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1. 发明申请

US20100279129A1 THERMOSETTING RESIN COMPOSITION AND PREPREG AND LAMINATE BOTH MADE WITH THE SAME. 审中-公开
标题翻译：热固性树脂组合物及其制备和层压体与其相同。
公开(公告)号：US20100279129A1
公开(公告)日：2010-11-04
申请号：US12810387
申请日：2008-06-19
申请人： Shinji Tsuchikawa , Masanori Akiyama , Tomohiko Kotake
发明人： Shinji Tsuchikawa , Masanori Akiyama , Tomohiko Kotake
IPC分类号： B32B15/08 , C08K5/3492
CPC分类号： C08K5/5333 , B32B5/02 , B32B15/092 , B32B15/20 , B32B2457/08 , C08G59/56 , C08J5/24 , C08J2363/00 , C08J2363/04 , C08K3/22 , C08K3/32 , C08K3/36 , C08K2003/2227 , C08L63/00 , C08L63/04 , C08L2201/02 , C09J163/00 , C09J163/04 , C09J2205/102 , H05K1/0353 , Y10T428/31678
摘要： The present invention provides a thermosetting resin composition comprising (A) a metal salt of disubstituted phosphinic acid, (B) a maleimide compound having a N-substituted maleimide group in a molecule, (C) a 6-substituted guanamine compound or dicyandiamide and (D) an epoxy resin having at least two epoxy groups in a molecule and a prepreg and a laminated plate which are prepared by using the same. The prepregs obtained by impregnating or coating a base material with the thermosetting resin compositions of the present invention and the laminated plates produced by laminating and molding the above prepregs are balanced in all of a copper foil adhesive property, a glass transition temperature, a solder heat resistance, a moisture absorption, a flame resistance, a relative dielectric constant and a dielectric loss tangent, and they are useful as a printed wiring board for electronic instruments.
摘要翻译：本发明提供一种热固性树脂组合物，其包含（A）二取代次膦酸的金属盐，（B）分子中具有N-取代的马来酰亚胺基的马来酰亚胺化合物，（C）6-取代的胍胺化合物或双氰胺和（ D）在分子中具有至少两个环氧基的环氧树脂和通过使用它们制备的预浸料和层压板。通过用本发明的热固性树脂组合物浸渍或涂覆基材获得的预浸料和通过层压和模塑上述预浸料制成的层压板均具有铜箔粘合性，玻璃化转变温度，焊料热电阻，吸湿性，阻燃性，相对介电常数和介电损耗角正切，并且它们可用作电子仪器的印刷线路板。

2. 发明授权

US09603244B2 Thermosetting resin composition and prepreg and laminate obtained with the same 有权
公开(公告)号：US09603244B2
公开(公告)日：2017-03-21
申请号：US12443260
申请日：2007-09-10
申请人： Shinji Tsuchikawa , Tomohiko Kotake , Masanori Akiyama
发明人： Shinji Tsuchikawa , Tomohiko Kotake , Masanori Akiyama
IPC分类号： B32B15/08 , C08G59/40 , H05K1/03 , C08G59/50 , C08G73/12 , C08L63/00 , C08L79/08 , B32B15/092 , B32B15/14 , C08L25/08
CPC分类号： H05K1/0373 , B32B15/08 , B32B15/092 , B32B15/14 , B32B2260/021 , B32B2260/046 , B32B2305/076 , B32B2457/08 , C08G59/4021 , C08G59/4042 , C08G59/506 , C08G59/5086 , C08G73/12 , C08G73/124 , C08J5/24 , C08J2363/04 , C08J2363/08 , C08J2423/22 , C08J2425/08 , C08L25/08 , C08L63/00 , C08L63/04 , C08L63/08 , C08L79/085 , C08L2201/02 , C08L2203/20 , H05K1/0353 , H05K2201/012 , Y10T428/31678 , C08L2666/04
摘要： The present invention provides a thermosetting resin composition comprising (A) a curing agent having an acidic substituent and an unsaturated maleimide group which is produced by a specific method, (B) a 6-substituted guanamine compound and/or dicyandiamide, (C) a copolymer resin comprising specific monomer units and (D) an epoxy resin and a prepreg and a laminated plate which are prepared by using the same. The thermosetting resin composition of the present invention is balanced in all of a copper foil adhesive property, a heat resistance, a moisture absorption, a flame resistance, a metal-stuck heat resistance, a relative dielectric constant and a dielectric loss tangent. They have a low toxicity and are excellent in a safety and a working environment, and therefore a prepreg and a laminated plate which have excellent performances are obtained by using the above thermosetting resin composition.

