operation or dehydrating operation or adding acetone to it before it is submitted to the acid cleavage. 2,6-Dihydroxynaphthalene may be reacted with acetic anhydride to obtain 2,6-diacetoxynaphthalene.

9. 发明申请

US20130071355A1 Recombinant Herpes Virus and Pharmaceutical Composition Containing The Same 有权
标题翻译：重组疱疹病毒和含有其的药物组合物
公开(公告)号：US20130071355A1
公开(公告)日：2013-03-21
申请号：US13579628
申请日：2010-02-19
申请人： Tomoki Todo , Hiroshi Fukuhara
发明人： Tomoki Todo , Hiroshi Fukuhara
IPC分类号： C12N7/00 , A61K35/76
CPC分类号： A61K35/763 , A61K35/76 , C12N7/00 , C12N15/86 , C12N15/869 , C12N2710/16621 , C12N2710/16632 , C12N2710/16643 , C12N2710/16671 , C12N2830/008
摘要： An object of the present invention is to provide a highly-safe recombinant herpes virus showing high antitumor activity regardless of the kind, grade of malignancy, or growth rate of tumor cells.The present invention provides a recombinant herpes simplex virus and the like constructed to express an ICP6 gene under control of a tumor-specific promoter or tissue-specific promoter on the genome of the virus.
摘要翻译：本发明的目的是提供一种高度安全的重组疱疹病毒，无论肿瘤细胞的种类，恶性程度或生长速度如何，都显示出高的抗肿瘤活性。本发明提供重组单纯疱疹病毒等，其构建为在病毒基因组上的肿瘤特异性启动子或组织特异性启动子的控制下表达ICP6基因。

10. 发明授权

US5337779A Automatic drain device 失效
标题翻译：自动排水装置
公开(公告)号：US5337779A
公开(公告)日：1994-08-16
申请号：US615571
申请日：1990-11-19
申请人： Hiroshi Fukuhara
发明人： Hiroshi Fukuhara
IPC分类号： F04B49/06 , F04B39/16 , F04B41/02 , F16T1/00 , F16T1/34 , F16K31/02
CPC分类号： F16T1/00 , Y10T137/3052 , Y10T137/3105 , Y10T137/7306
摘要： An automatic drain device in an air compressor system includes an electrode sensor in a liquid collection cell. An electronic control detects an electrical change in the electrode sensor resulting from contact with liquid in the liquid collection cell and energizes a drain valve for a predetermined time effective to drain the liquid collection cell. A cycle timer triggers the energization of the drain valve when the electrode sensor fails to provide the required electrical change for a predetermined cycle time. Test inputs permit driving the electronic control to simulate sensing of liquid, and also permit energization of the drain valve without involving the remainder of the electronic control.
摘要翻译：空气压缩机系统中的自动排水装置包括液体收集池中的电极传感器。电子控制器检测由于与液体收集单元中的液体接触而导致的电极传感器中的电变化，并且将排水阀通电一预定时间以有效地排出液体收集单元。当电极传感器不能在预定的周期时间内提供所需的电气变化时，周期定时器触发排水阀的通电。测试输入允许驱动电子控制来模拟液体的感测，并且还允许排水阀通电而不涉及电子控制的其余部分。

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