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1. 发明授权

US08017262B2 Lithium secondary battery with porous heat-resistant layer 有权
标题翻译：锂二次电池带多孔耐热层
公开(公告)号：US08017262B2
公开(公告)日：2011-09-13
申请号：US11339617
申请日：2006-01-26
申请人： Masato Fujikawa , Shinji Kasamatsu , Hajime Nishino , Hideharu Takezawa , Mikinari Shimada
发明人： Masato Fujikawa , Shinji Kasamatsu , Hajime Nishino , Hideharu Takezawa , Mikinari Shimada
IPC分类号： H01M10/02 , H01M2/16
CPC分类号： H01M10/052 , H01M2/1653 , H01M2/166 , H01M2/1673 , H01M2/1686 , H01M4/525 , H01M10/4235 , Y02T10/7011
摘要： A lithium secondary battery including: an electrode group, a non-aqueous electrolyte and a battery case housing the electrode group and the non-aqueous electrolyte, the electrode group including a positive electrode, a negative electrode and a separator layer interposed between the positive electrode and the negative electrode, wherein an end-of-charge voltage and an end-of-discharge voltage are set in such a manner that the electrode group has an energy density of not less than 700 Wh/L, the separator layer includes a porous heat-resistant layer, and a short circuit area A produced when an internal short circuit has occurred between the positive electrode and the negative electrode, and a reduced area B of the porous heat-resistant layer that is produced by heat generation satisfy 1≦(A+B)/A≦10.
摘要翻译：一种锂二次电池，其包括：电极组，非水电解质和容纳所述电极组和所述非水电解质的电池壳体，所述电极组包括正极，负极和插入在所述正极之间的隔板层和负极，其中以使得电极组的能量密度不低于700Wh / L的方式设定充电结束电压和放电终止电压，隔板层包括多孔耐热层和在正极和负极之间发生内部短路时产生的短路面积A，通过发热产生的多孔耐热层的减少面积B满足1＆lt; nlE;（ A + B）/ A＆nlE; 10。

2. 发明授权

US07687202B2 Non-aqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池
公开(公告)号：US07687202B2
公开(公告)日：2010-03-30
申请号：US11315189
申请日：2005-12-23
申请人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
发明人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
IPC分类号： H01M4/58 , H01M2/16 , H01M6/04 , H10M4/62
CPC分类号： H01M4/131 , H01M2/1653 , H01M4/505 , H01M4/525 , H01M10/4235
摘要： A non-aqueous electrolyte secondary battery including: a positive electrode having a positive electrode material mixture containing a composite lithium oxide; a negative electrode; a polyolefin separator; a non-aqueous electrolyte; and a heat-resistant insulating layer interposed between the positive and negative electrodes. The positive electrode active material mixture has an estimated heat generation rate at 200° C. of not greater than 50 W/kg. The estimated heat generation rate is determined by obtaining a relation between absolute temperature T and heat generation rate V of the positive electrode material mixture using an accelerating rate calorimeter; plotting a relation between the inverse of absolute temperature T and the logarithm of heat generation rate V according to the Arrhenius law; obtaining a straight line fitted to the plotted points in a heat generation temperature range of T
摘要翻译：一种非水电解质二次电池，包括：具有含有复合氧化锂的正极合剂混合物的正极; 负极; 聚烯烃分离器; 非水电解质; 以及插入在正极和负极之间的耐热绝缘层。正极活性物质混合物在200℃下的估计发热率不大于50W / kg。通过使用加速率量热计获得正极材料混合物的绝对温度T和发热量V之间的关系来确定估计发热速率; 根据Arrhenius定律绘制绝对温度T的倒数与发热量V的对数之间的关系; 在T <200℃的发热温度范围内获得拟合到绘图点的直线; 并将直线外推至200℃的温度。