3. 发明申请

US20100143728A1 THERMOSETTING RESIN COMPOSITION AND PREPREG AND LAMINATE OBTAINED WITH THE SAME 有权
标题翻译：热固性树脂组合物和与其相同的PREPREG和层压板
公开(公告)号：US20100143728A1
公开(公告)日：2010-06-10
申请号：US12443260
申请日：2007-09-10
申请人： Shinji Tsuchikawa , Tomohiko Kotake , Masanori Akiyama
发明人： Shinji Tsuchikawa , Tomohiko Kotake , Masanori Akiyama
IPC分类号： B32B15/08 , C08K5/3492 , C08K5/31 , B32B27/26
CPC分类号： H05K1/0373 , B32B15/08 , B32B15/092 , B32B15/14 , B32B2260/021 , B32B2260/046 , B32B2305/076 , B32B2457/08 , C08G59/4021 , C08G59/4042 , C08G59/506 , C08G59/5086 , C08G73/12 , C08G73/124 , C08J5/24 , C08J2363/04 , C08J2363/08 , C08J2423/22 , C08J2425/08 , C08L25/08 , C08L63/00 , C08L63/04 , C08L63/08 , C08L79/085 , C08L2201/02 , C08L2203/20 , H05K1/0353 , H05K2201/012 , Y10T428/31678 , C08L2666/04
摘要： The present invention provides a thermosetting resin composition comprising (A) a curing agent having an acidic substituent and an unsaturated maleimide group which is produced by a specific method, (B) a 6-substituted guanamine compound and/or dicyandiamide, (C) a copolymer resin comprising specific monomer units and (D) an epoxy resin and a prepreg and a laminated plate which are prepared by using the same. The thermosetting resin composition of the present invention is balanced in all of a copper foil adhesive property, a heat resistance, a moisture absorption, a flame resistance, a metal-stuck heat resistance, a relative dielectric constant and a dielectric loss tangent. They have a low toxicity and are excellent in a safety and a working environment, and therefore a prepreg and a laminated plate which have excellent performances are obtained by using the above thermosetting resin composition.
摘要翻译：本发明提供一种热固性树脂组合物，其包含（A）具有酸性取代基的固化剂和通过特定方法制备的不饱和马来酰亚胺基团，（B）6-取代胍胺化合物和/或双氰胺，（C）包含特定单体单元的共聚物树脂和（D）通过使用它们制备的环氧树脂和预浸料和层压板。本发明的热固性树脂组合物的铜箔粘合性，耐热性，吸湿性，阻燃性，金属粘着耐热性，相对介电常数和介电损耗角正切均衡。它们具有低毒性，安全性和工作环境优异，因此通过使用上述热固性树脂组合物可以获得具有优异性能的预浸料和层压板。

