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    • 2. 发明授权
    • Polyester resin for toner
    • 聚碳酸酯树脂
    • US5276127A
    • 1994-01-04
    • US744333
    • 1991-08-13
    • Masayuki TakyuNoriyuki TajiriHitoshi IwasakiShinji KuboMasahiro ItohHirokazu Ito
    • Masayuki TakyuNoriyuki TajiriHitoshi IwasakiShinji KuboMasahiro ItohHirokazu Ito
    • C08G63/20G03G9/087C08G63/02
    • C08G63/20G03G9/08755
    • A polyester resin for a toner capable of being stably prepared without an occurrence of an abrupt crosslinking reaction is provided. This polyester resin has a crosslinked structure and is derived from (a) at least one member selected from the group consisting of tribasic and tetrabasic carboxylic acid components and trihydric and tetrahydric alcohol components, (b) an aromatic or alicyclic diol component, at least one of the hydroxyl groups of which is a secondary hydroxyl group, (c) optionally other diol component, and (d) a dicarboxylic acid component, wherein the contents of the units of the component (a) and the units of the component (b) satisfy the requirement represented by the following formula (1):(8m+20n)a-(80m+80n).ltoreq.b.ltoreq.(8m+20n)a-(12m+30n) (1)wherein m represents the molar fraction of the tribasic carboxylic acid component and trihydric alcohol component units in the units derived from the component (a), n represent the molar fraction of the tetrabasic carboxylic acid component units and tetrahydric alcohol component units in the units derived from the component (a), the sum of m and n is equal to 1, and a and b represent the molar ratios (mole %) of the units of the component (a) and the units of the component (b) based on the total of the carboxylic acid components, respectively.
    • 提供了一种能够稳定地制备而不发生突然交联反应的调色剂用聚酯树脂。 该聚酯树脂具有交联结构,并且衍生自(a)选自三元和四元羧酸组分和三元和四元醇组分中的至少一种,(b)芳族或脂环族二醇组分,至少一种 其中羟基为仲羟基,(c)任选其它二醇组分,和(d)二羧酸组分,其中组分(a)的单元含量和组分(b)的单元含量, 满足由下式(1)表示的要求:(8m + 20n)a-(80m + 80n)<= b <=(8m + 20n)a-(12m + 30n)(1)其中m表示摩尔分数 的三元羧酸组分和三元醇组分单元的衍生自组分(a)的单元,n表示衍生自组分(a)的单元中的四元羧酸组分单元和四元醇组分单元的摩尔分数, m和n的和等于1,而 a和b分别表示组分(a)的单元和组分(b)的单元的摩尔比(摩尔%),基于羧酸组分的总量。
    • 5. 发明授权
    • Toner resin composition and process for preparing same
    • 调色剂树脂组合物及其制备方法
    • US5342722A
    • 1994-08-30
    • US878910
    • 1992-05-06
    • Hirokazu ItoMasahiro ItohMotoshi InagakiSyuji TakahiroKeiji Yoshida
    • Hirokazu ItoMasahiro ItohMotoshi InagakiSyuji TakahiroKeiji Yoshida
    • C08G59/00C08G59/20C08G59/32C08L63/00C08L67/00C08L67/02G03G9/087G03G9/00G03G9/13
    • G03G9/08786G03G9/08706G03G9/08711G03G9/08755Y10S430/105Y10S430/109
    • A toner resin composition comprising 5 to 40% by weight of a polyester (A) having a weight average molecular weight of 3,000 to 20,000 and 50 to 95% by weight of a styrene-acrylic copolymer (B). The styrene-acrylic copolymer (B) is comprised of 10 to 25% by weight of a high molecular weight polymer (B1) having a weight average molecular weight of 500,000 to 1,100,000 and 75 to 90% by weight of a low molecular weight polymer (B2) having a weight average molecular weight of 5,000 to 100,000. The high molecular weight polymer (B1) is comprised of a styrene component (b-1) and an acrylic ester and/or methacrylic ester component (b-2). The low molecular weight polymer (B2) is comprised of a styrene component (b-1), an acrylic ester and/or methacrylic ester component (b-2), 0.3 to 3 parts by weight, per 100 parts of the total weight of said component (b-1) and component (b-2), of an .alpha.-methyl styrene dimer (b-3) and 0.5 to 30 parts by weight, per 100 parts by weight of said polyester (A), of a glycidyl methacrylate component (b-4).
    • 一种调色剂树脂组合物,其包含5至40重量%的重均分子量为3,000至20,000的聚酯(A)和50至95重量%的苯乙烯 - 丙烯酸共聚物(B)。 苯乙烯 - 丙烯酸共聚物(B)由10至25重量%的重均分子量为500,000至1,100,000和75至90重量%的低分子量聚合物的高分子量聚合物(B1) B2),其重均分子量为5,000〜100,000。 高分子量聚合物(B1)由苯乙烯组分(b-1)和丙烯酸酯和/或甲基丙烯酸酯组分(b-2)组成。 低分子量聚合物(B2)由苯乙烯组分(b-1),丙烯酸酯和/或甲基丙烯酸酯组分(b-2)组成,每100份总重量为0.3-3重量份 所述组分(b-1)和组分(b-2),α-甲基苯乙烯二聚物(b-3)和0.5-30重量份,相对于所述聚酯(A)100重量份, 甲基丙烯酸酯组分(b-4)。