3. 发明申请

US20090104529A1 ELECTRODE FOR LITHIUM ION SECONDARY BATTERY 有权
标题翻译：用于锂离子二次电池的电极
公开(公告)号：US20090104529A1
公开(公告)日：2009-04-23
申请号：US11916603
申请日：2006-07-21
申请人： Hajime Nishino , Shuji Tsutsumi , Shinji Kasamatsu , Hideharu Takezawa , Mikinari Shimada
发明人： Hajime Nishino , Shuji Tsutsumi , Shinji Kasamatsu , Hideharu Takezawa , Mikinari Shimada
IPC分类号： H01M4/58
CPC分类号： H01M4/70 , H01M10/0525 , Y02E60/122 , Y02T10/7011
摘要： An object of the present invention is to provide an electrode for a lithium ion secondary battery that can ensure a high level of safety even when exposed to severe conditions such as a nail penetration test or crush test, and exhibit excellent output characteristics.The present invention relates to an electrode for a lithium ion secondary battery having a material mixture containing active material particles capable of reversibly absorbing and desorbing lithium, and a current collector that carries the material mixture, wherein a surface of the current collector has recessed portions, and an area occupied by the recessed portions accounts for not less than 30% of an a material mixture carrying area of the current collector. The present invention further relates to an electrode for a lithium ion secondary battery wherein, in a cut surface obtained by simultaneously cutting a material mixture and a current collector vertically to an electrode plane, the maximum depth of recessed portions is not less than 1 μm, or a difference between an average thickness of a current collector and a maximum thickness of the current collector is not less than 0.35 μm.
摘要翻译：本发明的目的是提供一种锂离子二次电池用电极，即使在暴露于诸如指甲穿透试验或粉碎试验等严酷条件下也能够确保高水平的安全性，并且显示出优异的输出特性。本发明涉及一种锂离子二次电池用电极，其具有包含能够可逆地吸收和解吸锂的活性物质粒子的材料混合物，以及承载该材料混合物的集电体，其中集电体的表面具有凹部，并且由凹部占据的面积占集电体的混合物承载面积的30％以上。本发明还涉及一种锂离子二次电池用电极，其特征在于，在与电极平面垂直地同时切割材料混合物和集电体的切断面中，凹部的最大深度为1μm以上，或者集电体的平均厚度与集电体的最大厚度的差为0.35μm以上。

4. 发明申请

US20080186030A1 EVALUATION METHOD AND EVALUATION APPARATUS FOR EVALUATING BATTERY SAFETY, AND BATTERY WHOSE SAFETY INDICES HAVE BEEN DETERMINED WITH THE SAME 失效
标题翻译：用于评估电池安全性的评估方法和评估装置，以及确定安全指标的电池
公开(公告)号：US20080186030A1
公开(公告)日：2008-08-07
申请号：US12027126
申请日：2008-02-06
申请人： Shinji Kasamatsu , Hajime Nishino , Masato Fujikawa , Mikinari Shimada
发明人： Shinji Kasamatsu , Hajime Nishino , Masato Fujikawa , Mikinari Shimada
IPC分类号： G01N27/416 , G01N25/00
CPC分类号： H01M10/44 , H01M2/34 , H01M4/131 , H01M4/133 , H01M10/0525 , H01M10/486 , H01M2200/00
摘要： An evaluation method for evaluating safety of a battery having an electrode group including a positive electrode plate, a negative electrode plate and a separator inserted between said electrode plates. The method includes the steps of charging the battery to a predetermined voltage; incorporating conductive foreign matter into the charged battery such that the conductive foreign matter is in contact with the positive electrode plate, and not in contact with the negative electrode plate; immersing said battery into which the conductive foreign matter has been incorporated in an electrolyte to dissolve and deposit the conductive foreign matter, thereby causing an internal short circuit to occur in the battery; and evaluating a thermal behavior of the battery in which the internal short circuit has occurred, and outputting results of the evaluation as safety indices.
摘要翻译：一种用于评估具有包括插入在所述电极板之间的正极板，负极板和隔板的电极组的电池的安全性的评估方法。该方法包括以下步骤：将电池充电至预定电压; 将导电异物掺入带电电池中，使得导电异物与正极板接触，而不与负极板接触; 将其中已经将导电异物掺入其中的所述电池浸入电解质中以溶解和沉积导电异物，从而在电池中发生内部短路; 并评估发生内部短路的电池的热性能，并输出评价结果作为安全指标。