4. 发明授权

US08461332B2 Method for producing curing agent having acidic substituent and unsaturated maleimide group, thermosetting resin composition, prepreg, and laminate 有权
标题翻译：具有酸性取代基和不饱和马来酰亚胺基团的固化剂的生产方法，热固性树脂组合物，预浸料和层压材料
公开(公告)号：US08461332B2
公开(公告)日：2013-06-11
申请号：US13527995
申请日：2012-06-20
申请人： Shinji Tsuchikawa , Masanori Akiyama , Hikari Murai
发明人： Shinji Tsuchikawa , Masanori Akiyama , Hikari Murai
IPC分类号： C07D251/48 , C07D207/452
CPC分类号： C08L79/085 , B32B27/12 , B32B27/28 , B32B27/42 , B32B2307/3065 , B32B2457/00 , C07D207/452 , C08G59/46 , C08G73/12 , C08J5/24 , C08J2363/00 , C08K3/40 , C08K5/18 , C08K5/3492 , C09D163/00 , Y10T428/31504 , Y10T428/31511
摘要： A method for producing a curing agent having an acidic substituent and an unsaturated maleimido group, including reacting, in an organic solvent, a maleimide compound (a) having at least two N-substituted maleimido groups in a molecule thereof with an amine compound (b) having an acidic substituent (represented by formula (I) below); a thermosetting resin composition containing the curing agent (A) produced through the method and a compound (B) which is cured with the curing agent, wherein a cured product of the composition has a glass transition temperature of 200° C. or higher; and a prepreg and a laminated sheet produced therefrom. The thermosetting resin composition can produce a prepreg or laminated sheet exhibiting excellent performance suitable for a printed wiring board for electronic devices and similar devices.
摘要翻译：一种制备具有酸性取代基和不饱和马来酰亚胺基的固化剂的方法，包括在有机溶剂中使分子中具有至少两个N-取代的马来酰亚胺基的马来酰亚胺化合物（a）与胺化合物（b ）具有酸性取代基（由下式（I）表示）; 含有通过该方法制备的固化剂（A）和用固化剂固化的化合物（B）的热固性树脂组合物，其中组合物的固化产物的玻璃化转变温度为200℃以上; 和由其制成的预浸料和层压片。热固性树脂组合物可以制造出适合于电子设备和类似装置的印刷线路板的表现出优异性能的预浸料或层压片。

5. 发明申请

US20100173163A1 METHOD FOR PRODUCING CURING AGENT HAVING ACIDIC SUBSTITUENT AND UNSATURATED MALEIMIDE GROUP, THERMOSETTING RESIN COMPOSITION, PREPREG, AND LAMINATE 有权
标题翻译：制备具有酸性取代基和不饱和马来酰亚胺基的固化剂，热固性树脂组合物，PREPREG和层压体的方法
公开(公告)号：US20100173163A1
公开(公告)日：2010-07-08
申请号：US12303627
申请日：2007-06-01
申请人： Shinji Tsuchikawa , Masanori Akiyama , Hikari Murai
发明人： Shinji Tsuchikawa , Masanori Akiyama , Hikari Murai
IPC分类号： B32B27/38 , B32B27/00 , C07D403/02 , C08G73/02 , C08G59/14 , C08L79/02
CPC分类号： C08L79/085 , B32B27/12 , B32B27/28 , B32B27/42 , B32B2307/3065 , B32B2457/00 , C07D207/452 , C08G59/46 , C08G73/12 , C08J5/24 , C08J2363/00 , C08K3/40 , C08K5/18 , C08K5/3492 , C09D163/00 , Y10T428/31504 , Y10T428/31511
摘要： The invention provides a method for producing a curing agent having an acidic substituent and an unsaturated maleimido group, including reacting, in an organic solvent, a maleimide compound (a) having at least two N-substituted maleimido groups in a molecule thereof with an amine compound (b) having an acidic substituent (represented by formula (I)); a thermosetting resin composition containing the curing agent (A) produced through the method and a compound (B) which is cured with the curing agent, wherein a cured product of the composition has a glass transition temperature of 200° C. or higher; and a prepreg and a laminated sheet produced therefrom. The curing agent produced through the method of the present invention has good solubility in an organic solvent and can provide a thermosetting resin composition exhibiting excellent adhesion-to-metal foil property, heat resistance, moisture resistance, flame retardancy, and copper cladding heat resistance, and low dielectric properties and low dielectric loss tangent. Therefore, the thermosetting resin composition can produce a prepreg or laminated sheet exhibiting excellent performance suitable for a printed wiring board for electronic devices and similar devices.
摘要翻译：本发明提供一种具有酸性取代基和不饱和马来酰亚胺基的固化剂的制备方法，包括在有机溶剂中使分子中具有至少两个N-取代的马来酰亚胺基的马来酰亚胺化合物（a）与胺具有酸性取代基的化合物（b）（由式（I）表示））; 含有通过该方法制备的固化剂（A）和用固化剂固化的化合物（B）的热固性树脂组合物，其中组合物的固化产物的玻璃化转变温度为200℃以上; 和由其制成的预浸料和层压片。通过本发明的方法制备的固化剂在有机溶剂中具有良好的溶解性，并且可以提供表现出优异的粘合性 - 金属箔性，耐热性，耐湿性，阻燃性和铜包层耐热性的热固性树脂组合物，低介电特性和低介电损耗角正切。因此，热固性树脂组合物可以制造出适用于电子设备和类似装置的印刷线路板的表现出优异性能的预浸料或层压片。

6. 发明申请

US20120316263A1 Method for Producing Curing Agent Having Acidic Substituent and Unsaturated Maleimide Group, Thermosetting Resin Composition, Prepreg, and Laminate 有权
标题翻译：具有酸性取代基和不饱和马来酰亚胺基团的固化剂的生产方法，热固性树脂组合物，预浸料和层合物
公开(公告)号：US20120316263A1
公开(公告)日：2012-12-13
申请号：US13527995
申请日：2012-06-20
申请人： Shinji Tsuchikawa , Masanori Akiyama , Hikari Murai
发明人： Shinji Tsuchikawa , Masanori Akiyama , Hikari Murai
IPC分类号： C08L79/04 , C08L63/04 , C08K5/09
CPC分类号： C08L79/085 , B32B27/12 , B32B27/28 , B32B27/42 , B32B2307/3065 , B32B2457/00 , C07D207/452 , C08G59/46 , C08G73/12 , C08J5/24 , C08J2363/00 , C08K3/40 , C08K5/18 , C08K5/3492 , C09D163/00 , Y10T428/31504 , Y10T428/31511
摘要： A method for producing a curing agent having an acidic substituent and an unsaturated maleimido group, including reacting, in an organic solvent, a maleimide compound (a) having at least two N-substituted maleimido groups in a molecule thereof with an amine compound (b) having an acidic substituent (represented by formula (I) below); a thermosetting resin composition containing the curing agent (A) produced through the method and a compound (B) which is cured with the curing agent, wherein a cured product of the composition has a glass transition temperature of 200° C. or higher; and a prepreg and a laminated sheet produced therefrom. The thermosetting resin composition can produce a prepreg or laminated sheet exhibiting excellent performance suitable for a printed wiring board for electronic devices and similar devices.
摘要翻译：一种制备具有酸性取代基和不饱和马来酰亚胺基的固化剂的方法，包括在有机溶剂中使分子中具有至少两个N-取代的马来酰亚胺基的马来酰亚胺化合物（a）与胺化合物（b ）具有酸性取代基（由下式（I）表示）; 含有通过该方法制备的固化剂（A）和用固化剂固化的化合物（B）的热固性树脂组合物，其中组合物的固化产物的玻璃化转变温度为200℃以上; 和由其制成的预浸料和层压片。热固性树脂组合物可以制造出适合于电子设备和类似装置的印刷线路板的表现出优异性能的预浸料或层压片。