5. 发明授权

US07336081B2 Cell evaluation device including short circuit detector 失效
标题翻译：电池评估装置包括短路检测器
公开(公告)号：US07336081B2
公开(公告)日：2008-02-26
申请号：US11098378
申请日：2005-04-05
申请人： Shinji Kasamatsu , Hajime Nishino , Mikinari Shimada
发明人： Shinji Kasamatsu , Hajime Nishino , Mikinari Shimada
IPC分类号： G01N27/416
CPC分类号： G01R31/3679 , H01M10/0525 , H01M10/4285
摘要： A cell evaluation device has a short circuit detection portion to detect an internal short circuit within a test cell that has been subjected to nail penetration or crushing using the pressure from a pressurization portion, a pressure control portion to halt the operation of the pressurization portion on detection of a short circuit, and a cell information detection portion to collect and record cell information such as the cell temperature. By using such a cell evaluation device, the location of an internal short circuit during an abuse test is specified, and variations in the cell temperature increase accompanying the internal short circuit is minimized.
摘要翻译：电池评估装置具有短路检测部，用于检测使用来自加压部的压力进行指甲穿透或破碎的测试电池内的内部短路，压力控制部分停止加压部分的操作检测短路，以及小区信息检测部分，用于收集和记录诸如小区温度的小区信息。通过使用这样的电池评价装置，规定了在滥用试验期间的内部短路的位置，并且使伴随内部短路的电池温度升高的变化被最小化。

6. 发明授权

US08951674B2 Non-aqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池
公开(公告)号：US08951674B2
公开(公告)日：2015-02-10
申请号：US11473327
申请日：2006-06-23
申请人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
发明人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
IPC分类号： H01M4/13 , H01M4/50
CPC分类号： H01M4/131 , H01M2/1653 , H01M4/505 , H01M4/525 , H01M10/4235
摘要： A non-aqueous electrolyte secondary battery including: a positive electrode having a positive electrode material mixture containing a composite lithium oxide; a negative electrode; a polyolefin separator; a non-aqueous electrolyte; and a heat-resistant insulating layer interposed between the positive and negative electrodes. The positive electrode material mixture has an estimated heat generation rate at 200° C. of not greater than 50 W/kg. The positive electrode and the negative electrode are wound together with the separator and the heat-resistant insulating layer interposed therebetween.
摘要翻译：一种非水电解质二次电池，包括：具有含有复合氧化锂的正极合剂混合物的正极; 负极; 聚烯烃分离器; 非水电解质; 以及插入在正极和负极之间的耐热绝缘层。正极材料混合物在200℃下的估计发热速率不大于50W / kg。将正极和负极与隔板缠绕在一起，并且将耐热绝缘层插入其间。

7. 发明授权

US08187748B2 Non-aqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池
公开(公告)号：US08187748B2
公开(公告)日：2012-05-29
申请号：US11473334
申请日：2006-06-23
申请人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
发明人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
IPC分类号： H01M4/13
CPC分类号： H01M4/131 , H01M2/1653 , H01M2/1673 , H01M4/133 , H01M4/525 , H01M4/58 , H01M10/0431 , H01M10/0525 , H01M10/0587 , H01M10/4235
摘要： A non-aqueous electrolyte secondary battery including: a positive electrode having a positive electrode material mixture containing a composite lithium oxide; a negative electrode; a polyolefin separator; a non-aqueous electrolyte; and a heat-resistant insulating layer interposed between the positive and negative electrodes. The positive electrode material mixture has an estimated heat generation rate at 200° C. of not greater than 50 W/kg. The positive electrode and the negative electrode are wound together with the separator and the heat-resistant insulating layer interposed therebetween.
摘要翻译：一种非水电解质二次电池，包括：具有含有复合氧化锂的正极合剂混合物的正极; 负极; 聚烯烃分离器; 非水电解质; 以及插入在正极和负极之间的耐热绝缘层。正极材料混合物在200℃下的估计发热速率不大于50W / kg。将正极和负极与隔板缠绕在一起，并且将耐热绝缘层插入其间。

8. 发明申请

US20080143337A1 Evaluation method for safety upon battery internal short circuit, evaluation device for safety upon battery internal short circuit, battery, battery pack, and manufacturing method for battery and battery pack 有权
标题翻译：电池内部短路的安全性评价方法，电池内部短路时的安全性评价装置，电池，电池组以及电池和电池组的制造方法
公开(公告)号：US20080143337A1
公开(公告)日：2008-06-19
申请号：US11798630
申请日：2007-05-15
申请人： Masato Fujikawa , Shinji Kasamatsu , Hajime Nishino , Mikinari Shimada
发明人： Masato Fujikawa , Shinji Kasamatsu , Hajime Nishino , Mikinari Shimada
IPC分类号： H01M10/48 , H01M2/00
CPC分类号： H01M10/4235 , G01R31/025 , G01R31/3641 , H01M10/052 , H01M10/4285 , H01M10/48 , H01M10/488 , Y10T29/49108
摘要： A method for evaluating the safety of a battery under an internal short-circuit condition. The method for evaluating an internal short-circuit of a battery is characterized in that a short-circuit can be caused at a desired location inside the battery. According to the evaluation method of the invention, the evaluation result is not affected by the constitution of the outermost part of the battery unlike nail penetration tests which are conventional evaluation methods. Also, unlike crush tests which are conventional evaluation methods, the locations of short-circuits do not vary among tests and the safety under an internal short-circuit condition can be evaluated accurately.
摘要翻译：一种用于在内部短路状况下评估电池的安全性的方法。用于评估电池的内部短路的方法的特征在于，可以在电池内的期望位置处引起短路。根据本发明的评价方法，评价结果不受作为常规评价方法的指甲穿透试验的电池的最外部的构成的影响。此外，与常规评估方法的挤压测试不同，短路的位置在测试之间不变，并且可以准确地评估内部短路条件下的安全性。