7. 发明授权

US08796473B2 Method for producing curing agent having acidic substituent and unsaturated maleimide group, thermosetting resin composition, prepreg, and laminate 有权
标题翻译：具有酸性取代基和不饱和马来酰亚胺基团的固化剂的生产方法，热固性树脂组合物，预浸料和层压材料
公开(公告)号：US08796473B2
公开(公告)日：2014-08-05
申请号：US12303627
申请日：2007-06-01
申请人： Shinji Tsuchikawa , Masanori Akiyama , Hikari Murai
发明人： Shinji Tsuchikawa , Masanori Akiyama , Hikari Murai
IPC分类号： C07D403/06 , C07D403/12
CPC分类号： C08L79/085 , B32B27/12 , B32B27/28 , B32B27/42 , B32B2307/3065 , B32B2457/00 , C07D207/452 , C08G59/46 , C08G73/12 , C08J5/24 , C08J2363/00 , C08K3/40 , C08K5/18 , C08K5/3492 , C09D163/00 , Y10T428/31504 , Y10T428/31511
摘要： The invention provides a method for producing a curing agent having an acidic substituent and an unsaturated maleimido group, including reacting, in an organic solvent, a maleimide compound (a) having at least two N-substituted maleimido groups in a molecule thereof with an amine compound (b) having an acidic substituent (represented by formula (I)); a thermosetting resin composition containing the curing agent (A) produced through the method and a compound (B) which is cured with the curing agent, wherein a cured product of the composition has a glass transition temperature of 200° C. or higher; and a prepreg and a laminated sheet produced therefrom. The curing agent produced through the method of the present invention has good solubility in an organic solvent and can provide a thermosetting resin composition exhibiting excellent adhesion-to-metal foil property, heat resistance, moisture resistance, flame retardancy, and copper cladding heat resistance, and low dielectric properties and low dielectric loss tangent. Therefore, the thermosetting resin composition can produce a prepreg or laminated sheet exhibiting excellent performance suitable for a printed wiring board for electronic devices and similar devices.
摘要翻译：本发明提供一种具有酸性取代基和不饱和马来酰亚胺基的固化剂的制备方法，包括在有机溶剂中使分子中具有至少两个N-取代的马来酰亚胺基的马来酰亚胺化合物（a）与胺具有酸性取代基的化合物（b）（由式（I）表示））; 含有通过该方法制备的固化剂（A）和用固化剂固化的化合物（B）的热固性树脂组合物，其中组合物的固化产物的玻璃化转变温度为200℃以上; 和由其制成的预浸料和层压片。通过本发明的方法制备的固化剂在有机溶剂中具有良好的溶解性，并且可以提供表现出优异的粘合性 - 金属箔性，耐热性，耐湿性，阻燃性和铜包层耐热性的热固性树脂组合物，低介电特性和低介电损耗角正切。因此，热固性树脂组合物可以制造出适用于电子设备和类似装置的印刷线路板的表现出优异性能的预浸料或层压片。

8. 发明授权

US4001842A Apparatus for making electro-luminescent screens for color cathode-ray tubes of continuous phosphor stripes 失效
标题翻译：用于制造连续磷酸盐条纹彩色阴极射线管的电致发光屏的装置
公开(公告)号：US4001842A
公开(公告)日：1977-01-04
申请号：US574639
申请日：1975-05-05
申请人： Takeshi Suzuki , Hiroshi Tanaka , Masanori Akiyama
发明人： Takeshi Suzuki , Hiroshi Tanaka , Masanori Akiyama
IPC分类号： H01J9/227 , G03B41/00
CPC分类号： H01J9/2272
摘要： An electroluminescent screen comprising a plurality of continuous phosphor stripes running the length of the screen formed on a panel for a color cathode-ray tube by applying film containing photosensitive material onto the panel. A shadow mask is attached to the panel, and the mask and film are irradiated by light from a light source.The shadow mask has on its concave face which faces the light source apertures arranged in substantially parallel rows, the apertures along the length of each of the rows being separated from each other by thin beam-intercepting bridge portions. The area on the shadow mask irradiated by the light is limited to cover only a part of the length of the rows of apertures by a shield plate having an opening for limiting the path of the light.The shield plate is moved so as to move the irradiated area on the shadow mask along the length of the rows of the apertures. The light source has sufficient length in the lengthwise direction of the rows of apertures to produce on the film the bright image of the apertures, each image being expanded to be connected with the adjacent bright images of the apertures on either side along the length of the row. The light source is gradually inclined synchronously with the moving of the irradiated area on the shadow mask, to always be kept substantially parallel to the rows of apertures in the irradiated area.

9. 发明申请

US20070211202A1 Liquid crystal display device, method of making the same, and electronic apparatus 审中-公开
标题翻译：液晶显示装置及其制造方法以及电子设备
公开(公告)号：US20070211202A1
公开(公告)日：2007-09-13
申请号：US11712608
申请日：2007-03-01
申请人： Taiji Ishii , Masanori Akiyama
发明人： Taiji Ishii , Masanori Akiyama
IPC分类号： G02F1/1339
CPC分类号： G02F1/1339 , G02F2001/133311
摘要： A liquid crystal display device includes a first substrate, a second substrate opposed to the first substrate, a liquid crystal layer between the first and second substrates, a plurality of seals arranged in a sealing area located around a display area in which an image is displayed through the liquid crystal layer, and two sealing portions each connecting ends of the seals to seal the space. The seals extend along the sealing area on the first substrate. The adjacent seals are disposed with a space therebetween in the direction from the center of the display area to the periphery thereof. The seals join the first substrate to the second substrate.
摘要翻译：液晶显示装置包括第一基板，与第一基板相对的第二基板，第一和第二基板之间的液晶层，布置在显示区域周围的密封区域中的多个密封件，其中显示图像通过液晶层和两个密封部分，每个连接密封件的端部以密封该空间。密封件沿着第一基板上的密封区域延伸。相邻的密封件在从显示区域的中心到其周边的方向上设置有空间。密封件将第一基底连接到第二基底。

10. 发明申请

US20070208514A1 Method of Preparing Disease Prognosis Model, Disease Prognosis Prediction Method using this Model, Prognosis Prediction Device Based on this Model, and Program for Performing the Device and Storage Medium Wherein Said Program is Stored 审中-公开
标题翻译：使用该模型预测疾病预后模型的方法，使用该模型的预测预测方法，基于该模型的预测预测装置，以及执行所述程序存储的装置和存储介质的程序
公开(公告)号：US20070208514A1
公开(公告)日：2007-09-06
申请号：US10553426
申请日：2004-04-23
申请人： Hiroshi Yatsuhashi , Masanori Akiyama , Takehiro Matsumoto
发明人： Hiroshi Yatsuhashi , Masanori Akiyama , Takehiro Matsumoto
IPC分类号： G06F19/00 , A61B5/00
CPC分类号： G16H50/20 , G16B20/00 , G16B40/00 , G16H50/50 , G16H50/70
摘要： The present invention relates to a disease prognosis prediction modeling method for preparing a model for predicting the prognosis of a specified disease from clinical laboratory test values for the disease by means of a computer, the method comprising the steps of: inputting a plurality of actually measured clinical laboratory test values for the disease and actual measured values of the prognoses into the computer; processing these values by a data mining method to determine one or a plurality of clinical laboratory test items which have an influence on the prognosis of the disease; determining a priority of the items with respect to the prognosis in a case where there are a plurality of the items; and establishing a judgment routine in which correlation of the plurality of clinical laboratory test items and the clinical laboratory test value ranges of the test items with the predicted value of the prognosis is stipulated on the basis of the priority, wherein the judgment routine is used as the model.
摘要翻译：本发明涉及一种通过计算机从疾病的临床实验室测试值中准备预测特定疾病的预后的模型的疾病预后建模方法，所述方法包括以下步骤：输入多个实际测量疾病的临床实验室检测值和计算机预后的实际测量值; 通过数据挖掘方法处理这些值以确定对疾病预后具有影响的一个或多个临床实验室检查项目; 在存在多个项目的情况下，确定项目相对于预后的优先级; 建立判断程序，其中基于优先级规定了多个临床实验室检查项目与检验项目的临床实验室检验值范围与预测值的预测值的相关性，其中判断例程用作该模型。

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