9. 发明申请

US20060286444A1 Non-aqueous electrolyte secondary battery 有权
标题翻译：非水电解质二次电池
公开(公告)号：US20060286444A1
公开(公告)日：2006-12-21
申请号：US11473327
申请日：2006-06-23
申请人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
发明人： Hajime Nishino , Shinji Kasamatsu , Hideharu Takezawa , Kazuhiro Okamura , Mikinari Shimada
IPC分类号： H01M10/50 , H01M2/16 , H01M4/58 , H01M4/48 , H01M4/50 , H01M4/52
CPC分类号： H01M4/131 , H01M2/1653 , H01M4/505 , H01M4/525 , H01M10/4235
摘要： A non-aqueous electrolyte secondary battery including: a positive electrode having a positive electrode material mixture containing a composite lithium oxide; a negative electrode; a polyolefin separator; a non-aqueous electrolyte; and a heat-resistant insulating layer interposed between the positive and negative electrodes. The positive electrode material mixture has an estimated heat generation rate at 200° C of not greater than 50 W/kg. The positive electrode and the negative electrode are wound together with the separator and the heat-resistant insulating layer interposed therebetween.
摘要翻译：一种非水电解质二次电池，包括：具有含有复合氧化锂的正极合剂混合物的正极; 负极; 聚烯烃分离器; 非水电解质; 以及插入在正极和负极之间的耐热绝缘层。正极材料混合物在200℃下的估计发热速率不大于50W / kg。将正极和负极与隔板缠绕在一起，并且将耐热绝缘层插入其间。

10. 发明申请

US20060286439A1 Lithium secondary battery 有权
标题翻译：锂二次电池
公开(公告)号：US20060286439A1
公开(公告)日：2006-12-21
申请号：US11339617
申请日：2006-01-26
申请人： Masato Fujikawa , Shinji Kasamatsu , Hajime Nishino , Hideharu Takezawa , Mikinari Shimada
发明人： Masato Fujikawa , Shinji Kasamatsu , Hajime Nishino , Hideharu Takezawa , Mikinari Shimada
IPC分类号： H01M10/50 , H01M2/16 , H01M4/52 , H01M4/40
CPC分类号： H01M10/052 , H01M2/1653 , H01M2/166 , H01M2/1673 , H01M2/1686 , H01M4/525 , H01M10/4235 , Y02T10/7011
摘要： A lithium secondary battery including: an electrode group, a non-aqueous electrolyte and a battery case housing the electrode group and the non-aqueous electrolyte, the electrode group including a positive electrode, a negative electrode and a separator layer interposed between the positive electrode and the negative electrode, wherein an end-of-charge voltage and an end-of-discharge voltage are set in such a manner that the electrode group has an energy density of not less than 700 Wh/L, the separator layer includes a porous heat-resistant layer, and a short circuit area A produced when an internal short circuit has occurred between the positive electrode and the negative electrode, and a reduced area B of the porous heat-resistant layer that is produced by heat generation satisfy 1≦(A+B)/A≦10.
摘要翻译：一种锂二次电池，其包括：电极组，非水电解质和容纳所述电极组和所述非水电解质的电池壳体，所述电极组包括正极，负极和插入在所述正极之间的隔板层和负极，其中以使得电极组的能量密度不低于700Wh / L的方式设定充电结束电压和放电终止电压，隔板层包括多孔耐热层和在正极和负极之间发生内部短路时产生的短路面积A，通过发热产生的多孔耐热层的减少面积B满足1 <= （A + B）/ A <= 10。

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